Journal of Modern Physics, 2015, 6, 1701-1710
Published Online September 2015 in SciRes. http://www.scirp.org/journal/jmp
http://dx.doi.org/10.4236/jmp.2015.611172
How to cite this paper: Velázquez, G.L. and Cabrera, G.M. (2015) Study of Decoherence of Entangled States Made up of
Two Basic States in a Linear Chain of Three Qubits. Journal of Modern Physics, 6, 1701-1710.
http://dx.doi.org/10.4236/jmp.2015.611172
Study of Decoherence of Entangled States
Made up of Two Basic States in a Linear
Chain of Three Qubits
Gustavo López Velázquez*, Gustavo Montes Cabrera
Departamento de Física, Universidad de Guadalajara, Blvd. Marcelino García Barragan y Calzada Olímpica,
Guadalajara, Mexico
Email: *gulopez@udgserv.cencar.udg.mx
Received 27 May 2015; accepted 26 September 2015; published 29 September 2015
Copyright © 2015 by authors and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
Abstract
Using Lindblad approach to study decoherence of quantum systems, we study the decoherence
and decay of entangled states, formed by two basic states of a chain of thee qubits. We look on
these states for a possible regular dependence on their decay as a function of their energy separa-
tion between the basic states under different types of environments. We didn’t find regular or sig-
nificant dependence on this energy separation for the type of environment considered.
Keywords
Decoherence, Entangled States, Three Quits, Linear Chain
1. Introduction
In the real world (quantum or classical) the interaction of the system with the environment is unavoidable. In
pri nciple, o ne could study t he unitar y evo lution o f the whol e syste m, qua ntum p lus envir onme nt plus qua ntum-
environment interaction, but this represents a many-bodies problem which is unsolvable within any picture of
the quantum mechanics. The most used ap proach t o study this phenomenon is to use the matrix density approach
for the whole system and to make the trace over the environment variables [1]-[5]. The re sultin g densi ty matr ix
is called reduced density matrix, and its associated non-unitary evolution equa tion is call ed master eq uation”.
This equation is pheno menological where dissipati ve and diffusion parameters are de fined, and they are respon-
sible of the decay behavior of the non diagonal elements of the reduced density matrix. This phenomenon is
*
Corresponding author.
G. L. Velázquez, G. M. Cabrera
1702
called decoherencebecause it is related with the disappearance of the interference in terms of the product of
the quantum wave function [6] [7] and many think that this decoherence effect is closely related with the ap-
pearance of the classical world [7]-[9]. In most of the approaches, the positiveness and trace equal to one are
kept as principal condition for the reduced density matrix. The best known mathematical approach which kept
these c ond ition s was gi ven b y Lind blad [10], which ga ve an abstr act ge neral non u nitar y evol ution e quat ion fo r
the reduced density matrix. The master equation is different when dealing with continuous systems (quantum
Browning motion, for example) [1] [2] or discrete quantum systems (spin system) [11]. One of the used ap-
proaches for quantum discrete system is described in [12], and we will use this approach for our study of deco-
herence of entangled states built up with two states of three qubits in a quantum computer model of a linear
chain of three paramagnetic atoms with nuclear spin one half [13]. In this work, we are interested in determining
the decoherence of several entangled states formed by two states of three qubits, and we will use the above men-
tioned Markovian-Lind b lad master type of equation [4] [12]. O n the ot her hand , even this model for sol id state
quantum computer has not been built; it has been very useful for theoretical studies about implementation of
quantum gates and quantum algorithms [13]-[16] which can be extrapolated to other solid state quantum com-
puters. The main idea is to explore the possible sensitivity of the decay of an entangled state with respect to the
energy-difference of its two sta tes involved; we establish four cases to be considered with the quantum-environ-
ment system: indep endent env ironment interactio n, pure dephasing interactio n, cor related dissipatio n interaction,
and dephasing correlated interaction. The analytical dynamical systems of the reduced density matrix elements
are obtained for these cases, and the results of the analytical and numerical simulations are presented.
2. Hamiltonian of the Chain of Nuclear Spins
Follo wing Llo yds idea [17], consider a linear chain of nuclear spin one half, separated by some distance and in-
side a magnetic in a direction z,
( )( )
( )
0
0,0,z Bz=B
, and making and angle
θ
with respect this linear chain.
Choosin g this angle such that
cos1 3
θ
=
, the dipole-dipole interaction is canceled, the Larmores fr equenc y
for each spin is different,
with
γ
th e g yro mag netic ratio. The magnetic moment of the nucleus
k
µ
is related with its spin through t he r e la tion
kk
γ
=S
µ
, and the interaction energy between the magnetic field
and magnetic moments is
( )
z
intkkk k
kk
HBz S
ω
=−⋅=−
∑∑
µ
. If in addition, one has first and second neighbor
Ising interact ion, the Hamiltonian of the system is just [13]
12
12
11 1
22
,
NN N
z zzzz
s kkkkkk
kk k
JJ
HS SSSS
ω
−−
++
= ==
=−−−
∑∑ ∑

(1)
where N is the number of nuclear spins in the chain (or qubits), J and J' ar e the c oup ling c onst ant o f the nucl eus
at first and second neighbor. Using the basis of the register of N-qubits,
{ }
1
,,
N
ξξ
with
0,1
k
ξ
=
, one has
that
( )
12
k
z
kk k
S
ξ
ξξ
= −
. Therefore, the Hamiltonian is diagonal on this basis, and its eigenvalues are
( )( )( )
12
12
11 1
1 11.
22 2
kkk kk
NN N
k
kk k
JJ
E
ξξξ ξξ
ξ
ω
++
−−
++
= ==
=−− −−−−
∑∑ ∑
 
(2)
3. Interaction with the Environment
Consider now that the environment is characterized by a Hamiltonian
e
H
and its interactin g with the quantum
system with Hamiltonian
s
H
. Thus, the total Hamiltonian would be
s e se
HHHH=++
, where
se
H
is the
part of the Hamiltonian which takes into account the interaction system-environment, and the equation one
would need to so lve, in terms of the density matrix, is [18] [19]
[ ]
,,
tt
iH
t
ρρ
=
(3)
where
( )
,
tt
se
ρρ
=
is the density matrix which depends on the system and environment coordinates. The evo-
lution of the system is unitary, but it is not possible to solve this equation. Therefore, under some approxima-
tions and traci ng over the envi ronment c oordinates [5] [20], it is possible to a rrive to a Lindblad type of equatio n
[4] [21] for the reduced density matrix
( )
( )
et
s tr
ρρ
=
,
G. L. Velázquez, G. M. Cabrera
1703
[ ]
† ††
1
11
,22
I
siii iii
i
iHVVV VVV
t
ρρ ρρρ
=

=+−−


(4)
where
i
V
are called Krausoperators. This equation is not unitary and Markovian (without memory of the dy-
namic al p roc ess) . T his eq uati on c an be writ te n in t he i nter ac tio n pict ure, thr ou gh the tra nsfo r matio n
UU
ρρ
=
with
e
s
iH t
U=
, as
( )
,it
ρρ
=
(5)
where
( )
ρ
is the Lindblad operator
( )
† ††
1
11
22
I
iii iii
i
VVV VVV
ρ ρρρ
=

= −−


 
 
(6)
with
V UVU=
. The explicit form of Lindblad operator is determined by the type of environment to consider
[12] at zero temperature. In this work we consider dissipation effects and dephasing. So, the operators can be
ii
VS
=
(for dissipation),
z
ii
VS=
(for dephasing), and
ii
γ
is the coupling constant with the environment.
In this way, one considers the following cases:
1) Independent: In this case, each qubit of the chain acts independently with the environment, and one has
local decoherence of the system. The Lindblad operator is
( )
( )
12
2
N
kk kkkkk
k
S SSSSS
i
ργ ρρρ
− ++−+−
= −−
 

(7)
where
k
S
+
and
k
S
are the ascend and descend operators such that
ˆ
e,
k
it
kk k
SUS US
±Ω
±± ±
= =
(8)
where
ˆ
k
has been defined as
()( )
112 2
ˆ.
zzz z
kkkkkk
JJ
w SSSS
+−+ −
Ω= ++++

(9)
2) Correlated independent: Each qubit interact with the environment but its effect is felt by the other qubits,
that is, the type of interaction is nonlocal with a collective interction between qubits and environment. The
Lindblad operator is
( )
( )
,
12
2
Njk k jjkjk
jk
S SSSSS
i
γ
ρρ ρρ
− ++−+−
= −−
 
(10)
where
jk
γ
are t he co upling co nstant between qubits and environment, with
jk kj
γγ
=
and
ii i
γγ
=
.
3) Dephasing: There is not interchange o f energy bet ween qubits a nd environme nt, only decoherence is pre-
sented where the non diagonal ele ments of the reduced density matrix go to zero. The Lindblad operator is
( )
(
)
12
Nz zzzzz
kkkkkkk
k
S SSSSS
i
ρρ ρρ
=Γ −−
(11)
where
k
Γ
is the parameter of the kth-qubit which take into account the dephasing of the qubit with the envi-
ronment (the tilde operators do not appear due to commutation of this operators with the evolution operator U).
4) Correlated dephasing: Here, one takes into account the collective effect of the environment to the qubits.
Lindblads operator is of the form
( )
( )
,
12,
Nz zzzzz
jkkjjkjk
jk
S SSSSS
i
ρρ ρρ
=Γ −−
(12)
where
jk kj
Γ=Γ
is the parameter with take into account the correlation
( )
ii i
Γ=Γ
.
The analytical solutions for these four c ases are given in the Appendix.
G. L. Velázquez, G. M. Cabrera
1704
4. Entanglement and GME-Concurrence
Our 3-qubits Hilbert space H is generated by the basis
. Labeling the qubit of the 3-qubits chain
as ABC, we understand an entanglement of the form AB when the qubits
{ }
1,2
are entangled, and we under-
stand an e ntanglement of the f orm ABC when the 3-qubits
{ }
1,2,3
are entangled. The entangled state under our
consideration are listed on Table 1 . We chose these state since they are mostly used on experiments of quantum
computation or quantum information.
Table 1. Entangled states ( ordered according t heir en er gy separation ).
Entangled form Initial entangled state
()
2πMHz
E
ABC
( )
18
1 82;Ψ= +
188 1
700E EE∆=−=
( )
27 2 72;Ψ=+
277 2
500E EE∆=−=
( )
36
3 62;Ψ=+
366 3
300E EE∆=−=
( )
45
4 52;Ψ= +
455 4
100E EE∆=−=
AB
( )
17 1 72;
α
= +
177 1
605.2E EE∆=−=
( )
28
2 82;
α
= +
288 2
594.8
E EE∆=−=
( )
46
4 62;
α
= +
466 4
209.8
E EE∆=−=
( )
35 3 52;
α
= +
355 3
195.2
E EE∆ = −=
BC
()
14 142;
β
= +
144 1
305.2E EE∆=−=
( )
58 5 82;
β
= +
588 5
294.8E EE∆=−=
( )
23 2 32;
β
= +
233 2
104.8E EE∆=−=
( )
67
6 72;
β
= +
677 6
95.2E EE∆ =−=
AC
( )
16
1 62;
ξ
= +
166 1
510E EE∆= −=
( )
38 3 82;
ξ
= +
388 3
490E EE∆ =−=
( )
25 2 52;
ξ
= +
255 2
300E EE∆=−=
( )
47
4 72;
ξ
= +
4774 300E EE
∆=−=
In order to quantify the entanglement of a state formed by three qubits basis-states, we will use the criteria
given on [22]-[24] where the lower bound of the concurr ence is
()
{ }
22
GME 1, ,
2
N
C
ββ
β
ρρ
⊗⊗

Φ ≥ΦΠΦ −ΦΠΠΦ


(13)
where
Φ
is a separable state of the two copies of the Hilbert space,
 
.
{ }
α
Π
is the permutation op er-
ator acting on the double copies of the Hilbert space,
 
, inte r c han gi ng e l e me nt s o f one sp ac e i nto the ot h-
er, for example
{ }
( )
121 2121 2
1
φφψψψ φφψ
Π ⊗=⊗
. if
{ }
1
,lmn
ζ
=
,
{ }
,lmn
Π
acting on
rs
Ψ
means that
the qubit label by lis fixed and the qubits label mand nare interchanged (
{ }
1|2,3
18 45Π=
,
{ }
1, 2,3
18 81Π=
). Denoting by
18 18mn
mn
ρ
= ΨΨ
, one has the fallowing GME-concurrence associated to
the given entangled state (Tab l e 2):
G. L. Velázquez, G. M. Cabrera
1705
Table 2. Entanglement form: ABC.
State
Φ
GME-concurrence
18
Ψ
18
1844 5533 662277
22 2 2
ρ ρρ ρρ ρρ
−−−
27
Ψ
27
271188336644 55
22 22
ρρρρρ ρρ
−−−
36
Ψ
36
3611 8822 7744 55
22 22
ρρρρρ ρρ
−−−
45
Ψ
45
4511 8822773366
22 22
ρρρ ρρ ρρ
−−−
For the case when entangled state is of the form AB, BC or AC, one makes the trace on the missing letter qubit,
and it follows that
( )
ijklΦ=
(Table s 3-5)
GME
2
ABAB AB
Cil kjijijkl kl
ρ ρρ
= −
(14)
Table 3. Entanglemet form: AB.
State
Φ
GME-concurrence
17
α
0101
( )( )
172833 44 55 66
22
ρρ ρρρρ
+− ++
28
α
46
α
0011
( )()
35 4611 22 77 88
22
ρρρρρρ
+− ++
35
α
Table 4. Entanglement form: BC.
State
Φ
GME-concurrence
14
β
0101
( )( )
14 5822 66 33 77
22
ρρ ρρρρ
+− ++
58
β
23
β
0011
( )()
23 671155 44 88
22
ρρρρρρ
+− ++
67
β
Table 5. Entanglement form: AC.
State
Φ
GME-concurrence
16
ξ
0101
( )( )
16 382244 55 77
22
ρρ ρρρρ
+− ++
38
ξ
25
ξ
0011
( )()
23471133 6688
22
ρρρρρρ
+− ++
47
ξ
G. L. Velázquez, G. M. Cabrera
1706
5. Results
In our case, we have three qubits space
, and our parameter in units 2π MHz are
123
123 123
12 2313122313
400;200;100;10;0.4
0.05; 0.05; 0.05;0.05;0.05;0.05
0.05;0.025 0.0125;0.05;0.025;0.0125
JJ
ωωω
γγγ
γγ γ
==== =
=== Γ= Γ= Γ=
===Γ= Γ=Γ=
the time is normalized by the same factor of 2π MHz. To determine the departure of the pure state entangled
state, we use the purity parameter,
( )
2
P Tr
ρ
=
[25]. Figure 1(a) shows the behavior of this parameter for the
entangled state
18
Ψ
as a function of time, where one can see that correlations does not affect much t he ind e-
pendent model of the environment, which can be seen only for much bigger dissipation parameters, Figure 1(b).
Dephasing models finish with the mix state on the system a t the end, instead of a pure state of the independent
model. As seen on Figure 2, ind epend ent mo del end s wit h a p ure stat e in t he s ystem d ue to the s ystem end s on
the ground state after sharing energy with the environment.
Let us see now how the GME-conc urrenc e and Purit y beha ve for different entangled state and different envi-
ronments.
Independent Model: For the entangled states listed on Table 1, Figure 3(a), Figure 3 (c) , Figure 4(a ), and
Figure 4(c) show GME-concurrence, and Figure 3(b), Figure 3(d), Figure 4(b), and Figure 4(d) show their
(a) (b)
Figure 1 . Independent model: (a) Purity behavior with 4-models environments; (b) Indepent model with big dissipation.
Figure 2 . Diagonal matrix elements behavior.
G. L. Velázquez, G. M. Cabrera
1707
Figure 3 . Independent: (a), (c) GME-concurrence vs
τ
. (b), (d) Purity vs
τ
.
Figure 4. Independent: (a), (c) GME-concurrence vs
τ
. (b), (d) Purity vs
τ
.
G. L. Velázquez, G. M. Cabrera
1708
associated Purity parameter behavior. The system always finish on the pure ground states
( )
1 000=
, the
lowest bound of the GME-conc urrenc e fall d own ( altho ugh this parameter can not tell us whether or not the en-
tanglement has been completely destroyed). Except for the entangled state
18
Ψ
(maximum entergy difference
between their entangled qubits), there is not clear difference how this entanglement decay is developed. For
example, the entangled states
27
Ψ
,
36
Ψ
,
45
Ψ
have the same GME-concurrence decay behavior, but
these states have different energy-difference on their associated qubits. The entangled states
17
α
and
46
α
the GME-concurrence decay is the same, although their energy-differe nce is q uite big.
Dephasing model: In this case, the GME-concurrence and purity parameters can be expressed explicitly in a
simple form as shown in Table 6 :
Table 6. Exact solution for dephasing model.
Entanglement
( )
GME: ij
C
τ
ϒ
()
ij
P
τ
ϒ
(ABC)
( )()
20exp
ij
ρτ
−Γ
,
( )( )( )()
22 2
0020 exp
ii jjij
ρρ ρτ
+ +−Γ
(AB)
( )()
12
20exp
ij
ρτ
− Γ +Γ


,
( )( )()()
22 2
12
0020exp
ii jjij
ρρ ρτ
++− Γ +Γ


(BC)
( )()
23
20exp
ij
ρτ
− Γ +Γ


,
( )( )( )()
22 2
23
0020 exp
ii jjij
ρρ ρτ
++−Γ+Γ


(AC)
( )()
13
20exp
ij
ρτ
− Γ +Γ


,
( )( )( )()
22 2
13
0020 exp
ii jjij
ρρ ρτ
++− Γ +Γ


where
12 3
Γ=Γ +Γ+Γ
, and
{ }
,,,
ijijijij ij
αβξ
ϒ=Ψ
, for the entangled cases ABC, AB, BC and AC
respectively. This expressions show that the decay behavior is the same for each family of entangled states, that
is, entangled states in the same family have the same decay behavior.
Figure 5 . GME -concurrence for entangled states with the four difference environments.
G. L. Velázquez, G. M. Cabrera
1709
Independent co rr elated: From Figure 1, we saw that correlations have no effect on the purity. In addition,
Figure 5 shows entangled states in different environments where we see that the behavior of the GME-concur-
rence is the same for the independent and independent correlated models.
6. Conclusion
We have studied the decay behavior of entangled states, formed by two basic states of three qubits registers, un-
der fou r di ffer ent environments and using Lindblad type of equation to see whether or not this decay has a regu-
lar dependence with respect to the energy-difference (difference of energy of the two basic states of three qubits
which made up the entangled state) associated to the entangled state. We did not find this regular dependence,
but rather a complicated situation which depends also on the type of environment.
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[24] Ma, Z.-H., Chen, Z.-H., Chen, J.-L., Spengler, C ., Gabr iel, A. and Huber, M. (2011) Phys ical Review A, 83, Article ID:
062325. http://dx.doi.org/10.1103/PhysRevA.83.062325
[25] Nielsen, M. and Chu a ng, I. (2004) Quantum Computation and Quantum Information. Cambrid ge Uni vers ity P r es s,
Cambridge.
G. L. Velázquez, G. M. Cabrera
1710
Appendix
We consider a linear chain of three nuclear spin system. Then, our basis is
, and the eq uat i o ns for
the reduced matrix elements are obtained by making the bracket with these elements of the basis of the equation
(5).
1) Independent:
( )( )
()
2 ,2
e
2mn Nk Nk
i kt
k
mnmnmnk mnmn
kk
kk
t
γ
ρδ ργδρ
−−
∆Ω
++
+=
∑∑
(15)
where we have made the following definitions
( )
22
,1 ,1
,0 ,0
mNknNk
mn
kk
kk
mn
k
αα
αα
δ δδδδ
−−
−−
= +
(16)
( )
,0,0
mn
kk
mn
k
αα
δ δδ
=
(17)
( )
,2,2
.
Nk Nk
mn kn km
k−−
++
∆Ω=Ω− Ω
(18)
2) Correlated independent:
( )()
( )
( )
( )
( )
( )
,
2 ,2
,
,,
22, ,22
2 ,e
2
,e ,e
mn Nk Nk
mn mn
Nl NkNl Nk
i klt
kl
mnmn mn
kl
i klti klt
mn
m nmn
t Nkl
t
kl kl
γ
ρ δρ
δρδ ρ
−−
−− −−
∆Ω
++
′ ′′
∆Ω ∆Ω
−+ −+
=
−−
(19)
where the following definitions have been made
( )( )
,0,0,2,2
,,
m nNkNk
lk
mnmn kn lm
kl kl
αα
δ δδ
−−
++
=∆Ω=Ω−Ω
(20)
( )( )
2
,1,2 2,2
,0
,,
mNlNl NkNl
m
lk
mmn km lm
kl kl
αα
δ δδ
−−− −
−+ −
=∆Ω=Ω− Ω
(21)
( )( )
2
,1,2 2,2
,0
,, .
nNlNl NkNl
n
lk
nmn kn ln
kl kl
αα
δ δδ
−−− −
−+ −
′′
=∆Ω=Ω−Ω
(22)
3) Dephasing:
( )()( )
11
mn
kk
N
mn kmn
k
tt
t
αα
ρρ
+

=Γ− −


(23)
which has the following analytical solutio n
( )()()
0 exp11.
mn
kk
N
mn mnk
k
tt
αα
ρρ
+


=−Γ−−




(24)
4) Correlated depahsing:
()( )( )( )( )
,
21 11
4
mn mm nn
lk lklk
Nkl
mn mn
kl
tt
t
αα αααα
ρρ
+++
Γ

=− −−−−


(25)
which has the e xp lic it so lution
( )()()()()
,
0 exp1121.
4
mm nnmn
lk lklk
Nkl
mn mnkl
tt
αα αααα
ρρ
++ +

Γ
=−−+−− −




(26)