Materials Sciences and Applications
Vol.10 No.04(2019), Article ID:92007,15 pages

Formation of Copper Nickel Bimetallic Nanoalloy Film Using Precursor Inks

Chaitanya G. Mahajan1, Amanda Marotta2, Bruce E. Kahn3, Mark Irving1, Surendra Gupta4, Richard Hailstone5, Scott A. Williams2, Denis Cormier1,3*

1Department of Industrial and Systems Engineering, Rochester Institute of Technology, Rochester, NY, USA

2School of Chemistry and Materials Science, Rochester Institute of Technology, Rochester, NY, USA

3AMPrint Center, Rochester Institute of Technology, Rochester, NY, USA

4Department of Mechanical Engineering, Rochester Institute of Technology, Rochester, NY, USA

5Center for Imaging Science, Rochester Institute of Technology, Rochester, NY, USA

Copyright © 2019 by author(s) and Scientific Research Publishing Inc.

This work is licensed under the Creative Commons Attribution International License (CC BY 4.0).

Received: March 6, 2019; Accepted: April 21, 2019; Published: April 24, 2019


Precursor (Metal-organic decomposition (MOD)) inks are used to fabricate 2D and 3D printed conductive structures directly onto a substrate. By formulating a nanoalloy structure containing multiple metals, the opportunity to modify chemical and physical properties exists. In this paper, a copper-nickel bimetallic nanoalloy film was fabricated by mixing copper and nickel precursor inks and sintering them in vacuum. The individual elemental inks were formulated and characterized using SEM, EDS, and XRD. During thermal processing, elemental copper forms first and is followed by the formation of bimetallic copper-nickel alloy. The encapsulation of the underlying copper by the nickel-rich alloy provides excellent oxidation resistance. No change in film resistance was observed after the film was exposed to an oxygen plasma. Nanoalloy films printed using reactive metallic inks have a variety of important applications involving local control of alloy composition. Examples include facile formation of layered nanostructures, and electrical conductivity with oxidative stability.


Copper-Nickel, Functional Printing, Metal Organic Decomposition, Printed Nanoalloy, Precursor Ink

1. Introduction

Functional printing has evolved from fabricating parts using a single material, to make multifunctional components using two or more materials. There is tremendous interest in functional printing, where different printing techniques [1] are used to make devices such as antennas [2] [3] [4] [5], electrical circuit components [6] [7] [8] [9] [10], and sensors [11] [12] [13] [14]. Metallic inks are often used to fabricate 2D and 3D structures to conduct heat and electricity. Numerous examples of printing of copper [15] - [20] and silver [21] - [26] inks on solid and flexible substrates have been demonstrated in the literature. These inks are either metal nanoparticle or precursor (metal-organic decomposition (MOD) inks. The opportunity to tune the physical and chemical properties of a material could be achieved by mixing several metal inks together to create an alloy. A nanoalloy is a solid state solution containing atoms or molecules of two or more metals [27]. Elements which are immiscible in the bulk form or have a large miscibility gap can be mixed at the nanoscale to produce properties that differ from those of the individual bulk materials [28] [29]. The physical and chemical properties of nanoalloys can be enhanced by varying their structure, composition and particle size to provide properties having applications in biomedical devices, electronics, engineering, and catalysis [30] [31] [32] [33]. It is generally easier to control the structure of nanoalloys using bottom-up synthesis where single atoms or molecules are assembled to form a nanostructure [34]. When using precursor inks, different structures are possible depending on the decomposition profiles, solid loading, and reactivity of individual inks. If the decomposition profiles are identical, then a well-mixed structure is possible. If the decomposition profiles are different, it is possible to synthesize a variety of different structures, for example core-shell structures [35] [36] [37].

In recent years, copper nickel nanoalloys have gained considerable interest in the research community due to the conductivity of copper and the corrosion resistance of nickel. For this reason, they are potential candidates as electrodes in corrosive environments. CuNi alloys are used in marine applications [38], solid oxide fuel cells [39], glucose sensors [40], hydrogenation of refined soybean oil [32], photodegradation of organic dyes [41], and in hyperthermia therapy [42]. Different methods have been used to fabricate CuNi nanoalloy particles. Chemical methods include electrochemistry [40], hydrothermal reduction [41] [43], microemulsions [44] [45], mechanical alloying [30] [46], reduction of polyols [30] [47] or salts [48] [49], and solution combustion [50] [51]. Synthesizing such nanoalloy particles is often accompanied by undesirable contamination in the final composition. For example, impurities from the metal salts may not be completely removed by repeated washing and drying of the nanoparticles. Oxidation is also a problem, requiring special care during washing, filtering and drying of the nanoalloy particles. Printing a precursor nanoalloy ink and directly sintering in situ on the substrate will eliminate some of the problems encountered in the synthesis and use of premade nanoparticles.

The printing of functional devices using nanoalloys is still at a relatively early stage and has not been widely explored. Inks containing nanoalloy particles can be printed using a wide variety of printing techniques to create customized parts for many specific applications. In this work, a nanoalloy precursor ink containing copper and nickel is prepared which can be reduced to a binary alloy of the desired composition. Different characterization techniques such as EDS, TEM, and XRD were used to confirm the formation of nanoalloys. The change in resistivity of the sintered conductive film on exposure to oxygen plasma is reported.

2. Experimental Section

2.1. Materials

All chemicals used were analytical grade. Nickel formate dihydrate (molecular weight (MW): 184.77) and copper formate tetrahydrate (molecular weight (MW): 225.65) were purchased from Alfa Aesar, USA. Ethylene diamine was purchased from Fisher Scientific, USA and ethylene glycol was purchased from Sigma-Aldrich, USA. These chemicals were used without further purification. Glass microscope slides (Thermo Scientific, USA), KaptonÒ film (DuPont USA, 5 mil thick) and single crystal quartz (MTI corporation, USA) were used as substrates and were cleaned with isopropyl alcohol before ink deposition.

2.2. Ink Formulation

To formulate copper precursor (MOD) ink, ethylene glycol (EG) (2 ml) was used as the solvent. Ethylene diamine (ED) (0.36 ml, 5.39 mmol) was used as the ligand and was added to the ethylene glycol. The mixture was stirred at room temperature for 15 minutes. Copper formate tetrahydrate (0.61 g, 2.70 mmol) was added to the solution and stirred at room temperature for one hour. A dark blue color was formed indicating the formation of a copper amine complex. The ink was filtered through a 0.2 µm syringe filter. The nickel precursor (MOD) ink formulation was adapted from the patent published by Ginley et al. [52]. To formulate the nickel ink, ethylene glycol (2 ml) was used as the solvent. Ethylene diamine (0.36 ml, 5.39 mmol) was used as the ligand and added to the ethylene glycol. The mixture was stirred at room temperature for 15 minutes. Nickel formate (0.50 g, 2.70 mmol) was added to the solution and stirred at room temperature for one hour. The ink turned from green to purple indicating the formation of a nickel amine complex. The ink was filtered through a 0.2 µm syringe filter. To formulate the alloy inks, copper and nickel inks were mixed in the desired ratio and stirred at room temperature. The same ligand molecule (ethylene diamine) and carrier solvent (ethylene glycol) were used to prepare the individual inks to avoid immiscibility and solubility issues during mixing.

2.3. Characterization

Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) (Shimadzu DTG-60, Japan) were performed by heating samples in a platinum pan from room temperature to 300˚C at 10˚C/min. For thermal analysis mass spectrometry (TA-MS), 4.0 µl of the ink was placed onto clean glass wool inside of a 0.25 inch OD glass tube. These were then placed into the autosampler tray (Gerstel TDSA, Germany) with the open ends blocked with VitonÒ O-rings. Each tube was individually loaded into the heated chamber at 30˚C, and helium flowed through the tube at 100 ml/min. Effluent from the tube was split, with 1.0 ml/min directed into the mass spectrometer (Agilent 5973, USA) through a heated one meter transfer line. The remainder of the effluent was vented. The sample tube was heated from room temperature to 280˚C at a rate of 10˚C/min. Surface morphology and elemental analysis of the printed films were analyzed using a scanning electron microscope having an energy-dispersive x-ray spectroscopy (EDS) detector (Jeol JSM-IT100LA, USA). The drop cast films were characterized by a RIGAKU DMax-IIB x-ray diffractometer. Transmission electron microscopy (TEM) (Jeol 2010, USA) was used at 200 kV to obtain the SAED pattern for the sintered alloy film. Infrared (IR) spectroscopy (Shimadzu IR Prestige-21 with ATR) was used to analyze the precursor (MOD) inks, ethylene glycol, and ethylene diamine.

To study the effect of oxygen exposure on resistance, the sintered film was exposed to an O2 plasma using a SurFxAtomfloTM 400 atmospheric plasma system. This system generates plasma using a helium-oxygen gas mixture to create an oxidizing environment. The plasma head was mounted on a linear stage to move in X and Y direction. The Z height between the sample and the head was kept constant at 10 mm. For each pass, the power of the plasma was set to 100 W. Helium and oxygen gas flow rates of 15.00 l/min and 0.30 l/min were used.

2.4. Inkjet Printing

The inks were printed onto a substrate using a Fuji Dimatix inkjet printer (DMP 3000). The printer uses a piezoelectric ink cartridge having a single row of 16 nozzles with a drop volume of 10 pl. The print head temperature and the voltage were adjusted for individual inks before printing. For electrical measurements, a solid square film (1 cm × 1 cm) was printed on a glass substrate and sintered in a vacuum furnace.

3. Results and Discussion

3.1. Copper and Nickel Ink Characterization

The copper and nickel precursor (MOD) inks contain the metal formate salts complexed by ethylenediamine. Formate ions were used because of their low molecular weight and volatility [53]. Furthermore, the decomposition of formate is accompanied by the release of carbon dioxide and molecular hydrogen, (Equation (1) & Equation (2)), the latter of which generates a reducing atmosphere, thus limiting the amount of oxidation of the reduced metals [36].

2 HCOO 2 CO 2 + H 2 + 2 e (1)

M 2 + + 2 e M 0 ( M = CuorNi ) (2)

The bidentate ethylenediamine was used in the formation of the metal complex to enhance the reduction efficiency, achieve complex stability, and increase solubility in the solvent. Ethylene glycol was used as a solvent to obtain suitable solubility and rheological properties for inkjet printing. The high boiling point (~198˚C) of ethylene glycol also enables reduction of the complex to metal at elevated temperature.

Figure 1 shows the primary IR absorbance for ethylene glycol, ethylenediamine, and the copper and nickel precursor (MOD) inks. As expected, all of the EG peaks in the ink spectra match those associated with neat EG. EG vibrational transitions in the ink do not exhibit any evidence of metal-EG interactions through vibrational peak damping or significant spectral band shifting. The IR spectra (Figure 1) also confirms that the EDA is directly complexed to the metals as indicated by dampening of the IR frequencies assigned to amine transitions.

Figure 2(A) and Figure 2(B) show the TA-MS results for copper and nickel precursor inks respectively. For both the inks, the thermal decomposition occurs in two stages. The solvent evaporates first, followed by the metal reduction. In the first stage (<130˚C), ethylene glycol and water are released leaving behind the metal complex. The reduction of the copper and nickel precursor inks occur at ~155˚C and ~220˚C respectively. The metal complex decomposition evolves carbon dioxide, carbon monoxide and ethylenediamine, consistent with the reactions in Equation (1) and Equation (2). The final solid loadings of copper and nickel are 6.5% and 4.5% w/w respectively.

Figure 3 shows scanning electron microscopy (SEM) images of the reduced copper and nickel from the precursor inks. The metal deposits are composed of sintered nanoparticles having an average particle size around 500 nm. The size of the particles are dependent on various factors such as the rates of reaction,

Figure 1. IR spectra of ethylene glycol (EG), ethylenediamine (ED), copper ink and nickel ink.

Figure 2. Thermal analysis mass spectrometry (TA-MS) of (A) Cu and (B) Ni precursor inks.

Figure 3. SEM image of (A) copper and (B) nickel film sintered in N2 atmosphere.

nucleation and crystal growth [54]. Small particles can coalesce into larger particles. XRD analysis confirmed the presence of elemental copper and nickel (Figure 4).

Kα1 peak positions were obtained from Pearson type VII peak decomposition [55]. Precise lattice parameter was determined from a plot of lattice parameter versus cos2θ/sinθ [56]. The experimental lattice parameters for copper and nickel were found to be 3.6145 Å and 3.5242 Å respectively. These values are in good agreement with the lattice parameter for pure copper (3.614 Å, PDF# 00-004-0836) and pure nickel (3.524 Å, PDF# 00-004-0850).

Figure 5 shows the differential thermal analysis for copper and nickel inks heated up to 300˚C at 10˚C/min. The reduction of copper and nickel to their elemental states occurs in four stages. The first stage is same for both the inks and includes evaporation of ethylene glycol and water as indicated by the endothermic region below 140˚C. The second stage includes reduction of the metal complex as indicated by the exothermic range up to 155˚C for copper and around 200˚C for nickel. The exothermic ranges for the metals match the TA-MS

Figure 4. X-ray diffraction patterns for reduced copper and nickel films on quartz substrate.

Figure 5. Differential thermal analysis for copper MOD ink and nickel MOD ink at 10˚C/min.

(Figure 2). Nucleation takes place in the third stage. This is indicated by endothermic range from ~160˚C - 180˚C for Cu, and ~195˚C - 230˚C for Ni. Nucleation can be affected by impurities present in the ink and/or substrate. Impurities may inhibit or accelerate the rate of the reactions. The fourth stage is the crystal growth indicated by exothermic ranges > ~180˚C for Cu and ~230˚C for Ni.

3.2. Alloy Characterization

Figure 6 shows a proposed schematic overview of the nanoalloy formation process. The copper and nickel nuclei formed at the beginning of the reduction

Figure 6. Schematic overview of formation of nanoalloy structure onto a substrate.

reaction result in copper-nickel nanoalloy particles. These nanoalloy particles subsequently sinter into a continuous film.

In order to observe the endothermic and exothermic events for the formation of bimetallic film, DTA was carried out for Cu, Ni and CuNi MOD inks at 2˚C/min (Figure 7). As shown above for 10˚C/min, the reduction of the metal complex to elemental metal was observed in four stages (S1 - S4). The first stage (S1, solvent evaporation) was the same for all inks. The copper complex reduces at a lower temperature than nickel due to its lower reduction potential. For the CuNi alloy ink, copper reduces first and provides nucleation sites for nickel which reduces later when the temperature is increased. The endothermic peak for the nickel reduction takes place at a lower temperature suggesting that the presence of copper nanoparticles may catalyze the reaction. DTA data suggests the presence of two phases which are copper and copper nickel alloy. The resulting alloy films have a layered structure with copper reducing first at the substrate and a non-uniform distribution of Cu and Ni atoms (CuNi) alloy on top of the reduced copper.

The EDS elemental mapping (Figure 8(A)) shows no segregation of copper and nickel (within the measurement resolution). The x-ray diffraction pattern in Figure 8(C) shows peaks for both a copper phase and a copper-nickel alloy phase. This corroborates the results obtained from the DTA where copper reduced first and the copper-nickel alloy deposited on the reduced copper. The lattice parameter obtained for the copper peak was 3.6143 Å, and from the copper-nickel alloy peak was 3.5318 Å respectively. Using Vegard’s law, the composition of the alloy phase was estimated to be Cu8Ni92.

Figure 9(A) shows the TEM image of drop casted CuNi film sintered at 2˚C/min in a vacuum furnace. The film was removed from the substrate and placed on the TEM grid for analysis. The nanoparticles and grain boundaries are easily seen. Figure 9(B) shows the electron diffraction pattern obtained from the

Figure 7. Differential thermal analysis for copper MOD ink, nickel MOD ink, and CuNi alloy MOD ink.

Figure 8. (A) EDS elemental maps on samples sintered in a vacuum furnace. (B) EDS spectrum of the sintered sample. (C) X-ray diffraction pattern for sintered film on quartz substrate.

same area shown in Figure 9(A). The d spacing from electron diffraction data was used to calculate the lattice constant and then was averaged over all four lattice constants. The lattice constants obtained from the TEM analysis were not consistent with either a pure copper or pure nickel phase, indicating an alloy formation. Other unresolved ring patterns may be due to impurities, amorphous materials, or formation of small amounts of metal oxides (NiO, CuO or NiCuO).

Figure 9. (A) TEM micrograph and (B) electron diffraction pattern of the alloy film.

To study the effect of oxygen exposure on resistance, the sample was printed with copper, nickel and alloy MOD ink on a glass substrate using an inkjet printing technique. The resistance was measured across the sintered sample after every ten passes of the oxygen plasma. Figure 10 shows the change in relative resistance of the printed film with exposure. As expected, the relative resistance of the sintered copper increased due to oxidization as the number of passes were

Figure 10. Measured change of resistance in printed film on exposure to oxygen plasma.

increased. In contrast, the relative resistance of the nickel and copper nickel alloy samples was not affected by the oxidizing environment. This demonstrated ability of the nanoalloy structure to maintain conductivity in a strongly corrosive or oxidative environment suggests numerous potential applications in electronics.

4. Conclusion

A new method to easily form copper-nickel nanoalloys directly onto a substrate has been shown. The copper and nickel precursor inks were formulated using metal formate salts, ethylenediamine, and ethylene glycol. The reduction process of copper, nickel and combined solutions was studied in detail. XRD analysis of the sintered alloy shows the presence of two phases, copper and bimetallic copper-nickel. Sintering of the alloy ink resulted in the formation of a copper film on the substrate that was encapsulated by nickel-rich copper-nickel alloy. The lattice constant for the sintered alloy was 3.5318 Å, indicating the average composition of the bimetallic alloy to be Cu8Ni92. The relative resistance change was observed for all MOD inks in an oxidizing environment. After several passes of oxygen plasma treatment, the nanoalloy film demonstrated no change in resistivity values, making the copper-nickel nanoalloy film suitable in oxidizing environments. This research enables the creation of complex shapes and functionally graded materials with a variety of stoichiometric ratios by simply mixing individual metal inks in the desired proportions.

Conflicts of Interest

The authors declare no conflicts of interest regarding the publication of this paper.

Cite this paper

Mahajan, C.G., Marotta, A., Kahn, B.E., Irving, M., Gupta, S., Hailstone, R., Williams, S.A. and Cormier, D. (2019) Formation of Copper Nickel Bimetallic Nanoalloy Film Using Precursor Inks. Materials Sciences and Applications, 10, 349-363.


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