International Journal of Geosciences
Vol. 3 No. 3 (2012) , Article ID: 21185 , 24 pages DOI:10.4236/ijg.2012.33055
Geochemistry and Geochronology of Peraluminous High-K Granitic Leucosomes of Yaoundé Series (Cameroon): Evidence for a Unique Pan-African Magmatism and Melting Event in North Equatorial Fold Belt
1Department of Geology, University of Dschang, Dschang, Cameroon
2Department of Earth Sciences, University of Yaoundé I, Messa, Yaoundé
3Institut für Mineralogie, Technische Universität Bergakademie, Freiberg, Germany
4Department of Geology, University of Buea, Buea, Cameroon
Email: *tngnotue@yahoo.fr, lpgsdor@yahoo.com
Received January 2, 2012; revised March 6, 2012; accepted May 5, 2012
Keywords: Pan-African North-Equatorial Fold Belt; Yaoundé series; EMP monazite dating; LA-ICP-MS U-Pb dating; Leucosomes; Peraluminous; Melting event; Magmatism
ABSTRACT
Geochemical and geochronological studies have been carry out on the leucosomes of Yaoundé series with the aims to identify the magma sources and to indicate their production periods and emplacement within the formations of the Pan-African North-Equatorial Fold Belt (PANEFB) in Cameroon. The Yaoundé series belongs to the Southern domain of the PANEFB and it is composed of migmatites in which two types of granitic leucosomes (in situ leucosomes and injected leucosomes) have been distinguished. These rocks display characteristic of calc-alkaline (in situ leucosomes) and high-K calc-alkaline to shoshonitic series (injected leucosomes). All the rocks are peraluminous with in situ leucosomes conform to S-type and injected leucosomes conform to Iand S-type granitoids. Major and trace elements composition reveal that in situ leucosomes derived from the partial melting of the host metapelite whereas injected leucosomes derived from the melting of metagreywacke. These sources are similar to those of granitoids from central and northern domains of the PANEFB. Th-U-Pb dating by electron microprobe (EMP) and LA-ICP-MS U-Pb dating on zircon have been used to constraints the melting event and emplacement of leucosomes in Yaoundé series. Th-U-Pb monazite dating, undertaken in two samples of leucosomes, gives two groups of monazite ages. The older group gives an age of 658 Ma whereas the age of younger group is 592 Ma. U-Pb dating of zircons from the leucosomes reveals a Pan-African age ranging from 626 to 654 Ma whereas zircons from metapelitic host rock reveal the overprinting of an early Pan-African event 911 - 1127 Ma on Palaeoproterozoic (2127 Ma) inheritance. These data clearly indicate that the host rocks of leucosomes of Yaoundé series have been firstly metamorphosed during Tonien-Stenien period (911 - 1127 Ma) and reveal the existence of extended unique melting event (592 and 658 Ma) in the Yaoundé series which is contemporaneous with the magmatism responsible for the emplacement of granitoids in the other domains of the PANEFB.
1. Introduction
Peraluminous magmatism is largely reported in the collisional belt. However, this magmatism is also observed, but in least proportion, in the passive margin setting where it is expressed by volcanic tuffs [1,2]. The study of metamorphic and igneous rocks provides important information on the magmatic processes which took place in the continental lithosphere, especially in the collisional belt. In this type of orogeny, there is a strong relation between metamorphism, deformation, melting and/or magmatism. The study of the granitic melt is of fundamental importance for the understanding of the main processes of genesis and evolution of the continental crust and notably of the palingenesis.
Till date, peraluminous magmatism in Cameroon is only reported in the northern and the central domains of the Pan-African North-Equatorial Fold Belt (PANEFB). The study of the leucosomes in the migmatites of Yaoundé in the southern domain of the PANEFB has revealed their granitic composition and their peraluminous affinity. The ubiquity of the magmatism in the PANEFB, which spreads more than 500 km, from the northern domain to the southern domain, can be assigns either to the existence of a unique melting event along the belt, or to distinct melting episodes. Indeed, the uniqueness of metamorphic and tectonic phenomena throughout the PANEFB was demonstrated by many authors [3-5].
This paper presents the results of geochemical and geochronological studies of the leucosomes of the southern domain of the Pan-African North-Equatorial Fold Belt. These results, compared to those obtained on the granitoids of the northern and the central domains, allow us 1) to identify the magma sources all over the PanAfrican North-Equatorial Fold Belt and 2) to indicate their production periods (ages) and emplacement within the formations of the PANEFB in Cameroon.
2. Regional Geological Setting
The Yaoundé series belongs to the Southern domain of the Pan-African North-Equatorial fold belt and is situated in the northern edge of the Congo craton (Figure 1). It is composed of intensely deformed metasedimentary and meta-igneous rocks [6]. The metasedimentary rocks are made up of chlorite schist, garnet and/or kyanite bearing micaschist and garnet and kyanite bearing gneisses. The protoliths of these rocks are shale and greywacke deposited in an intracontinental rift context or thinned margin [6,7]. These metasediments are locally intruded by diorite and/or granodiorite and metamorphosed under HPHT conditions (T = 750˚C - 800˚C, P = 0.9 - 1.3 GPa; [6, 8]) at 620 ± 10 Ma (U-Pb age on zircon; [9]) or at 616 Ma (U-Pb age on zircon and Sm-Nd; [10]) and or between 613 ± 33Ma and 586 ± 15Ma (Th-U-Pb age on monazite; [11]).
The rocks of this unit have been affected by two major phases of deformation associated to the metamorphism [6, 12,13]: 1) the D1 phase is marked by a compositional bedding (So/S1) parallel to the preferential orientation of the phyllosilicates and ended by the formation of the high
Figure 1. (a) Location map of the study area; (b) Geological map of Yaoundé group (adapted from [6]). 1: Congo Craton; 2: Mbalmayo series; 3 and 4: Yaoundé series (Garnet micaschist and migmatitic gneisses, respectively); 5: Sampling site.
pressure granulite-facies assemblage and the beginning of partial melting; 2) the D2 event is a compressionnal phase marked by the intrusion of mafic rocks, the in situ partial melting, the injection of the quartzo-feldspathic melt along the C2 shear plane and by a southward thrusting of the rocks of this series onto the Archean Congo Craton. The migmatisation develops mainly during this second phase.
In addition to the southern domain, the Pan-African North-Equatorial Fold Belt is made of two other geodynamic domains (the northern and the central domains, Figure 2):
Figure 2. Geological map of Cameroon (adapted from [4]) showing the localization of the Yaoundé area and the three main lithotectonic domains of PANEFB: 1) Southern domain; 2) Central domain; 3) Northern domain. CCSZ: Central Cameroon Shear Zone); SF: Sanaga Fault; TBF: Tibati Banyo Fault; NT: Ntem Complex; DS: Dja Series; NS: Nyong Series.
1) The northern domain, with polyphase and polycyclic evolution [14-18], consists of metavolcanite of tholeiitic and alkaline affinities associated with metasediments (Poli series) and widespread 630 - 660 Ma calc-alkaline orthogneisses interpreted as major episode of accretion [17]. These orthogneisses contain granulitic relics of Palaeoproterozoic age (2100 Ma, [9]).
2) The central domain consists of an assembly of fragments of Paleoproterozoic continental crust recristallised under high-grade granulite facies (850˚C - 900˚C, 10 - 12 Kb) at ca. 2100 Ma [3,19,20] intruded by widespread Pan-African syntectonic granitoids. These granitoids have high-K calc-alkaline to shoshonitic affinities. They are either S-type peraluminous granite [4], or I-type metaluminous to weakly peraluminous granite [21-24] and are derived from the partial melting of the metapelite or metagreywacke sources. Their emplacement age ranges from 558 Ma to 621 Ma [19,21,24-26].
3. Analytical Procedures
3.1. Whole Rock Geochemistry
Samples were collected from fresh outcrops in quarries around Yaoundé. Leucosomes were separated from each other in a set of centimeter-thick slabs cut perpendicular to the foliation of the samples. Major elements, as well as Rb, Sr, Zr, Nb, and Y, were determined by X-ray fluorescence (XRF) spectrometry at the University of Nancy I using the procedure outlined by Govindaraju & Montanari [27]; Th, U and rare earth elements (REE) were determined by inductively coupled plasma emission spectrometry (ICP-ES) and by absorption spectrometry at CRPG, Nancy [28]. Analytical uncertainties are estimated at 2% for major elements, and at 5% or 10% for trace element concentrations higher or lower than 20 ppm respectively. Precision for REE is 5% when chondrite-normalized concentrations are >10 and 10% when there are lower. Samples are normalized to chondrite using the factors presented by Jahn et al. [29].
3.2. EMP Method
Analysis of Th, U and Pb for calculation of monazite model ages, as well as for Ca, Si, LREE and Y for corrections and evaluation of the mineral chemistry were carried out on a JEOL JXA 8200 (Chair of Mineralogy, University of Erlangen-Nürnberg) at 20 kV, 100 nA, and a beam size of 5 μm [30]. M1 lines of Th and Pb and the M1 lines for U of a PETH crystal were selected for analysis. Resulting errors (1σ) are typically 1.0%, 0.20% and 1.30% for Pb, Th and U, respectively, based on counting statistics. The lines Lα1 for La, Y, Ce; Lβ1 for Pr, Sm, Nd, Gd and Kα1 for P, Si and Ca were chosen. Orthophosphates of the Smithsonian Institution were used as standards for REE analysis [31,32]. Calibration of PbO was carried out on a vanadinite standard, while U was calibrated on an appropriate glass standard with 5 wt% UO2. The Madmon monazite [30], dated by SHRIMP at 489 ± 9 Ma and numerous Pb-Pb-TIMS monazite evaporation data at 497 ± 2 Ma, contains ThO2 at around 10 wt%. The ThO2 in Madmon was previously determined by LA-ICPMS and by the microprobe at University of Salzburg [33] and was used for calibration of ThO2 as well as for the control of data. Interference of YLg on the PbM line was corrected by linear extrapolation after measuring several Pb-free yttrium glass standards as proposed by Montel et al. [34]. An interference of ThMg on UM was also corrected by using a Th-glass standard. Interference of a Gd-line on UMβ needs correction when Gd2O3 in monazite is >5 wt%. These parameters matched the analytical problems discussed in [35] in the best way [30]. For each single analysis, a chemical age (CHIME) and a 2σ error based on the Pb counting statistics was calculated. Other possible sources of error, as standardization, matrix effect correction, YLγ-on-PbMα correction and instrumental drift were not taken into account. Therefore the given error on the calculated ages should be considered as a minimum error.
3.3. U-Pb LA-ICP-MS Method
U-Pb isotopic analyses were performed in the geochronology laboratory of the University of Brasilia and followed the analytical procedure described by Buhn et al. [36]. Zircon concentrates were extracted from ca. 10 kg rock samples using conventional gravimetric and magnetic techniques at the geochronology laboratory of the University of Brasilia. Mineral fractions were hand picked under a binocular microscope to obtain fractions of similar size shape and colour.
For in situ ICP-MS analyses, hand picked zircon grains were mounted in epoxy blocks and polished to obtain a smooth surface. Backscattered electron and cathodoluminescence images were obtained using a scanning electron microscope in order to investigate the internal structures of zircon crystals prior to analysis.
Before LA-ICP-MS analyses, mounts were cleaned with dilute (ca. 2%) HNO3. The samples were mounted in a specially adapted laser cell and loaded into a new Wave UP213 Nd: YAG laser (l = 213), linked to a Thermo Finnigan Neptune Multi-collector ICPMS. Helium was used as the carrier gas and mixed with argon before entering the ICP. The laser was run at a frequency of 10 Hz and energy of 34%. In order to avoid down-hole fractionation during ablation, we adopted for a raster scan of about 70 μm in total diameter with a spot size of 30 μm.
Two international zircon standards were analysed throughout the U-Pb analyses. The zircon standard GJ-1 [37] was used as the primary standard in a standardsample bracketing method, accounting for mass bias and drift correction.
The resulting correction factor for each sample analysis considers the relative position of each analysis within the sequence of 4 samples bracketed by two standard and two blank analyses each [38]. The Temora 2 standard [39] was run at the start and the end of each analytical session, yielding an accuracy around 2% and a precision in the range of 1%. The errors of sample analyses were propagated by quadratic addition of the external uncertainty observed for the standards to the reproducibility and within run precision off each unknown analysis. The instrumental set-up and further details of the analytical method applied are given by Buhn et al. [36].
The masses 204, 206 and 207 are measured with ion counters, and 238U was analyzed on a Faraday cup. The signal of 202Hg was monitored on an ion counter for correction of the isobaric interference between 204Hg and 204Pb. The signals during ablation were taken in 40 cycles of 1 sec each. For data evaluation, only coherent intervals of signal response were considered. Data reduction was performed with an Excel spreadsheet developed by one of the authors that considers blank values, zircon standards composition and errors propagation. The 204Pb signal intensity was calculated and corrected using a natural 202Hg/204Hg ratio of 4.346. A common Pb correction was applied for zircons with 206Pb/204Pb lower than 1000, applying a common lead composition following the Stacey and Kramers model [40]. Plotting of U-Pb data was performed by ISOPLOT v.3 [41] and errors for isotopic ratios are presented at the 2σ level. Because of the statistical treatment applied in calculating Concordia ages, those are more precise than any individual U/Pb or Pb/Pb ages [42] and, in data herein presented, always correspond to less than the 2% accuracy obtained from the intercalibration of the standards. Consequently, the Isoplot calculated errors were modified in order to incorporate this uncertainty level and, hence, represent a more realistic age in terms of the analytical limitations of the method.
4. Results
4.1. Petrography and Mineral Chemistry
Two main types of leucosomes have been distinguished on the basis of petrographic and structural criteria:
1) Injected leucosomes Injected leucosomes occur in two manners: i) along the C2 shear zone; ii) as cross-cutting dykes (Figure 3(a)). They are observed in both metapelitic gneisses and metabasites where they are sometimes associated with ultramafic dykes. Injected leucosomes are either:
i) fine-grained, composed of ribbons quartz (25% - 30%), large perthitic K-feldspar (Or95 Ab5-Or89 Ab11) crystals, euhedral plagioclase (5% - 10%) crystals rarely zoned showing deformed twins (figure 3(b)). Garnet (<3%) occurred as euhedral crystals or as atoll including
Figure 3. Field occurrences of injected leucosomes (a) and in situ leucosomes (c), and detail of microstructure of injected leucosomes (b) and in situ leucosomes (d).
muscovite, rutile, plagioclase and quartz. The average mineral composition of garnet is presented in table 1. Garnet forms solid solution (Figure 4) of almandine (XFe: 0.63 - 0.68) rich in pyrope (XMg: 0.24 - 0.30) meanwhile kyanite (<2%) is prismatic, crackled crystals associated with garnet. Accessory minerals include apatite, zircon, monazite and rutile;
ii) coarse-grained, mainly composed of ribbons or interstitial quartz (25% - 40%), plagioclase, K-feldspar and biotite. Plagioclase (10% - 45%; An17-An18) occurs as euhedral antiperthitic crystals with deformed twins and sometimes as porphyroblasts with inclusions of quartz and biotite flakes. K-feldspar (10% - 50%) occurs as large crystals and is often perthitic (Or95 Ab5-Or86 Ab14). Biotite (<2%) is of magnesian composition (XMg: 0.62 - 0.67, Table 2; Figure 5) and occurs as flakes of various dimensions, most of which contain small inclusions of zircon and apatite. Accessories are monazite, zircon, apatite and often sillimanite, calcite, tourmaline and muscovite.
2) In situ leucosomes In situ leucosomes are the most abundant in the Yaoundé series. They are observed in both metapelite and metabasite (Figure 3(c)), structured or not, medium to coarsed-grained, mainly composed of quartz, plagioclase, K-feldspar and garnet. Quartz (30% - 35%) forms elongated or interstitial crystals with undulatory extinction. Plagioclase (An21-An24; 20% - 60%) are anhedral and antiperthitic (Or92Ab8-Or90Ab10) crystal with polycrystalline almond shape. K-feldspar (10% - 20%) is
Figure 4. Triangular diagram showing the nature of garnet in Yaoundé leucosomes.
Table 1. Electron microprobe data of garnet from Yaoundé leucosomes.
Table 2. Electron microprobe data of biotite from Yaoundé leucosomes.
Figure 5. XFe vs AlVI diagram showing the composition of biotite in Yaoundé leucosomes.
anhedral and perthitic (Or89Ab11-Or93Ab7). The perthitic composition ranges from An18Ab82 to An20Ab80. Garnets (<5%) appears as small euhedral crystals or zoned porphyroblasts (Figure 3(d)). The mineral composition of garnet is given in table 1. They form a solid solution of almandine (XFe: 0.55 to 0.58) rich in pyrope (XFe = 0.33 to 0.39) and poor in spessartine (Figure 4). Biotite (≤3%) has magnesian composition (XMg = 0.65 - 0.67, Table 2) and appears as frayed flakes. Kyanite (<2%) is corroded twinned euhedral crystals (1 - 3 mm). They are often oriented or lodged between plagioclase, K-feldspar, garnet and quartz crystals (Figure 3(d)). Muscovite, monazite, zircon, rutile, apatite and oxides represent the accessory phase.
In the XFe vs AlVI biotite diagram (Figure 5), there is a significant difference between in situ leucosomes and injected leucosomes. In situ leucosomes are enriched in both aluminium and iron, whereas injected leucosomes are depleted with respect to the same elements.
4.2. Geochemistry
1) Major elements
We use the Na2O + K2O vs SiO2 of Middlemost [43] for chemical classification of the different types of lecosomes. In situ leucosomes plot in granite while injected leucosomes plot in granite and quartz monzonite fields (Figure 6). The rocks are silica rich (with a SiO2 content ranging from 64.66 to 80.35 wt%, table 1) and show a variable content in total alkaline content (3.53 ≤ Na2O + K2O ≤ 4.84% for in situ leucosomes; 6.15 ≤ Na2O + K2O ≤ 9.21% for injected leucosomes). This high alkaline content is also expressed by the K2O/Na2O ratios range from 0.49 to 0.59 in in situ leucosomes and from 0.51 to 3.72 in injected leucosomes. In the K2O vs SiO2 diagram, the in situ leucosomes plot in the calc-alkaline domain while the injected leucosomes show high K-calcalkaline
Figure 6. Classification diagram of plutonic rocks [43] showing the localization of the studied leucosomes in the granite field.
to shoshonitic affinities (Figure 7). In major elements variation diagrams vs SiO2 (Figure 8), the two rock types form well defined clusters, and taken together define more or less well-defined trends. In situ leucosomes show decreasing concentration of K2O, Al2O3, MgO, TiO2 and CaO with an increase in SiO2, while injected leucosomes show decreasing concentration of Al2O3, TiO2, Fe2O3 and MgO with an increase in SiO2. In the alumina index molar diagram (Al2O3/(CaO + Na2O + K2O) vs Al2O3/(Na2O + K2O)), all the rocks plot in peraluminous field with in situ leucosomes conform to S-type and injected leucosomes conform to S-type and I-type granitoids (Figure 9).
2) Trace elements
Trace elements concentrations of the different leucosomes are listed in table 3. Selected elements are plotted against SiO2 in figure 10. In in situ leucosomes, Rb and Zr concentrations decrease with increasing of SiO2 while Y, Sr are scatter with increasing of SiO2. In injected leucosomes Zr, Sr, Y contents decrease when SiO2 contents increase (Figure 10). The K/Rb ratios (261 - 361 for in situ leucosomes; average at 315 and 351 - 737 for injected leucosomes; average at 480) are similar to those observed in the continental calc-alkaline igneous series [44,45]. Chondrite-normalized REE (the normalizing values are from Jahn et al. [29]) patterns show that the two types of leucosomes are much fractionated. In situ leucosomes have a strong LREE (Light Rare Earth Element) enrichment (CeN/SmN = 1.5 - 2.03) compared to HREE (GDN/YbN = 1.20 - 1.54) with more pronounced positive Eu anomalies (Eu/Eu* = 1.29 - 1.36) for some and weakly negative Eu anomalies (Eu/Eu* = 0.93) for the others (Figure 11(A)). Injected leucosomes are also characterised by a strong HREE (heavy rare earth element) depletion (GdN/YbN = 1.60 - 16.20) and LREE
Figure 7. Diagram K2O vs SiO2 showing calc-alkaline, high-K to shoshonitic affinity of the Yaoundé leucosomes. Symbols as in figure 6.
enrichment (CeN/SmN = 2.19 - 4.70; Figure 11(B)). The REE patterns lead to the distinction of two groups of injected leucosomes: 1) a first group (Figure 11(Ba)) characterized by strong Eu positive anomalies (Eu/Eu* = 2.01 - 8.84) and, 2) a second group (Figure 11(Bb)) with negative to null Eu anomalies (Eu/Eu* = 0.63 - 1.22) and a strong enrichment in LREE (CeN/SmN = 2.19 - 4.70). These geochemistry behaviours are in accordance with subdivisions done in petrography.
4.3. Geochronology
4.3.1. U-Th-Pb Age on Monazite
Two samples of leucosomes (OL3A & OL3B) were selected for U-Th-Pb monazite ages. These samples were chosen because they are more enriched in monazite crystals than other samples. The analyzed monazite crystals are of two main types: 1) globular or ovoid crystals, often crackled with no optical zoning (Figures 12(a) and (b)); 2) prismatic crystals, also with no optical zoning, but spotted by opaque granules which form inclusions in biotite flakes (Figures 12(b) and (c)). No systematic core-to-rim optical age zonation of were observed. This observation implies that monazite crystallize from melting liquid. This allows the calculation of ages composed of several single analyses by regression through zero [34] and of weighted means [41]. Chemical Th-U-Pb ages (Tables 4 and 5) have been gotten by Electron microprobe analysis (EMP). Two groups of ages, corresponding probably to the two events of monazite crystallisation, are recognised in the diagrams of mineral chemistry of monazite element vs Th-U-Pb chemical ages (Figures 13 and 14). The first event (younger) occurs at around 600 Ma and the second (older) at around 660 Ma. The analysed monazite age data are compared in the PbO vs ThO2* diagram (Figure 15(a)) of Suzuki et al. [46]. On this diagram, the two generations of monazite previously described are clearly individualized. The average age of
Table 3. Representative major (wt%) and traces (ppm) elements analyses of the Yaoundé leucosomes.
Figure 8. Harker diagrams of selected major elements. Symbols as in figure 6.
the younger generation gives 592 ± 10 Ma while it gives 658 ± 25 Ma for the older one (Figure 15(b)). These two groups of ages seem to belong to the same thermal event because the petrography study reveals that all the monazite crystals are included in biotite flakes. Statistically, all these data can be considered as belonging to the same crystal population.
4.3.2. LA-ICP-MS U-Pb Zircon Ages
1) U-Pb zircon ages of leucosomes
Fourteen grains of zircons from the leucosomes of metapelite were analyzed by the LA-ICP-MS method (Table 6). The Concordia diagrams (Figure 16) obtained reveal a concordant Pan-African age at 626 ± 6.4 Ma (MSWD = 2.1). The analyzed zircons crystals did not show any sign of a complex history. The obtained concordant ages correspond to the melting age during the Pan-African orogeny in Cameroon.
For the leucosomes occurring in metabasite, sixteen grains of zircons were analyzed by the same method. The obtained results (Table 7) define a Discordia (Figure 17) with an average Pan-African age at 654 ± 6.7 Ma (MSWD = 1.3).
2) U-Pb zircon age of metapelitic (basement)
Two types of zircon crystals (zoned and no zoned) were identified in metasediment. Zoned zircon crystals are observed in the leucosomes from the metasediment whereas no zoned zircon crystals were selected from paleosome. The analytical results of no zoned zircons are listed on table 8. The ages obtained define a Discordia
Table 4. Electron microprobe analyses of monazite from Yaoundé leucosomes (sample OL3A). Monazite ages from single analyses are given with minimal error (see text).
Figure 9. Molar A/NK vs A/CNK diagram showing the peraluminous character of Yaoundé leucosomes. Symbols as in figure 6.
with upper intercept at 2127 ± 150 Ma and the lower intercept at 911 ± 56 Ma (Figures 18(a) and (b)). This means that the metapelitic rocks (in situ leucosomes rich) of the Yaoundé series underwent Paleoproterozoic history (2127 ± 150 Ma) before the overprinting of an early Pan-African event at around 911 Ma.
Zoned zircon crystals were also analyzed and their radiometric results are given in table 9. The histogram (Figure 19(a)) of zoned zircon crystals shows two groups of ages. This is confirmed in the Discordia diagram (Figure 19(b)) where the ages are discordant and define two intercepts with upper intercept at 1122 ± 110 Ma and the lower one at 620 ± 61 Ma. The 1122 Ma age of the upper intercept confirms the existence within the Yaoundé series of a metamorphic event between 1122 Ma and 911 Ma as revealed by radiometric data of no zoned zircon from metapelite. The lower intercept age (620 ± 61 Ma) is similar to the age previously obtained on no zoned zircons of metapelitic rock (626 ± 6 Ma; Figure 16) and probably corresponds to the melting age. The Tonien-Stenien event (911 - 1122 Ma) is new in the Yaoundé series and in the Pan-African North-Equatorial Fold Belt in general. This period can be interpreted as the beginning of metamorphism in the Yaoundé series.
5. Discussion
5.1. Origin and Petrogenesis of Leucosomes in the Yaoundé Series
Peraluminous magmatism is commonly associated to the
Figure 10. Harker diagrams of selected trace elements. Symbols as in figure 6.
(a) (b)
Figure 11. Chondrite-normalized REE patterns (the normalising values are from Jahn et al., 1978) for in situ leucosomes (a) and injected leucosomes (b).
deformed and metamorphosed rocks of the orogenic belt (along faults and shear zones) or occurs as syn to post-tectonic plutons [47-49]. Three main models have been proposed to explain the formation of peraluminous granitoids: 1) partial melting of quartzo-feldspathic orthogneisses [50]; 2) reaction between basaltic melts and crustal rocks [51]; and 3) the spatial association and the presence of metasedimentary enclaves in the leucogranites suggesting an origin from partial melts of metasedimentary rocks [13,52,53].
Table 5. Electron microprobe analyses of monazite from Yaoundé leucosomes (sample OL3B). Monazite ages from single analyses are given with minimal error (see text).
Figure 12. Backscattered electron images of selected dated monazite crystals in Yaoundé leucosomes: (a) and (b) Globular shape crystals; (c) and (d) Prismatic crystals.
Table 6. LA-ICP-MS U-Pb results for zircons from leucosomes in metapelite of the Yaoundé series.
The leucosomes of the Yaoundé series are characterized by: 1) their peraluminous affinity; 2) their Rb/Zr weak ratios (0.2 - 6.38) characteristic of granites of crustal origin [54]; 3) the relative low content in Sr (1.93 - 499), the relative enrichment in K2O (1.52 - 5.18) and the relatively low contents in CaO (1.24 - 3.04) characteristic of the rocks of pelitic origin [55]. Their chemical composition is similar to S-type granite from S-type Transamazonian and Hercynian peraluminous leucogranites [55, 56] and to that of melts produced experimentally from sedimentary protoliths [57,58]. The enrichment in alkali in relation with CaO is characteristic of calc-alkaline Cordillera type granitoids [59]. In molar diagram CaO/(MgO + FeOt) vs Al2O3/(MgO + FeOt) of Altherr
(a)(b)(c)
Figure 13. Mineral chemistry of monazites vs Th-U-Pb chemical ages of sample OL3A. (a) Y2O3 of monazites vs age; (b) ThO2 of monazite vs age; (c) UO2 of monazites vs age.
(a)(b)(c)
Figure 14. Mineral chemistry of monazites vs Th-U-Pb chemical ages of sample OL3B. (a) Y2O3 of monazites vs age; (b) ThO2 of monazite vs age; (c) UO2 of monazites vs age.
(a) (b)
Figure 15. (a) Th-U-Pb CHIME model ages for Yaoundé leucosomes. Total PbO vs (wt%) isochron diagram; = ThO2 + UO2 equivalents expressed as ThO2, after [46]. Isochron age derived from these diagrams broadly match weighted average ages calculated for the rocks according to [34]; (b) Histogram view of EMP-Th-U-Pb monazite ages.
Table 7. LA-ICP-MS U-Pb results for zircons from leucosomes in metabasite of the Yaoundé series.
et al. [60], the in situ leucosomes are plotted in the field of partial melts from metapelite source whereas the injected leucosomes are plotted in the field of partial melt from metagreywacke source (Figure 20). These sources, which are predominantly found in the upper part of the continental crust, allow us to confirm that the source of in situ leucosomes was the metapelitic host rocks and to suggest that the injected leucosomes are originated
Table 8. LA-ICP-MS U-Pb results for no zoned zircons from leucosomes in metapelite of the Yaoundé series.
Table 9. LA-ICP-MS U-Pb results for zoned zircons from leucosomes in metapelite of the Yaoundé series.
Figure 16. U-Pb Concordia diagram ages for zircons from leucosomes in metapelite of the Yaoundé series.
Figure 17. U-Pb Discordia diagram for zircons from leucosomes in metabasite of the Yaoundé series.
from melting of metagreywacke. The difference between the two types of leucosomes could be linked to the difference in the composition of their source and the probable contamination during transportation of the melting material (displacement and injection of magmatic liquids). Thus the melting phenomenon observed in the Yaoundé series has not only affected the metapelitic rocks of this series but also the metagreywacke of the upper part of the crust as proposed in the other domains of the PANEFB. The proposed source for the leucosome of theYaoundé series is similar to that for the AkumBamenda leucogranites [4] and for the two-mica granitoids of Bafoussam area [21].
5.2. Comparison with the Granitoids of the PANEFB
The leucosomes of the Yaoundé series are silica-rich
(a)(b)
Figure 18. (a) Histogram of ages showing the different thermal event recorded by zoned zircons from leucosomes in metapelite of the Yaoundé series; (b) U-Pb Discordia diagram ages for these zircons.
(71.91 - 74.41 wt% SiO2; Table 10). The alkali concentration (Na2O + K2O =3.53 - 9.11 wt%) and the variable K2O/Na2O ratios between 0.6 and 2 are characteristics of the high-K calc-alkaline to shoshonitic series (Figure 21(a)) as proposed for the granitoids of the central domain of the PANEFB [4,21-24,61-63]. The leucosomes of the Yaoundé series are peraluminous with the characteristics of S-type (in situ leucosomes) and I-type (injected leucosomes) granite. In the alumina index comparison diagram (Figure 21(b)), the in situ leucosomes show similar composition with Akum-Bamenda leucogranites [4] and two-mica granitoids of Bafoussam [21] whereas injected leucosomes are closer to the BanefoMvoutsaha granitoids [22] and to high-K calc-alkaline granitoids of Bapa-Batié [24]. These leucosomes can therefore be considered as peraluminous granite associated to the orogenic belt such as those described in [47-
(a)(b)
Figure 19. (a) Histogram showing the different thermal event recorded by no zoned from leucosomes in metapelite of the Yaoundé series; (b) U-Pb Discordia diagram ages for these zircons.
Figure 20. Molar CaO/(MgO + FeOt) vs Al2O3/(MgO + FeOt) diagram showing the same sources for Yaoundé leucosomes, Akum-Bamenda leucogranites and two-micas granitoids of Bafoussam.
(a)(b)
Figure 21. SiO2 vs K2O (a) and molar A/NK vs A/CNK (b) diagrams showing the same calc-alkaline, high-K to shoshonitic affinity, peraluminous character of the Yaoundé leucosomes, Akum-Bamenda leucogranites and two-micas granitoids of Bafoussam.
49].
The average Sr contents of Yaoundé leucosomes (218 ppm in in situ leucosomes, 410.63 ppm in injected leucosomes) are closer to those of Akum-Bamenda leucogranites (307.39 ppm, table 10), high-K calc-alkaline granitoids of Bapa-Batié (111 - 609 ppm) and Tonga (281 - 780 ppm). The REE patterns of Yaoundé leucosomes and those of the granitoids of the central domain of the PANEFB are strongly parallel (Figure 22).These spectra show that the leucosomes of the Yaoundé series, as the other granitoids of the PANEFB, are strongly fractionated, with HREE depletion and LREE enrichment. However, the Yaoundé in situ leucosomes are more depleted in LREE and enriched in HREE than the AkumBamenda leucogranites and the two-mica granitoids of
Table 10. Compared average chemical analyses of the Yaoundé leucosomes, Akum-Bamenda leucogranite and twomicas granitoids of Bafoussam.
Figure 22. Chondrite-normalized REE comparison patterns for the Yaoundé leucosomes, Akum-Bamenda leucogranites and two-micas granitoids of Bafoussam.
Bafoussam. The REE patterns also show positive Eu anomalies for the Yaoundé leucosomes and negative to null Eu anomalies for the Akum-Bamenda leucogranites and the two-mica granitoids of Bafoussam. This contrasting Eu behaviour can be attributed to the difference in the geodynamic setting (tectono-metamorphic context in Yaoundé and tectono-magmatic context in the other domain of the PANEFB) of the emplacement of these granitoids.
5.3. Uniqueness of the Melting/Magmatism during the Pan-African Orogeny
The Palaeoproterozoic protolith (2127 Ma) of Yaoundé series underwent metamorphism between 1122 and 911 Ma. The Nd isotopic signature confirms the presence of late Paleoproterozoic to Archean relics in the central domain of the PANEFB [3,19,20,64-66]. In the SE of Tibati-Banyo shear zone, Pan-African granitoids derived from melting of a Paleoproterozoic crust with low participation of juvenile magma [3,18,62,66,67]. These observations confirm the initial existence of Paleoproterozoic formations in the three domains of the PANEFB in Cameroon.
The melting or the magmatism responsible for the leucosomes emplacement in the Yaoundé series occurred between 658 and 620 Ma. This magmatism is contemporaneous:
1) In the central domain, with the emplacement of two-mica granitoids of Bafoussam (564 - 558 Ma, EMP age; [21]), high-K calc-alkaline granitoids of Bapa-Batié (619 - 600 Ma, U-Pb age on zircon; [24]), and synkinematic granitoids of Tonga (618 Ma, U-Pb age on zircon; [19]);
2) In the northern domain, with the Pan-African (630 Ma, U-Pb age on zircon; [15]) calc-alkaline Syn-D2 plutonism (diorite, granodiorite and tonalite);
3) In the eastern Cameroon, with the continental magmatism responsible for the emplacement of PanAfrican (614 ± 41 Ma) peraluminous granite and diorite, orthogneisses at 621 ± 13 Ma [25]. These orthogneisses are very abundant at the Cameroon-Central African Republic boundary.
For the above observations, the following interpretations could be made:
1) The high-K calc-alkaline to shoshonitic affinity of granitoids is observed in both central domain [4,19,21, 22,24,63], northern domain [15] and southern domain (as revealed by this work) of the PANEFB. With the ubiquity of the high-K calc-alkaline affinity in the PANEFB, we suggest that a former crust, widespread from the south to the north, was involved in the genesis of these rocks as outlined in [3,5,6];
2) The generalization of magmatism or melting in the whole PANEFB during the Pan-African orogeny between 592 and 658 Ma;
3) The existence of two sources (metapelite and metagreywacke sources) for the peraluminous granitoids of the PANEFB.
All these interpretations allow us to propose, in addition to metamorphism and tectonics, the existence of a unique magmatic event along the entire PANEFB in Cameroon.
6. Conclusions
The main conclusions obtained from this study are the following:
1) The Yaoundé series is composed of metasediment and metabasite which have been metamorphosed during Tonien-Stenien (911 - 1127 Ma) period.
2) These rocks have been affected by a melting responsible for the S-type and I-type peraluminous leucosomes emplacement. These leucosomes are calc-alkaline, high-K to shoshonitic affinity similar to the other granitoids of the PANEFB.
3) Geochemical data reveal that in situ leucosomes derived from the melting of the host metapelite whereas injected leucosomes derived from the melting of metagreywacke. These sources are similar to those of granitoids from central and northern domains of the PANEFB.
4) The melting responsible for the genesis of leucosomes in the Yaoundé series took place between 592 and 658 Ma as the magmatism responsible for the emplacement of granitoids in the other domains the PANEFB.
5) There is therefore uniqueness of melting and magmatism all over the PANEFB as the uniqueness observed in metamorphic and tectonic aspects.
7. Acknowledgements
The authors thank the Institute für Minerologie of University of Freiberg (Germany) and the Laboratory of Geochronology of the University of Brasilia (Brazil) for providing many facilities for EMP monazite dating and LA-ICP-MS U-Pb dating respectively. This is a contribution to IGCP project 616.
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NOTES
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