Materials Sciences and Applications
Vol.09 No.01(2018), Article ID:81735,19 pages

Synthesis, Characterization, Optical and Transport Properties of BaSnO3 Synthesized by Wet Chemical Route

Rakesh Kurre, Sharmila Bajpai, Parmendra Kumar Bajpai*

Department of Pure & Applied Physics, Guru Ghasidas Vishwavidyalaya, Bilaspur, India

Copyright © 2018 by authors and Scientific Research Publishing Inc.

This work is licensed under the Creative Commons Attribution International License (CC BY 4.0).

Received: September 7, 2017; Accepted: January 9, 2018; Published: January 12, 2018


Alkaline earth stannates have renewed attention as potential materials for gas sensing, transparent conducting oxides and ceramic capacitor applications. A noble wet chemical route is chosen to synthesize BaSnO3 powders having micron size grains. Problems related to uneven grains and poor densification in conventional solid state route have been overcome in the present method. X-ray diffraction data confirms the single phase formation without any secondary phase having cubic perovskite structure (S.G. Pm-3 m). The estimated lattice parameter is ≈4.11933 Ǻ and percentage density is ≈90%. The microstructure probed by scanning electron micrograph reveals almost homogeneously distributed particles having random shape with some porosity. Phonon modes in FT-IR and Raman spectra confirm the local symmetry distortion. The DC conductivity at 200˚C approaches almost 2 × 102 (Ω-cm)1, which is almost of the same order as that observed in perovskite based electronic conductors. DC and a.c. electrical conductivity of the material follow Mott’s variable range hopping at low temperature and Arrhenius type thermally activated process at elevated temperatures. Evidence of small polar on formation is also verified. Optical band gap estimated from absorption data is ≈2.94 very close to the reported value. Composition prepared through the noble wet chemical route has high electrical conduction and suitable for gas sensing applications.


X-Ray Diffraction, Raman Spectra, Variable Range Hopping, Phonons

1. Introduction

Barium stannate (BaSnO3) belongs to the family of alkaline earth stannates having the general chemical formula MSnO3 (M = Ca, Ba, Sr) and has been studied widely due to their potential applications in the field of thermally stable capacitors, photo catalyst, chemiresistive sensor materials for toxic and noxious gases [1] - [6] . It stabilizes in cubic perovskite structure at room temperature (space group Pm-3 m) with lattice parameter slightly varying from 0.4117 - 0.4119 nm depending upon the method of synthesis used [7] [8] [9] [10] , and behaves like n-type semiconductor with an optical band gap reported from 3.1 - 3.4 eV [11] [12] [13] [14] . BaSnO3 (BSO)compositions have been widely investigated with a view to improving the sensor response for a number of target gases including NH3, Co, H2, Cl2, LPG, ethanol, NOx, humidity, O2, etc. [15] - [20] .

It may be noted that the bulk and surface electrical properties in polycrystalline ceramics are correlated with microstructure, grain size, density and intrinsic defects present in the material. For the synthesis of BSO powder, different physical and chemical methods are therefore, used to improve the conduction behavior. The solid state reaction route adopted mainly to improve the densification [21] - [26] encountered the problem of low densification and uneven grain growth. In solid state route, sintering in the range of 1200˚C - 1400˚C was inadequate for proper grain growth, inter granular connectivity and adequate densification [19] . BSO ceramics sintered even up to 1600˚C for 12 h even could not eliminate the porosity and only after sintering for 72 h, the relative density > 95% was achieved [23] . Another major problem using high temperature sintering has been that the sintered material resulted into large anion defects and further that the high temperature processing is not compatible with sensor technology [27] . Self-heat sustained method [28] has been suggested as an alternate, and homogeneous grains of cubical nature are obtained in this method at 1325˚C, however, the non-uniformity of grain size has not been addressed [19] . Chemical methods including oxalate co-precipitation method [10] [15] [16] , sol-gel [7] [29] [30] [31] [32] , sol-gel based wet chemical method [33] [34] , hydrothermal [35] [36] [37] , molten salt synthesis [38] , polymerized complex route [39] [40] [41] [42] , etc. have been reported. Most of these reports have focused towards smaller grain size so as to increase the surface area to improve the surface adsorption process. Despite large number of efforts devoted on the synthesis, detailed analysis of transport properties and their correlation with processing parameters based on systematic characterization of material structure at atomic level has been missing. In this paper, we tried to fill that gap and present the structural, microstructural features of the material synthesized through simple wet chemical method and probed the local structural details through FTIR and Raman spectroscopy. Optical band gap and electrical conduction mechanism operating in different temperature ranges are also probed.

2. Experimental Technique

The modified wet chemical method is used to synthesize barium stannate powders. The highly pure starting materials BaCl2 (Aldrich, 99.5%), SnCl4∙5H2O (Sigma, 99.5%), NaOH (BDH, 99%), were used as received. A starting solution was made by mixing 20.823 g of anhydrous barium chloride (BaCl2) and 35.051 g of stannic chloride (SnCl4) in 100 ml deionized doubled distilled water. During this process 4 g sodium hydroxide was added into the solution. The solution was aged for 24 h, a white precipitate was obtained in the lower surface of solution. After filtering, the product was repeatedly washed by distilled water to remove Cl ions. The white powder was dried at 80˚C for 24 h by using a muffle furnace. Finally, the dried barium stannate powders were annealed at 800˚C in ambient environment.

Annealed powders were structurally analyzed using X-ray diffraction data which were measured on X-ray diffractometer (Rigaku Smart Lab, Japan). In order to make impedance measurements, the fine annealed powder was pressed as cylindrical pellets (diameter 10 - 12 mm and 1 - 2 mm thickness) after adding a few drops of poly vinyl alcohol (PVA) as binder. The prepared powder was again annealed at 800˚C temperature in furnace for 5 h. After firing the samples were furnace cooled. The pellets were finally coated with conductive silver paint and dried at 500 ˚C for 2 h before performing dielectric and impedance measurements.

The percentage porosity was calculated using measured experimental density (Archimedes principle as well as by measuring the weight, area and thickness of the pellet) and by calculating the theoretical density from XRD data. X-ray diffraction (XRD) studies of the materials were made at room temperature in the Bragg angle range 20˚C ≤ 2θ ≤ 80˚C with CuKα radiation (λ = 1.5418 Å) using CuKβ filter. The complex impedance measurements over temperature range from 35˚C - 300˚C were performed using a computer controlled impedance analyzer (HIOKI LCR Hi-TESTER MODEL 3532-50) in the frequency range 1 kHz to 1 MHz. Scanning electron microscopy (SEM) is used for the analysis of surface microstructure along with EDAX spectra. DC conductivity was measured by (Keithley) 6514 system electrometer. Room temperature FT-IR and Raman spectra were measured using Shimadzu 7800 FTIR and Technos micro Raman spectrometer respectively.

3. Result and Results and Discussion

3.1. Structural Analysis

Figure 1 shows the room temperature X-ray diffraction pattern of BaSnO3 powder prepared by wet chemical method. The XRD pattern shows peaks due to cubic perovskite structure only without any impurity peak. We have performed the Reitveld refinement on structural data using PDXL software with pseudo-Voight band profile in order to get the reliable estimate of the cubic cell parameters. Table 1 presents the Lattice parameter, unit cell volume and goodness of fitting using Reitveld refinement technique. Accordingly, the value of cell parameter obtained is 4.11933 Å which is very close to the literature value and the fitting parameters are also quite satisfactory. The fitting matches very well with

Figure 1. X-ray diffraction pattern of BSN powder prepared by wet chemical method.

Table 1. Lattice parameter, unit cell volume and goodness of fitting using Reitveld refinement technique.

ICDD DB card No. 04-007-8719 and observed d-values shown in the table are also very close to the reference data. The formation of single phase material is confirmed as no extra XRD lines due to precursor oxides or minor secondary phases are traceable within the detection limit. The theoretical density of the unit cell was calculated from XRD data and density of the pellets was measured using Archimedes technique. Accordingly, the densification of ceramics is 91.7%. We also obtained the percentage density by simply weighing the pellets and measuring its volume which also comes out to be around 90%. The average crystallite size calculated using Scherer method is ~42 nm. Small crystallite size may be the reason while higher densification is observed at relatively lower temperature.

3.2. Microstructural Characterization

The surface morphology was studied by scanning electron microscopy (Zeiss, EVO® MA 10). The surface microstructure is an important factor that controls the electrical properties through inter-grain connectivity. The SEM micrographs of the BSO powder synthesized by wet chemical route are shown is Figure 2(a). Random grain growth is clearly visible with agglomeration of smaller particles forming the grains. Average grains size is estimated from linear intercept method using five different lines on the micrographs each having roughly 15 grains.

(a) (b)

Figure 2. (a) Scanning electron microscope (SEM) micrograph of BaSnO3 powder; (b) EDAX signal from section of BaSnO3 surface. Inset shows the region from which the signal spectra are recorded.

The average grain size is ≈2 μm with loosely interconnected grains. The average grain size in the sintered pellets remains same with homogeneous grain distribution. The elemental analysis and the chemical uniformity over the surface have been probed using EDAX spectra. The representative EDAX spectra are shown in Figure 2(b) from a section. Similar EDAX signals have been studied from various selected region over the surface. Elemental percentage in BaSnO3 sample are estimated from EDAX using standards SiO2 for O; Sn for Sn and BaF2 for Ba as shown in Table 2. The estimated values of Ba, Sn and oxygen atoms are very close to the stoichiometric composition. There is no significant difference in the elemental percentage obtained from different regions.

3.3. Nature of Phonon Modes

Raman spectroscopic studies of cubic perovskites have been extensively reported and spectral features are understood quite well [43] [44] [45] [46] . In the cubic phase (space group Pm-3 m), group theoretical analysis allows 12 optical modes (3F1u and 1F2u) that are Raman forbidden. Despite the fact that there are no allowed phonons in cubic perovskite phase, reported Raman spectra of BSO show a number of peaks coming from the first order Raman activity [47] . There are contradictory interpretations regarding the origin of these peaks [47] [48] . Recently, we have made an attempt to resolve the controversy and attributed the observed Raman activity due to local structural symmetry change induced by defects in the system [49] . This results into folding of Γ-point of Brillion zone (Zone Centre) into M- and or R-point (zone boundary), as suggested by DFT based calculations also [47] . Thus, Raman spectroscopy could be used to track the local structural changes occurring in the material during processing as first order Raman activity is forbidden in cubic phase. On the other hand, three optical phonons are active in IR viz. TO1, TO2 and TO3; the LO-TO splitting is expected due to ionic character of bonds.

The unpolarised room temperature Raman spectrum for the composition is shown in Figure 3. Raman modes due to BSO are observed at 135 and 241 cm−1. The band appearing at 152 cm−1 is probably due to BaCO3which may be formed if defects are present as reported earlier [50] . Non-observance of higher frequency modes in compositions is due to large background scattering suppressing these modes probably due to the presence of moisture. Appearance of modes

Table 2. Elemental percentage in BaSnO3 sample as estimated from EDAX using standards. Processing options: All elements analyzed (normalized), Number of iterations = 5. Standard: O SiO2; Sn Sn; Ba BaF2.

Figure 3. Room temperature unpolarised Raman spectrum of BSO powder prepared through wet chemical route.

at 135 and 241 cm−1 assigned to BSO means the local symmetry structure is distorted from cubic symmetry.

The room temperature FTIR spectrum of BSO composition in the range 500 cm−1 to 4000 cm−1 is shown in Figure 4. The observed bands are also marked in the figure. The broad band appearing in the O-H stretching range (3000 - 3500 cm−1) as well as those coming from ambient gases (1700 - 2300 cm−1) appears clearly reflecting the presence of moisture in the composition. This may be due to porous nature of sample. The transverse optical modes of BSO in IR appears at 135, 244 and 668 cm−1, whereas corresponding longitudinal phonons are expected at 154, 421 and 723 cm−1 as reported from IR reflectivity data [47] . Based on this, the strong band appearing at 668 cm−1 could be assigned to BSO TO mode. The low frequency modes could not be observed due to experimental limitations in our experiment. Two bands appearing at 865 and 1446 cm−1 could be associated with BaCO3 vibrational modes [51] and indicate the presence of small amount of BaCO3 in the samples below the detection limit of XRD. A shoulder around 421 cm−1 is also visible in compositions assigned to LO mode clearly indicating that the LO-TO splitting is present and local structure is distorted from cubic symmetry as evident from Raman spectra also.

3.4. Optical Properties

The optical (UV-Vis) absorption spectrum for the BSO powder has been measured using Shimadzu UV 1700 Pharma spec spectrophotometer in the absorption mode. The spectrum is shown in Figure 5. Strong absorption bands around 250 nm and 430 nm are mainly due to optical transitions from valence band to conduction band involving O2−: 2p and Sn4+: 5s orbitals. An absorption tail towards NIR region is also observed. Theoretically, for direct band semiconductors, the absorption coefficient follows the relation [52]

α ( h ω ) α h ω E g / h ω (1)

Figure 4. Room temperature FTIR spectrum of BSO powder prepared through wet chemical route.

Figure 5. Optical absorption spectrum of BSO powder prepared through wet chemical route.

This leads to the Tauc relation given as

( α h ν ) 2 = A ( h ν E g ) (2)

Here α is the absorption coefficient, hw is the photon energy, A is a constant. Thus, the optical band gap energy (Eg) can be calculated by plotting the graph between (αhν)2 vs. (hν). Band gap (Eg) can be obtained by extrapolating the linear portion of the plot to the x axis, where (αhν)2 = 0. The Tauc plot is shown in Figure 6(a). The calculated band gap energy is 2.85 eV, which is albeit smaller to those reported earlier [53] . The smaller value of optical band gap in comparison to the known band gap of ≈3.1 eV may be due to local states formation near the band edge. It is well known that band gap measurements using the Tauc plot require the precise determination of absorption coefficient (α) in order to get correct value of band gap. However, for this, it is necessary to perform corrections to the absorption due to reflection. We have therefore, used an alternate procedure called absorption spectra fitting (ASF) to calculate the band gap [54] .


Figure 6. (a) Plot of (αhν)2 vs. hν (Tauc plot (left) and (b) (absorption/λ)2 vs. 1/λ plot used for calculating the optical band gap of BSO powder prepared by wet chemical route. The estimated band gaps are shown in the figures.

The absorption spectra fitting procedure (ASF) has advantage over Tauc plot method as the optical band gap can be determined directly from absorbance data and without having the need to measure the thickness of the sample and is not affected by local states due to disorder.

ASF procedure has been a simple modification of Tauc plot method. This could be done by rewriting Equation (1) as α ( λ ) = A ( h c ) m 1 λ [ 1 λ 1 λ g ] m , and substituting α ( λ ) = 2.303 × A b s ( λ ) d using Beer’s Lambert law gives

A b s ( λ ) = A 1 λ [ 1 λ 1 λ g ] m + A 2 (3)

where A1 and A2 being constants. The value of parameter λg can be obtained by extrapolating the ( A b s λ ) 1 m vs . 1 λ plot linearly at ( A b s λ ) 1 m = 0 . The optical band gap energy (Eg, in electron volt), can be calculated as E g = 1239.83 λ g . The

least square fitting of the absorption data has best fitting for m = 1/2. The plot

( A b s λ ) 1 m vs . 1 λ is shown in Figure 6(b). The value of Eg (2.97 eV) is quite close to the reported values ranging from 3.1 - 3.4 eV.

3.5. Electrical Conductivity and Transport Properties

Figure 7 shows the variation of d. c. electrical conductivity as a function of temperature. DC electrical conductivity increases with increase in temperature for all compositions showing typical semiconductor-like behavior. The observed value of dc electrical conductivity at room temperature is ≈10−3 (Ω×cm)1 which increases and approaches 10−2 (Ω×cm)−1 at 200˚C. The observed high value of DC electrical conductivity approaching to those reported in perovskite electronic conductors [55] .

DC electrical conductivity in n-type semiconductors is generally found to be thermally activated with Arrhenius form. The Arrhenius type plot (logσdc Vs. 1000/T) (Figure 7) show non-linear variation and could be fitted into linear form in different temperature ranges with varying slope. This means that different thermally activated processes operative in different temperature ranges either involve different charge species or charge transport is being governed by hopping rather than being thermally activated. The activation energies are calculated using the relation σ = σ 0 exp ( E a / k T ) where σ0, Ea and k are the pre-exponential factor, activation energy of the mobile charge carriers and

Figure 7. Arrhenius plot for dc electrical conductivity of BSO powder prepared by wet chemical method.

Boltzmann constant respectively. The calculated values of activation energies in different temperature ranges are shown in Table 3. The activation barrier energy varies significantly in different temperature range. It may be noted that the values of activation energies in the temperature range (35˚C - 150˚C), and (150˚C - 200˚C) are 0.08, and 0.44 eV respectively. This means different charge species are involved in the conduction process at low temperatures (35˚C - 150˚C) and high temperatures (150˚C - 200˚C). The typical values of activation energy at least in the lower temperature range are very small than the activation energy required for O2− vacancies (typically 0.5 eV) in the conduction process indicating that oxygen ion vacancies are not involved in dc conduction process up to 150˚C.

It seems that low temperature conductivity mechanism may be Mott-type variable range hopping, whereas, at higher temperature, it may be thermally activated Arrhenius type. To get a clear picture of conductivity mechanism and to understand the transport behavior, the role of electronic structure of the doping becomes crucial [56] . However, in pure material, defects (intrinsic) generated during synthesis may modify Sn structure partially reducing Sn4+ into Sn2+, increasing charge career density and also creating disorder in the octahedral (SnO6) units restricting the long range motion of charge species. Thus, conduction may occur due to hopping of electron between equivalent sites. As per the Mott’s variable range hopping (VRH) model, the electrical conductivity in bulk due to hopping can be expressed as [57]

σ ( T ) = σ 0 exp ( T 0 T ) 1 / 4 (4)

Here T0 is the Mott’s characteristic temperature which depends on density of states in the vicinity of Fermi energy and localization length “a” given as [58]

T 0 = 18 k B N ( E F ) a 3 (5)

The mean hopping distance Rh(T) and hopping energy Eh(T) at a given temperature T could also be estimated in terms of T0 and localization length as given by [59]

Table 3. Calculated activation energies in different temperature ranges using Arrhenius relation.

R h ( T ) = 3 8 a ( T 0 T ) 1 / 4 (6)


E h ( T ) = 1 4 k B T 3 / 4 T 0 1 / 4 (7)

We fitted the temperature dependent dc electrical conductivity data using Mott’s VRH model (Equation (4)) as shown in Figure 8(a). The plots reveal that the range of temperature in which data could be fitted with VRH model is restricted only at higher temperatures. This means that the conduction mechanism is dominantly governed by the disorder induced localization of charges at elevated temperatures.


Figure 8. (a) Plot of temperature dependent DC conductivity data fitted with Mott-Davis small polaron approach. Lines are theoretical fit to Equation (7), and (b) theoretical fit using Mott’s variable range hopping approach, Equation (1).

Some reports have also indicated the role of small polaron in the conduction in alkali earth stannates [60] . A small polaron may be formed when an excess of charge carriers moves slowly and stays at some atomic position so as to allow the coordinate ion to adjust its position due to the presence of the carrier. The conduction may take place by diffusion of electrons at localized sites. In fact, in La-substituted SrSnO3, it is suggested that conduction occurs through low polaron hopping of electrons between localized ions Sn4+/Sn2+.

In order to confirm the nature of hopping conduction, we use Mott-Davis small polaron hopping model [61] which has been found successful in many rare earth transition metal oxide systems at high temperature including Fe-substituted SrSnO3 [62] . According to small polaron hopping, the temperature dependent electrical conductivity can be expressed as

σ T = σ k exp ( E p k B T ) (8)

where Ep is the activation energy, kB is the Boltzmann constant and T is absolute temperature. In order to estimate the polaron hopping energy, we plotted the ln(σT) vs. 1000/T in Figure 8(b). The activation energy is related to polaron hopping energy (WH) and disorder energy (WD) in the temperature range given by [63]

E p = { W H + W D / 2 ( T > θ D / 2 ) W D ( T < θ D / 4 ) (9)

Here θD is Debye temperature. The plot(logsT vs. 1000/T) deviates from straight line at certain value of temperature denoted by θD/2 in Figure 8(b). The slope of high temperature side (above θD/2) has been used to estimate the activation energy of polaron (Ep), which comes out to be 0.08 eV. Analysis clearly reveals that oxygen vacancies are not the dominant defects involved in charge transport and probably protonic type of conduction takes place with small polaron formation being evident at higher temperatures.

3.6. AC Conductivity

Figure 9 shows the frequency variation of ac conductivity (σac) at different temperatures. The ac conductivity was calculated from the impedance data using the relation σ a c = ω ε 0 ε r ( tan δ ) . The conductivity spectra at different temperatures show some typical behavior; no dispersion has been observed in the low frequency range of measurements with almost frequency independent low frequency plateau observed up to 250˚C. However, a. c. conductivity shows significant increase at 300˚C. Further, in the high frequency region dispersion is observed with the conductivity variation becoming non-linear at higher temperature. The frequency independent region shows a general trend; the region shifts towards higher frequency side with increase in temperature. These results indicate the existence of multiple relaxation processes and thermally activated charge species in the materials. The frequency at which change in slope of the of the

Figure 9. Frequency variation of a. c. electrical conductivity at representative temperatures (shown in figure). The lines in each plot are theoretical fit using Jonscher’s universal power law (Equation (7) in the manuscript).

pattern occurs is known as hopping frequency (ωp) suggesting that the electrical conduction occurs via hopping mechanism governed by Jonscher’s power law [64] .

The frequency dependence of a. c. conductivity may arise due to free as well as bound charge carriers. In case of conduction being due to free carriers the conductivity showed decrease with increase in frequency [65] . In our case, a. c. conductivity remains frequency independent and increases with frequency only after a certain frequency; therefore, bound charges trapped in the materials seems to be mainly responsible for conduction. Energy required for the relaxation/orientational process is lower than that required for mobility of charge carriers over a long distance. The observed almost frequency independent ac activation energy at lower frequencies indicates that contribution due to long range charge mobility is insignificant in the material.

The frequency dependence of conductivity is fitted with Jonscher’s power law relation [64] ,

σ ( ω ) = σ d c + A ω n (10)

where σdc is the frequency independent conductivity and the coefficient A and exponent n are temperature and material dependent. The term Aωn contains ac dependence and characterizes all dispersion phenomena. The exponent n show different dependence with temperature in different systems i.e. remains constant, decreasing with temperature, increasing with temperature but always varies between 0 < n < 1. The variation of ac conductivity (σac) with frequency at different temperatures, along with the fitting with Jonscher’s relation, is shown in Figure 9. From the theoretical fit (lines in the plot) it is evident that ac electrical conductivity spectrumobeys Jonscher’s power law at all frequencies; hence electrical conduction of the materials is thermally activated process at these frequencies. According to Jonscher [64] , the origin of the frequency dependent conductivity lies in the motion of mobile charge carriers. When a mobile charge carrier hops to a new site from its original position, it remains in a state of displacement between two potential energy minima. After a sufficiently long time, the defect could relax until the two minima of lattice potential energy coincide with the lattice site.

4. Conclusion

Phase pure BaSnO3 powder has been successfully synthesized using simple wet chemical route. Composition is stabilized in average cubic structure (Pm-3 m). Nature of the vibrational modes in both IR and Raman reveals local symmetry distortion probably due to intrinsic defects generated during synthesis. The optical band gap is 2.95 eV, very close to the reported value. The high value of dc electrical conductivity at room temperature, almost dispersion free and temperature independent nature of a. c. conductivity spectra reflect significant improvement in the electrical behavior of the composition with respect to those reported from conventional solid state route. The conduction mechanism is found to be governed by Mott’s variable range hopping mechanism at lower temperature and thermally activated at elevated temperatures. Small polaron formation also seems to be the possibility at high temperature. Small values of activation energy derived from conductivity data rule out the possibility of oxygen vacancies being involved in dc conduction process.


PKB is thankful to Department of Science & Technology (DST), Govt. of India for providing support under FIST program and the University Grants Commission (UGC), New Delhi for the financial support under SAP program.

Cite this paper

Kurre, R., Bajpai, S. and Bajpai, P.K. (2018) Synthesis, Characterization, Optical and Transport Properties of BaSnO3 Synthesized by Wet Che- mical Route. Materials Sciences and Applications, 9, 92-110.


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