Open Access Library Journal
How to cite this paper: Touset, J.-P. H. (2014) An Approach for Life Cycle Assessment of Electricity Generation at Gas-HFO
Internal Combustion Engines in a Central Station. Open Access Library Journal, 1: e765.
http://dx.doi.org/10.4236/oalib.1100765
An Approach for Life Cycle Assessment
of Electricity Generation at Gas-HFO
Internal Combustion Engines in a
Central Station
Juan-Pedro Hernández Touset1, Jandecy Cabral Leite2, Iván-Leandro Rodríguez Rico1,
Alcimar de Jesus França3, Elena-Rosa Dominguez1, Oiama de Assis Guedes3,
Italo-Jorge Tavares Jimenez2, Arnaldo Herrera Artiles1, Maylier Pérez Gil1
1Universidad Central “Marta Abreu” de Las Villas, Santa Clara, Cuba
2ITEGAM-Instituto de Tecnologia e Educação Galileo da Amazônia, Manaus, Brasil
3Companhia Energética Manauara S.A., Manaus, Brasil
Email: juanpedro@uclv.edu.cu, jandecycabral@hotmail.com, alcimarfranca@utemanauara.com.br
Received 5 July 2014; revised 10 August 2014; accept ed 15 September 2014
Copyright © 2014 by authors and OALib.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
Abstract
This paper applies the Life Cycle Assessment (LCA) as an assessment tool to quantify the environ-
mental impacts associated with electricity generation by internal combustion engines. Steps, re-
sources and/or supplies that have the greatest impacts during the life cycle of electricity generation
are identified to contribute with measures of cleaner production in companies with similar power
generation. The goal of this study is to evaluate the environmental impacts associated with the
production of 1552 kWh of electricity by gas-HFO internal combustion engines, considering a sce-
nario that responds to use of lubricating oil, oily water treatment, collection and transportation of
sludge. The study of additives and contaminants from lubricating oil is included, taking into
account that it is a complex task for life cycle inventory considering limitations to get data. Arising
from the use of the program SimaPro we get that the greatest impact are the lubricating oil use
and transport on respiration of inorganic products and the use of fossil fuels. Most environmental
impacts are concentrated in the use of lubricating oil and transportation.
Keywords
Additives, Internal Combustion Engines, Life Cycle Assessment, Lubricating Oil
Subject Areas: Chemical Engineering & Technology, Environmental Sciences
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1. Introduction
The gas power plants are designed for optimal operation in a wide variety of decentralized energy production,
among these, stationary plants. The motors are designed for continuous operation mode, natural gas or dual fuel
gas and High Fuel Oil.
The company sets its own environmental policy and operates in accordance with the principles of sustainable
development, however, and industrial emissions and waste from maintenance of the engines do not express the
absolute truth of the environmental impacts [1].
The Life Cycle Assessment (LCA) applied at a power plant may have several benefits; its use for assessing
the environmental impact of electricity generation may help to compare types of lubricants and fuels in engines
and to assess lube and wastes impact.
In conventional thermal energy conversion in power plants, impacts connected to constructing the power plant
or manufacturing the equipment are not important for the overall environmental impact of the electricity pro-
duced. A la r ge po rtion of the environmental impact is connected to the production of electricity [2].
Primary life cycle inventory of the different types of lubrica ting oil additives , obtained fro m lab chemica l and
physical analysis is a good tool for assessing the environmental impact of lubricants and wastes. The novelty of
this study lies on the information provided by the lubricating oil composition, sludge and waste water for further
applicat ion of LCA methodol ogy w i t h e xtended b o undaries .
In researching the environmental impact of lubricants, Wissol Autoexpress [3] considered the end of the lu-
bricants life cycle, as the key stage for identifying the problems that may occur during the handling and disposal
of used oil-based lubricants. For the LCA of the studied product, the information of the energy used and emis-
sions generated by the different agents is required, which implies in most cases working with data from different
and not homogeniz e d sources [4].
In this context, LCA methodolog y was applied to examine the role of lubricating oil on electricity generation
and the effect of considering its consumption in process equipments. The present study aimed to contribute to a
better understanding of the influence of material and processes involved at a power plant in the results of LCA.
Based on potential impacts on human health and the environment, re-refining and distillation ar e significantly
better practices than burning used oil as fuel [5]. From the environmental standpoint [6], the collection and sto-
rage of used lubricating oil (with subsequent regeneration of the lubricating oil by catalytic hydrogenation) re-
duces the environmental deterioration as it reduces th e effects of incineration (air emission s) of used lubricating
oil and unc o ntrolle d di s c harge (w a t e r, soil cont a minati on a n d gr oundwat e r).
The functional processes are also a problem for the LCA because not all functional flows are usually part of
the same product system. Thus, a multifunctional process is part of the studied production system and of other
systems too. The challenge is to allocate the environmental impacts of this process to the different multifunc-
tional product systems, i.e. to the different functional flows [7]. The most frequently used methods for solving
this problem are subdivision, system expansion, physical and economic partition and replacement. Several au-
thors have argued that replacement is conceptually equivalent to system expansion [8] [9].
The energy in the form of electricity is an important input into many industrial processes, and as there are
several alternatives for energy production, many LCAs on electricity production have been carried out at nu-
merous institutes and companies throughout the world [10]. This research focuses on lubricating oil subsystem
and the generated electricity as the output product to technosphere. Used lubricating oil su bsystem is not consi-
dered.
On the other hand, taking into consideration the LCA benefits related with the incorporation of different types
of lubricating oil additives , it was necessary to review some important theoretica l views on this topic. The addi-
tives are substances formulated to enhance antifriction properties, chemical and physical properties of base oils
(mineral, synthetic, vegetable or animal) which result in improved performance of the lubricant and so the
equipment life extension. The amount of additives may be up to 30% [11].
The additives have different functions and usually belong to the categories of friction modifiers (Graphite,
Molybdenum Disulfide, Boron Nitride, Tungsten Disulfide, Polytetrafluoroethylene), antiw ear (Zinc Dith iopho-
sphate (ZDP), Zinc Dialkyl Dithiophosphate, Tricresyl), extreme pressure additives (chlorinated paraffins, sulfur
fats, Esters, Zinc Dialkyl Dithiophosphate, Molybdenum Disulfide); rust and corrosion inhibitors (alkaline
compounds, organic acids, esters, amino-acid derivatives ), antioxidants (Zinc Dithiophosphate, alkyl sulfides,
aromatic sulfides, aromatic amines, hindered phenols), detergents (phenolates, sulfonates and phosphonates of
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alkali and alkaline-earth elements such as calcium, magnesium, sodium or barium); dispersants (Polyisobutylene
Succinimides) pour point depressants (Polyalkyl Methacrylate Copolymers ) viscosity index improvers (Poly-
meric Acrylate) and antifoamin g agents (Dimethylsiloxanes).
Raimondi [12] integrates and expands the previous LCAs of oil-based lubricants and also examines the addi-
tives contribution of a fully formulated lubr icant to the environmental im pact. In this case, the additive con tribu-
tion to the life cycle impacts o f commercial lubricating oil was found to be nearly 35% to global warming. The
main sources of data for the LCA were the Boustead Model [13], Ecoinvent [14], European Reference Life
Cycle Database-ELCD [15] and the report IFEU/GEIR [16]. The last one reports that the composition of lubri-
cating oil ca n be 80% of oil-based lubricants (mineral/synthetic), 2% of detergents, 6% dispersants, 9% viscosity
modifiers (olefin copolymers), 1% antioxidant (Zinc Dialkyl Dithiophosphates/Phenols) and 2% antiwear (Zinc
Dialkyl Dithiophosphates). LCA models proposed phases include extraction, transportation and production to
the output of the refinery/fa ctory. The allocation criterion for th e outputs is mass. The main conclusion is th at in
modern lubricants, additives contribution in terms of environmental impact can be significantly high and there-
fore should not be excluded. Ekman and Börjesson [17] admit that in applications where the amount of additives
can be up to 30%, the environmental consequences are significant and ultimately recommend to include addi-
tives in future LCAs.
Since new components of lubricating oils blended with conventional additives are emerging there are not
enough data for the implementation of LCA. On the other hand, manufacturers of additives and lubricants are
extremely conservative and rarely are willing to provide data and information. This paper is structured as fol-
lows. Firstly a critical analysis of the literature on various aspects related to the application of LCA is given.
Then, the elements to be taken into account to define the goal and scope of the study and life cycle inventory for
the environmental impact assessment are suggested, as well as a discussion on the availability and understanding
of the data and the influence of additives on LCA for future research of alternative scenarios in the life cycle of
used lubricating oils and oily wa s tes .
The goal of this study was to assess the environmental impacts of electricity generation by natural gas-High
Fuel Oil internal combustion engines, considering a scenario that responds to use of lubricating oil, oily water
treatment, collection and transportation of sludge. Also the environmental profile of electricity generation sys-
tem is examined using Eco-indicator 99 method to obtain the total contribution of the process for each one of the
impacts categories in correspondence with the study conditions.
2. Materials and Methods
The reason for analyzing the LCA of electricity generation is to provide the power plant with a systematic
framework to identify, quantify, interpret and evaluate the environmental impacts of electricity generation from
internal combustion engines.
2.1. Goals and Scope Definition
The goal of this study is to assess the environmental impacts associated with the production of 1552 kWh of
electricity by gas-HFO internal combustion engines, considering a scenario that responds to the use of lubricat-
ing oils, oily water treatment, collection and transportation of sludge.
As an analytical tool, LCA facilitates the information for decision-making and identification of opportunities
for improvement. The analysis, evaluation and proposals for the application of LCA to lubricating oils are in
corresponde nce with the standards of ISO 14 040, 14041, ISO 14042, and ISO 1404 3.
2.1.1. Function and Description of the Power Plant and the Lubricating Oil System
The power plant has an installed capacity (total power of generation) of 85,380 kW, composed of 5 groups of
Wärtsilä generators with an engine gas/HFO cycle of medium rotation, each of 17,076 kW continuous power at
ISO conditions, at 514 rpm. The gas is carried directly by pipes to the engine hall from the supplier. The plant
operates with a power demand of 63 MW, delivering 525,600 MWh/y of electric power, and consumes 11 310
MWh/year during 8700 h/year and a specific fuel consumption of 209 g/kWh. For engine lubrication the plant
uses Marbrax CCD 430 mineral oil. Figure 1 shows the flowchart of the lubricating system.
The oil is pumped back to the carter through a plate cooler. The centrifugal separator unit keeps the fuel and
lubricant quality by removing water and sludge. 200 liters per day of lubricating oil is restored in the crankcase
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Figure 1. Lubricating oil system.
due to separation of sludge, burning in the engine jacket, saturation of the filter elements and other small losses.
The process water is supplied from a well. The lubricating oil is supplied from a storage tank of 60 m³. In case
of maintenance lubricating oil becomes reusable, and it is pumped to a service tank of 16 m3. A 30 m3 tank
receives used motor lubricating oil. When the tank is full it is discharged into tank trucks of environmental
companies. Figure 2 shows the oily water system. Oily water and sludge generated in the plant are stored in a
box and separated into oily water and sludge. The water is sent to a processing unit by dissolved air flotation
system. The treated water suitably mixed with other flows and effluents is discharged to the environment.
Sludge and HFO (fuel) averaged 1000 kg/d are collected in a tank of 55 m3 and transported to a collector enter-
prise.
2.1.2. Setting System Boundaries
The system boundaries for the case study are in correspondence with those shown in Figure 3 by dashed lines.
Multiple scenarios for lubricating oil treatment can be defined, and therefore the boundaries for the application
of LCA may be different depending on the quality of data available for each option. The system, in general,
starts with the use of lubric ating oil in the internal combustion engines. In the setting boundaries stage, electric-
ity generation is defined as the main system and o il cleaning in the separation unit and the oily water tre atment
is considered a subsystem.
Therefore it is necessary to know the operations of the lubricating system and materials and energy flow be-
tween them. For doing this the process tree is designed and it is represented in Figure 3, which shows the life
cycle model for electricity generat i on used in a p ow er plant .
2.1.3. Allocation Rule of Environmental Loads and Main Assumptions
In the lubrication stage an environmental load distribution is applied as function of mass percent that represents
each output stream of the stage regarding to the total. The environmental load allocation is performed in order to
evaluate the actual impact of the stream involved in the analysis; in the study the allocation criterion is mass.
The main product is the electric energy.
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Figure 2. Diagram of oily water collectio n an d tr eat ment unit.
Figure 3. Process tree.
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The avoided product is considered the mixture sludge/HFO by replacing the use of Diesel in combustion at
industrial plants.
The adopted assumptions during the study are listed below:
-It has been established as a functional unit an amount of 1512 MWh/day.
-Sludge/HFO is considered avoided products, since they avoid the use of equivalent amounts of Diesel for
combustion in industrial plants.
-Exhaust gases are excluded.
-Production of lubricating oil, maintenance and solid waste are not considered, but these may be included in
other studies.
-Systematic chemical analyses for evaluating the oil type and concentration of additives in the databases are
carried out.
-Mass balance results for the lubricating and oily water treatment system are used.
-Impact assessment is carried out without including consumed electricity a t lube oil separators, since electric-
ity is produced by the power plant.
-Transportation of 20 tons of sludge/HFO in tanker trucks, traveling 40 Km every 20 days.
2.2. Life Cycle Inventory
In the lubricating and oily water system, primary data were taken from operating reports, literature and special-
ists’ criteria.
It has been considered that the data meet the quality indicators for a proper interpretation of LCA results and
has been kept in mind: 1) validity of the data (temporary), which correspond to the same year in implementing
the L CA; 2) geographical coverage, where the data correspond to an operating plant; 3) accuracy, since the work
has been done with the extreme value when the data match a range of values and 4) representativeness, since
process-specific database are used, database and referenced literature are also used, considered a mature and
modern technology.
2.3. Life Cycle Impact Assessment
Methodology of Eco-indicator 99 for the assessment of environmental impacts is applied, using the SimaPro 6.0
software. 11 impact categories considered in the Eco-indicator 99 are assessed with weighting based on the hie-
rarchical cultural perspective (Eco-indicator 99 (H) V2.1/Europe EI 99 H/H).
These categories are related with three damage categories (human health, ecosystem quality and resources)
[18]-[22]. Materials, resources and products used in the assessment were taken from Ecoinvent database, devel-
oped by Ecoinvent Center, Swizerland.
2.4. Study Interpretation
The whole system analysis, weak points and better alternatives were determined from the environmental point of
view. As results of the evaluation, the final contribution of the inventory data, the network process, environ-
mental profiles in impact and damage categories in tabular and graphical form were obtained, allowing deter-
mining the stages and most striking system.
3. Results and Discussion
3.1. Analysis of Life Cycle Inventory
In correspondence with SimaPro software, the categories for the inventory data are:
-Inputs from the Ecosphere (natural resources).
-Inputs from Technosphere (products, resources, human activity).
-Outputs to Technosphere (products, by-products).
-Ecosphera Emissions (emissions).
Table 1 shows the results of physical and chemical analyses to th e treated water discharged into the water/so il
[23], where the most significant value is the concentration of oils and fats.
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Table 1. Results of physical and chemical analyses to the treated water discharged into the water/soil (MICRO-LAB, 2012).
Parameters Unit Sample M.P.V.
COD mg O2/L 139.0 N.A.
Total phenols mg C6H5OH/L 0.00 up to 0.5
Phosphorus mg P/L 2.8 N.A.
Nitrate mg N/L 1.4 N.A.
Nitrite mg N/L 0.00 N.A.
Oil and Fats mg /L 17.00 up to 20.0
Dissolved oxyge n mg O2/L 3.1 N.A.
Settleable solids mg/ L <1.00 Up to 1.0
Dissolved solids mg/L 350.00 N.A.
Suspended soli ds mg/L 26.00 N.A.
Sulfites mg S/L 0.47 up to 1.0
Sulfates mg SO4/L 15.00 N.A.
Turbidity NTU 32.00 up to 100.0
Temperature ˚C 31.00 N.A.
M.P.V.: Maximum permissible values by article 16 of resolution CONAMA 430 of May 1 3 , 2011. N.A.: Not applicable.
Lubricating Oil Additives
Due to the absence of specialized literature on the topic and the low availability of primary data, a simplified
methodology is adopted [12] to carry out the LCA considering the impact of the additives in the lubricant and
wastes. It involves:
1) Identification of the category of the additive used in lubricating oil: lubricating oil Marbrax CCD 430 has
antioxidant, anti-corrosion, anti-wear, anti-foam, detergent, dispersant, alkaline reserve agent and pour point de-
pressant [24] (LUBRAX, 2011) and additives to 14% [25];
2) Selection of a representative additive for each category, which can be taken from physical and chemical
analysis results;
3) Identification of the correspondence between the selected additive and the industrial product available in
the database Ecoinvent Data V 1.01 [14].
Figure 4 shows the chemical analysis resu lts to the lubricating oil Marbrax CCD 430 using infrared spectro-
metry with ASTM E2412 FFT version JOAP/Tribolab [26] and Fig ure 5 shows the physical-chemical analysis
results of the lubricating oil using ASTM D6525, atomic emission spectrometry improved by Tribolab, which
determines the wear particle conc entration (Fe, Cr, Sn, Al, Ni, Cu, Pb, Mo), add itives concetration (Ca, Mg, B,
Zn, P, Ba) and contaminants con centration (Si, Na, Va). The last one with low variation bu t of great importance
in diagnoses since it can provide information regarding the composition of the waste oil and sludge.
Corresponding to Figures 4, Figure 5 and Table 1 [23], the information provided by FDSPQ [25] and a
sludge analysis report (HFO) from Intertek [27], Table 3 summarizes the main data and assumptions for addi-
tives, contaminants and wastes. In this analysis a representative additive for each category of additive and con-
taminants is adopted, which subsequently allows identifying the chemical in the software database.
Table 2 shows the concentrations and the amount of additives and contaminants and also the concentration
and amount of oil and grease in wastewater that is discharged into the environment, according to the analysis.
Table 3 reports the results of inventory data of all stages according to the inventory categories. The inputs and
outputs of process stages were inventoried in correspondence to the mass and energy balances, indexes reported
in the literature and previous studies .
3.2. Life Cycle Impact Assessment
In this section results for life cycle inventory assessment previously showed are discussed.
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Figure 4. Infrared spectrometry to marbrax CCD 430 lubricating oil.
Figure 5. Atomic emission spectrometry to marbrax CCD 430 lubricating oil.
3.2.1. Characterization
In Figure 6 the characterization of the system express the percentages (%) each material represents for impact
categories (carcinogenesis, organic compounds respiration, inorganic compounds respiration, climate change,
radiation, ozone layer, ecotoxicity, acid ification/eutrophication, land use, miner als and use of fossil fuels) with-
out considering electric consumption at lubricating oil separators. The contribution of lubricating oil, considered
as an input in the sys tem boundaries established to the LCA is high and the contribution of transport is lower. In
the categories of radiation, ozone layer, ecotoxicity and respiration of organics, lubricating oil contributes in
more than 90% to the environmental impact.
It is logical that the categories with the most impact are ozone layer, radiation, ecotoxicity, and respir ation of
organics and the use of fossil fuels.
3.2.2. Weighting
Materials weighting is analyzed in Figure 7 without considering electric consumption at lubricating oil separa-
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Table 2. Main suppositions and data for LCA at power plant.
Category Per cent
(%) Concentration
(mg/kg) Quantity
(kg/1000 kWh)
ADDITIVES
Oíl-based lubricant 86
Antioxidant (Zinc dialkyldithiophosphate)
14
387 0.0195
Corrosion inhibi tor (Zi nc dialkyldithiophosphate)
Anti-wear
Antifoaming agent
Detergent (Calcium alkylbencesulphonate) 9433 0.475
Dispersant
alkaline reserve agent
pour point depressants
CONTAMINANTS
-
Silica 8 0.0004
Sodium 30 0.015
Vanadium 10 0.005
WASTES
Oil and fats in waste water 17 0.000028
Sludge:
Residual carbon conradson 7.38% p 0.017
Asphaltenes 2.49% p 0.0060
Metals: - -
Vanadium 31.8 0.0000077
Aluminium 485.0 0.000117
Silica 678.0 0.00016
Calcium 2487.0 0.00060
Aluminium + Silica 1163.0 0.00028
Sodium 235.0 0.0000568
Nickel 41.70 0.00001
Iron 28.80 0.0000069
Table 3. Life cycle inventory.
Known outputs to t echnosphere. Products and co-products Amount Unit Quantity Comments
Electric energy 1512 MWh/d Energy Company handbook
Known outputs to technosphe re. Avoided products Amount Unit Distribution
Diesel 0.73 t/d Normal Operating reports
Known inputs from nature (resources) Subcompartment Amount Unit Distribution Comments
Process water 1.652 t/d Normal Operating reports
Air 1.22 m3/d Normal Operating reports
Lubricant oil 0.720 t/d Normal Operating reports
Gas to engines 300 t/d Normal Operating reports
HFO to engines 15.8 t/d Operating reports
Emissions to water Subcompartment Amount Unit Distribution
Hydrocarbons, non specified Water 0.000028 t/d Normal MICRO-LAB, 2012
Water 1.552 t/d Normal Mass balance
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Figure 6. Environmental impacts without considering electric consumption at lubricating oil separators.
Figure 7. Materials weighting on environmental impact categories.
tors. It has been analyzed how each impact category is affected for all the materials involved in the electric gen-
eration. It is noted again th at the biggest impact are the use of lubricating oil and transport on respiration of in-
organic s as well as the us e of fossil fue ls.
3.2.3. Single Score
Figure 8 shows the effect in Pt (impact points) that has the lubricating oil of internal combustion engines,
transportation and damage avoided by reusing HFO and sludge wastes, on the 11 environmental impact catego-
ries. A major influence is on the exhaustion of fossil fuels and respiration of inorganics in lubricating oil and
transport.
4. Conclusions
This study is a contribution in terms of the particularities to be taken into account in the steps of goal and scope
of the study and in the step of life cycle inventory, which is brought to the power plant fundamental characteris-
tics of LCA as an analytical tool for decision-making and the identification of opportunities for improvement.
The contribution to the environ mental impact by materials indicates that the effect of the use of lubricating oil
is minimal.
A reference LCA Model and data for life cycle inventory is apported which can be examened in further
studies.
The impact evaluation of electricity generation system by means of Eco-indicator 99 and SimaPro software
reported beneficial impacts on the carcinogenesis, radiation, ecotoxicity and land use categories, because of the
reduction of emissions to the air, water and land by concept of avoided products.
Most environmental impacts are concentrated in the use of lubricating oil and sludge transportation on respi-
ration of inorga nics and the use of fossil fue ls.
Analyzing 1.51E3 MWh “Produced energy without electricity”; Method: Eco-indicator 99 (H) V2.04 / Europe EI 99 H/H / Characterization
Produced energy without electricityLubricant oil Transport, crude oil pipeline, offshore/OCE S
Diesel, at refinery/RER S
Carcinogens Resp. organicsResp. inorganicsClimate changeRadiation Ozone layerEcotoxicity Acidification
/ EutrophicationLand useMinerals Fossil fuels
%
120
110
100
90
80
70
60
50
40
30
20
10
0
-10
-20
-30
Analyzing 1.51E3 MWh 'Produced energy without electricity'; Method: Eco-indicator 99 (H) V2.04 / Europe EI 99 H/H / W e i gh ting
Produced energy without electricityLubricant oil Transport, crude oil pipeline, offshore/OCES
Diesel, at refinery/RER S
CarcinogensResp. organicsResp. inorganicsClimate changeRadiation Ozone layerEcotoxicity Acidification
/
Eutrophication Land useMinerals Fossil fuels
Pt
30
25
20
15
10
5
0
-5
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Figure 8. Processes effects on impact categories without considering electric consumption at lubricating oil separators.
The application of LCA to lub ricating oils is not only from the operational point of view. The inclusion of ad-
ditives in the LCA is a complex task, considering the limitations in information, however additives inventory
contributes significantly in identifying chemicals in the waste oil and sludge, which have a marked effect on the
environment.
It is recommended for further studies to include Life Cycle Inventory (LCI) data of lubricants in LCAs of
products and services.
LCA methodology is a scientifically based tool to assess the environmental impact generated by the use of
lubricants in internal combustion engines at power plants.
An EIA (Environmental Impact Analysis) has been made to identify and assess possible environmental im-
pacts associated to electricity generation .
The power plant practices good housekeeping and operating practices including inventory control to reduce
the amount of waste.
The power plant does not have significant impacts on the quality and quantity of ground water and the treated
effluent is disposed w ithin the permissible limits o f regulations into the wastewater drainage system.
This work may be taken as a reference for future developments of LCAs on lubricants, considering the inclu-
sion of additives.
The study allows comparing the environmental impacts of processes and materials involved in similar power
plants.
Acknowledgements
Institute of Technology and Education Galileo of Amazonas (ITEGAM) and Manauara Thermoelectric Plant
(UTE Manaua ra), for provi di n g information and financial support for this res e arch.
References
[1] Skrotski, B. and Vopat, W. (1960) Power Station Engineering and Economy. McGraw-Hill Companies, New York,
751 p.
[2] Bai, L. (2012) Life Cycle Assessment of Electricity Generation from Low Temperature Waste Heat. The Influence of
Working Fluid. Department of Energy and Process Engineering, Norwegian University of Science and Technology,
Trondheim.
[3] Wissol Autoexpress (2012) About Lubricants. Online. Accessed: 2012-1-18.
http://www.wissolautoexpress.ge/index.php?eng&cat=91&type=1.
[4] UPC ( 2012) ACV. Estado del conocimiento. 29-41, Online. Accessed 2012-2-3. http://upcommons.upc.edu
[5] Boughton, B. (2004) Environmental Assessment of Used Oil Management Methods. Environmental Science & Tech-
nology, 38, 353-358. http://dx.doi.org/10.1021/es034236p
[6] EPEM (2012) Innovative Collection System and Life Cycle Assessment for Waste Lube Oils. Task 6: Life Cycle As-
sessment—Conclusions. Innovative Collection System and Life Cycle Assessment for Waste Lube Oils LIFE02 ENV/
GR/000360. Online. Accessed 2012-1-10. htt p : //www.epem.gr/icol/pdfs/task_6_a.pdf
J.-P. H. Touset et al.
OALibJ |
DOI:10.4236/oalib.1100765 12 September 2014 | Volume 1 | e
765
[7] Wardenaar, T., et al. (2012) Differences between LCA for analysis and LCA for policy: A Case Study on the Conse-
quences of Allocation Choices in Bio-Energy Policies. The International Journal of Life Cycle Assessment, 17, 1059-
1067. http://www.springeropen.com/journals http://dx.doi.org/10.1007/s11367-012-0431-x
[8] Ekvall, T. and Tillman, A. (1997) Open-Loop Recycling: Criteria for Allocation Procedures. The International Journal
of Life Cycle Assessment, 2, 155-162. http://dx.doi.org/10.1007/BF02978810
[9] Finnveden, G. and Lindfors, L. (1998) Data Quality of Life Cycle Inventory Data—Rules of Thumb. The International
Journal of Life Cycle Assessment, 3, 65-66. http://dx.doi.org/10.1007/BF02978486
[10] WEC (2004) Comparison of Energy Systems Using Life Cycle Assessment. World Energy Council. Accessed: 2013-
4-20.
http://www.worldnuclear.org/uploadedFiles/org/WNA/Publications/Working_Group_Reports/comparison_of_lifecycle
.pdf
[11] Kopelioivich, D. (2012) Additives in Lubricating Oils. (online). http://www.substech.com
[12] Raimondi, A., Girotti, G., Blengini, G.A. and Fino, D. (2012) LCA of Petroleum-Based Lubricants: State of Art and
Inclusion of Additives. The International Journal of Life Cycle Assessment, 17, 987-996. http://www.springerlink.com
http://dx.doi.org/10.1007/s11367-012-0437-4
[13] Boustead Model 5.0 (2005) Operating Manual. Boustead Consulting Ltd., Horsham.
[14] Ecoinvent (2006) Life Cycle Inventories of Chemicals—Ecoinvent Report No. 8. Swiss Centre for Life Cycle Invento-
ries, Zürich and Dübendorf.
[15] European Commission (2010) ELCD Core Database Version II.
[16] Fehrenbach, H. (2005) Ecological and Energetic Assessment of Rerefining Used Oils to Base Oils: Substitution of
Primarily Produced Base Oils Including Semi-Synthetic and Synthetic Compounds. Institut für Energie- und Umwelt-
forschung GmbH (IFEU), a Study Commissioned by GEIR-Groupement Européen de l’Industrie de la Régénération.
[online] http://ec.europa.eu/environment/index_fr.htm
[17] Ekman, A. and Börjesson, P. (2011) Life Cycle Assessment of Mine ral Oil-Based and Vegetable Oil-Based Hydraulic
Fluids Including Comparison of Biocatalytic and Conventional Production Methods. The International Journal of Life
Cycle Assessment, 16, 297-305. http://dx.doi.org/10.1007/s11367-011-0263-0
[18] Contreras, A.M., Rosa, E., Pérez , M., Van Langenhove, H. and Dewulf, J. (2009) Comparative Life Cycle Assessment
of Four Alternatives for Using By-Products of Cane Sugar Production. Journal of Cleaner Production, 17, 772-779.
http://dx.doi.org/10.1016/j.jclepro.2008.12.001
[19] Goedkoop, M. and Spriensma, R. (2001) The Eco-Indicator’99. A Damage Oriented Method for Life Cycle Impact
Assessment, Methodology Report. 3rd Edition, PRé Consultants, Amersfoort. http://www.pre.nl
[20] Pérez, M. (2009) Evaluación ambiental del proceso de cogeneración con bagazo en la Industria Azucarera Cubana
mediante el Análisis del Ciclo de Vida. Tesis presentada en opción al grado científico de Máster, Unive rsidad Central
de Las Villas, Santa Clara.
[21] Pérez, M., Con treras, A.M., et al. (2013) Life Cycle Assessment of the Cogeneration Processes in the Cuban Sugar In-
dustry. Journal of Cleaner Production, 41, 222-231.
http://dx.doi.org/10.1016/j.jclepro.2012.08.006
[22] PRé Consultants (2004) SimaPro End User License Agreement (EULA) and Service Level Agreement (SLA).
http://www.pre.nl
[23] MICROLAB (2012) Relatório analítico RA 173/12. http://www.laboratoriomicrolab.com.br
[24] LUBRAX-PETROBRAS (2011) Ficha técnica MARBRAX CCD.
http://www.br.com.br/wps/wcm/connect/da160d00465086cf8cb8ddffd66dff26/fispq-lub-embarcacoes-marbrax-ccd.pdf
?MOD=AJPERES
[25] FDSPQ (2011) Ficha de Datos de Seguridad de Producto Químico MARBRAX CCD.
http://www.br.com.br/wps/wcm/connect/da160d00465086cf8cb8ddffd66dff26/fispq-lub-embarcacoes-marbrax-ccd.pdf
?MOD=AJPERES
[26] TRIBOLAB (2012) Relatório de exame. Lub: MARBRAX CCD 430/440. http://www.tribolab.com.br
[27] Intertek (2011) Relatório de análise óleo combustível 1A. GERA-Geradora de Energia, Candeias.