
H2 and CH4 Sorption on Cu-BTC Metal Organic Frameworks at Pressures up to 15 MPa and Temperatures
between 273 and 318 K
Copyright © 2011 SciRes. JSEMAT
619-623.
[10] J. Beneyto, F. Suárez-García, D. Lozano-Castelló, D.
Cazorla-Amorós and A. Linares-Solano, “Hydrogen
Storage on Chemically Activated Carbons and Carbon
Nanomaterials at High Press ures,” Carbon, Vol. 45, No. 2,
2007, pp. 293-303. doi:10.1016/j.carbon.2006.09.022
[11] Q. M. Wang, D. Shen, M. Bulow, M. L. Lau, S. Deng, F.
R. Fitch and N. O. Lemcoff, J. Semanscin,
“Metallo-Organic Molecular Sieve for Gas Separation
and Purification,” Microporous and Mesoporous Mate-
rials, Vol. 55, No. 2, 2002, pp. 217-230.
doi:10.1016/S1387-1811(02)00405-5
[12] X. Lin, A. J. Blake, C. Wilson, X. Z. Sun, N. R.
Champness, M. W. George, P. Hubberstey, R. Mokaya
and M. Schroder, “A Porous Framework Polymer Based
on a Zinc(II) 4,4’-Bipyridine-2,6,2‘, 6‘-Tetracarboxylate:
Synthesis, Structure, and ‘Zeolite-Like’ Behavio r s ,”
Journal of American Chemical Society, Vol. 128, No. 33,
2006, pp. 10745-10753. doi:10.1021/ja060946u
[13] J. Senkovska and S. Kaskel, “High Pressure Methane
Adsorption in the M etal-Organic Frame works Cu3(BTC)2,
Zn2(bdc)2dabco, and Cr3F(H2O)2O(bdc)3,” Microporous
and Mesoporous Materials, Vol. 112, No. 1-3, 2008, pp.
108-115. doi:10.1016/j.micromeso.2007.09.016
[14] U. Setzmann and W. Wagner, “A New Equation of State
and Tables of Thermodynamic Properties for Methane
Covering the Range From the Melting Line to 625 K at
pressures up to 1000 MPa,” Journal of Physical and
Chemical Reference Data , Vol. 20, No. 6, 1991, pp.
1061-1155. doi:10.1063/1.555898
[15] R. D. McCarty and V. D Arp , “A New Wide Ran ge Equ-
ation of State for Helium,” Advances in Cryogenic Engi-
neerin g, Vol. 35, 1990, pp. 1465-1475.
[16] Y. Gensterblum, P. van Hemert, P. Billemont, A. Busch,
D. Charriere, D. Li, B. M. Krooss, G. de Weireld, D.
Prinz and K.-H. A. A. Wolf, “European Inter-Laboratory
Comparison of High Pressure CO2 Sorption Isotherms. I:
Activated Carbon ,” Carbon, Vol. 47, No. 13, 2009, pp.
2958-2969. doi:10.1016/j.carbon.2009.06.046
[17] A. L. Goodman, A. Busch, G. Duffy, J. E. Fitzgerald, et
al., “An Inter-laboratory Comparison of CO2 Isotherms
Measured on Argonne Premium Coal Samples,” Energy
and Fuels, Vol. 18, No. 4, 2004, pp. 1175-1182.
doi:10.1021/ef034104h
[18] Y. Gensterblum, P. Van Hemert, P. Billemont, et al.,
“European inter-laboratory comparison of high pressure
CO2 sorption isotherms II: Natural coals,” International
Journal of Coal Geology, Vol. 84, No. 2, 2010, pp.
115-124. doi:10.1016/j.carbon.2009.06.046
[19] A. Busch, Y. Gensterblum, B. M. Krooss and R. Littke,
“Methane and Carbon Dioxide Adsorption-Diffusion Ex-
periments on Coal: An upscaling and Modelling,” Inter-
national Journal of Coal Geology, Vol. 60, No . 2-4, 2004,
pp. 151-168. doi:10.1016/j.coal.2004.05.002
[20] S. Brunauer, P. H. Emmett and E. Teller, “Adsorption of
Gases in Multimolecular Layers,” Journal of American
Chemical Society, Vol. 60, No. 2, 1938, pp. 309-319.
doi:10.1021/ja01269a023
[21] M. M. Dubinin, “Physical Adsorption of Gases and Va-
pors in Micropo res,” Acade mic Press, New York, 1975, p.
1-70.
[22] M. M. Dubinin and V. A. Astakhov, “Description of Ad-
sorption Equilibria of Vapors on Zeolites over Wide
Ranges of Temperature And Pressure,” Advances in
Chemistry, Vol. 102, No. 69, 1971, pp. 65-69.
doi:10.1021/ba-1971-0102.ch044
[23] M. Thommes, B. Smarsly, M. Groenevolt, P. I. Ravi-
kovitch and A.V. Neimark, “Adsorption Hysteresis of
Nitrogen and Argon in Pore Networks and Cha-
racterization of Novel Micro- and Mesoporous Silicas,”
Langmuir, Vol. 22, Vol. 2, 2006, pp. 756-764.
doi:10.1021/la051686h
[24] M. Kramer, U. Schwarzer, S. Kaskel, “Synthesis and
properties of the metal-organic framework Mo3(BTC)2
(TUDMOF-1)” Journal of Material Chemistry, Vol. 16,
2006, pp. 2245-2248. doi:10.1039/b601811d
[25] P. Krawiec, M. Kramer, M. Sabo, R. Kunschke, H. Fröde
and S. Kaskel, “Improved Hydrogen Storage in the
Metal-Organic Framework Cu3(BTC)2” Advanced Engi-
neering Material, Vol. 8, No. 4, 2006, pp. 293-296.
doi:10.1002/adem.200500223
[26] A. R. Millward and O. M. Yaghi, “Metal-Organic
Frameworks with Exceptionally High Capacity for
Storage of Carbon Dioxide at Room Temperature,”
Journal of American Chemical Society, Vol. 127, No. 51,
2005, pp 17 998-17999. doi:10.1021/ja0570032
[27] R. Humayun, D. L. Tomasko, “High-Resolution Adsorp-
Tion Isotherms of Supercritical Carbon Dioxide on Acti-
vated Carb on,” A ICHE Journal, Vol. 46, No. 10, 2000,pp.
2065-2075. doi:10.1002/aic.690461017