Journal of Minerals and Materials Characterization and Engineering, 2012, 11, 965-969
Published Online October 2012 (http://www.SciRP.org/journal/jmmce)
Physico-Chemical Characterization and Speciation of
Sulphur of Nigerian Coal Samples
Folahan A. Adekola*, Alafara A. Baba, Sherifat Buhari
Department of Chemistry, University of Ilorin, Ilorin, Nigeria
Email: *faadekola@yahoo.fr, fadekola@unilorin.edu.ng
Received July 27, 2012; revised August 29, 2012; accepted September 10, 2012
ABSTRACT
Studies of physico-chemical characterization, and chemical speciation of sulphur of seven Nigerian coal samples have
been undertaken. The seven coal samples originated from South-east, North-central and North-east of Nigeria where
there are proven economic deposits of this mineral. Moisture content, bulk density, percentage ash and loss of mass on
ignition of all the coal samples were determined. The ultimate analysis of the raw coal, the corresponding coal ash as
well as sulphur content of all samples were carried out with the aid of X-ray fluorescence technique (XRF). The major
elements were Fe, Ca and S while the minor metals were K, Sc, Zn, Ni, Ti and Zr. Other metals including Ga, Cu, Mn,
Cr and V were found in traces. The Nickel/Vanadium ratio which is a means of providing information on the source
rock depositional environment ranged between 8.8 - 32.9. Three different source rock depositional environments were
deduced for the coals from their nickel/vanadium ratios, while the calculated values of V/(V+Ni) suggested that they
were all formed under oxic condition. The three ch emical species of sulphur, su lph ate, pyritic and organic su lphu r in the
seven coal samples were determined using the ASTM method.
Keywords: Sulphur Speciation; Nigerian Coal; X-Ray Fluorescence Analysis; Heavy Metals
1. Introduction
Coal can be defined as a chemically and physically het-
erogeneous, “combustible”, sedimentary rock consisting
of both organic and inorganic materials. Organically,
coal consists primarily of carb on, hydrogen, and oxygen,
with lesser amounts of sulphur and nitrogen. Inorgani-
cally, coal consists of a diverse range of ash-forming
compounds distributed throughout the coal [1].
Coal is classified into four general categories, or
“ranks”. They range from lignite through subbituminous
and bituminous to anthracite, reflecting the progressive
response of individual deposits of coal to increasing heat
and pressure. The carbon content of coal supplies most of
its heating value, but other factors also influence the
amount of e ner gy it cont ai ns p e r unit of wei g ht [2] .
The sulphur content of coal varies considerably with
the nature and origin of the fossil depo sits [3]. Sulphur in
coal is present in both inorganic and organic forms. The
inorganic sulphur in coal consists predominantly of sul-
phides (pyrite (FeS2), sphalerite (ZnS), galena (PbS),
arsenopyrite (FeAsS) and others) and sulphates (barite
(BaSO4), gypsum (CaSO4·2H2O), anhydrite (CaSO4),
and a number of iron sulphates and others) [4]. Pyrite is
generally the preponderant inorganic sulphur in coal.
Particles of pyrite are randomly distributed as crystals
throughout th e coal but are not bound to it [5].
The organic sulphur in coal is covalently bound into its
large complex structure and is d ifficult to remove ph ysic-
cally or chemically, in contrast to pyritic or inorganic
sulphur [6]. The organic sulphur in coal exists as both
aliphatic and aromatic or heterocyclic forms, which can
be classified into four groups [7]: aliphatic or aromatic
thiols (mercaptans, thiophenols); aliphatic, aromatic, or
mixed sulphides (thioethers); aliphatic, aromatic, or mixed
disulphides (dithioethers) and heterocyclic compounds or
the thiophene type (dibenzothiophenes).
The utilization of co als for both energy productio n and
various coal conversion processes is limited by the pre-
sence of sulphur in the coal. The high sulphur dioxide
emissions caused by the utilization of coals as a major
fossil fuel leads to worldwide environmental problems
[8]. When coal is burnt its sulphur con tent combines with
oxygen to form sulphur dioxide (SO2), which contributes
to both pollution and acid rain [9]. Acid rain resulting
from SO2 has a harmful effect on agriculture and de-
stroys the ecological balance [10]. The presence of sul-
phur in coal also reduces the quality of metallurgical coal
[11,12]. Therefore, it is necessary to remove the mineral
matter and sulphur from coal prior to its utilization.
Nigeria has major coal resources that have not been
*Corresponding author.
Copyright © 2012 SciRes. JMMCE
F. A. ADEKOLA ET AL.
966
well explored or exploited. The coal reserves in Nigeria
are estimated to be in excess of 2.5 billion tonnes and
they are mainly of sub-bituminous type. The government
has prioritized the use of these resources in order to deal
with the country’s power supply problems [13].
Several studies have been carried out on the trace
metal characterization of coals from various locations in
Nigeria using mainly Atomic Absorption spectrometry
(AAS). There has been important underestimation of the
levels of metals due to incomplete wet digestion of the
coal materials on one hand and as a result of limited ca-
pacity of this technique when compared to modern in-
strumental techniques such as XRF. Moreover, most of
the works reported concerned the raw coal samples and
with lack of information on the coals’ ashes residues.
This study has therefore b een conceived with the view of
carrying out comprehensive trace metal analysis of not
only the coal materials but in addition, their correspond-
ing ashes residues.
Furthermore, there is dearth of information on the
chemical forms of sulphur in Nigerian coals which is a
pre-condition for assessing its suitability for use in a
coal-fired plant. The objectives of the present investiga-
tion were therefore to carry out physico-chemical char-
acterization of some Nigerian coal samples, determine
the various chemical forms of sulphur in these coals.
2. Experimental Section
2.1. Sample Collection
All coal samples used were obtained either from the Ni-
gerian Coal Corporation, Enugu or the National Metal-
lurgical Research Centre, Jos, Nigeria. The coal samples
originated from the following seven coal mining fields in
Nigeria:
Onyeama(OYM), Okpara (OKP), Okaba (OKB), Iva
(IVA), Chikila (CKL), Lafia Obi (LFB) and Jankwa Sha-
kodi (JKS).
2.1.1. Sample Pre-Treatment
The selected lumps of coal samples were air-dried and
then pulverized with clean mortar and pestle and sieved
into selected mesh powder. The powdered samples with
particles diameter less than 50 mm were retained for all
investigations.
2.1.2. Physico-chemical ch a racterization of Material s
The physic-chemical parameters analysed for in the coal
samples were moisture content, bulk density, loss of
mass on ignition, ash content, sulphur and metals.
Moisture content was determined by heating to a con-
stant weight using a MINO/53/CLAD oven at a tem-
perature of 105˚C for three hours [14]; The bulk density
of coal samples was determined following a simple dis-
placement procedure based on the Archimede’s principle
[14]; The loss of mass on ignition and the ash content
were determined by heating the sample to constant weight
at 650˚C for three hours in the carbolite ELF 11/148
muffled furnace [14]. The elemental composition of the
coal samples were carried out with the aid of Energy
Dispersive-X-ray fluorescence spectrophotometer (ED-
XRF), Philip’s model 12045 B4/3. The total sulphur in
coal samples was determined with ED-XRF. While Sul-
phate-S and Pyritic-S in the coals were carried out using
standard ASTM methods [15]. Organic sulphur was de-
termined by difference.
3. Results and Discussion
Physico-chemical characteristics of seven different coal
samples from Nigeria are summarized in Table 1.
Chikila coal has the highest moisture content with
value of 7.1% while Jankwa Shankodi has the lowest
moisture content of 1.3%. Onyeama, Okpara and Iva
coals have moisture contents of 2.6%, 3.1% and 4.1%
respectively which are very close to the value of 3.5%
earlier reported by Onwu [16] for Enugu coals.
3.1. Total Elemental Analysis
The results of elemental analysis of the coal obtained
with the aid of ED-XRF are given in Table 2.
It is evident from the ED-XRF results that there is
variation in abundance of various elements in all the coal
samples investigated. In Onyeama coal, sulphur occurred
Table 1. Proximate analysis of Nigerian coal samples.
Samples Moisture content (%) Bulk density (g/cm3) Loss of mass on ign i t i o n (%) Ash content (%)
Onyeama 2.6 0.71 83.7 16.3
Okpara 3.1 0.69 93.4 6.7
Okaba 4.3 0.73 91.0 9.4
Iva 4.1 0.69 93.4 6.7
Chikila 7.1 1.37 75.7 23.4
Lafia obi 1.5 1.29 87.4 12.9
Jankwa shankodi 1.3 1.20 79.9 20.1
Copyright © 2012 SciRes. JMMCE
F. A. ADEKOLA ET AL. 967
Table 2. Sulphur and metals analysis of some Nigerian coal samples.
Element Onyeama Okpara Okaba Iva Chikila Lafia obi Jankwa S.
S (ppm) 3015 ± 249 8614 ± 1414 7002 ± 12042996 ± 2557811 ± 398 3503 ± 28 1 4511 ± 286
K (ppm) 213 ± 12.1 667 ± 73.4 792 ± 76 106 ± 12401 ± 19 185 ± 16 291 ± 20
Ca(ppm) 533 ± 41 9751 ± 100 8201 ± 101.83852 ± 10.21.604 ± 0.01355 ± 41 5966 ± 121
Sc(ppm) 32.8 ± 4.6 1223 ± 176 1061 ± 159 168.9 ± 19.1414 ± 40.3 64.2 ± 11 84 ± 9
Ti (ppm) 784 ± 17.1 15,010 ± 0.03 13,000 ± 0.021559 ± 261342.1 ± 34356.1 ± 15 691.7 ± 21
V(ppm) 8.11 ± 1.7 137 ± 7.81 106.3 ± 7 15 ± 3 15.2 ± 1 9 ± 3 9.1 ± 1
Cr(ppm) 11 ± 1.4 86 ± 8.03 50.6 ± 6.1 13.1 ± 1.121.1 ± 4 14. 9 ± 2 13. 0 1 ± 3
Mn(ppm) 45.81 ± 2.4 130.2 ± 8 86 ± 5.8 155.8 ± 569 ± 3 62.3 ± 2 51.97 ± 3
Fe (%) 7.11 ± 0.051 5.02 ± 0.051 5.585 ± 0.077.771 ± 0.047.1 ± 0.03 9.07 ± 0.04 8.72 ± 0.031
Ni(ppm) 87.1 ± 10 1450.8 ± 69 933.1 ± 53.02149.2 ± 14. 1277 ± 21 296 ± 21 158 ± 17
Cu(ppm) 63 ± 5.2 290.3 ± 21 279.7 ± 18.474.8 ± 6.388.1 ± 5.9 64.9 ± 6.2 81 ± 9
Zn(ppm) 231 ± 17.2 861 ± 55 1081 ± 57 199 ± 18529.93 ± 29463 ± 27 465 ± 27
Ga(ppm) 77 ± 5.6 345.3 ± 25.2 290.8 ± 22 84.01 ± 8.869.2 ± 7 69 ± 6.4 50.6 ± 4.4
Zr(ppm) 178 ± 8 219 ± 21 144.6 ± 17.899.02 ± 942.01 ± 5.1 24.1 ± 4 33.1 ± 5
as the major element, while K, Ca, Ti, Zn and Zr oc-
curred as minor elements and Sc, V, Cr, Mn, Fe, Ni, Cu
and Ga occurred in trace elements. S, Ca, Sc and Ni are
present as major elements while K, V, Mn, Cu, Zn, Ga,
Zr occurred as minor elements and Ti, Ga and Fe oc-
curred as trace elements in Okpara coal. Okaba coal from
Kogi state has S, Ca, Sc, and Zn as major elements while
K, V, Ni, Cu, Ga and Zr occurred as minor elements and
Ti, Cr, Mn and Fe are the trace elements present. In Iva
coal, S, Ca, and Ti occurred as major elements while K,
Sc, Mn, Ni and Zn occurred as minor and V, Cr, Fe, Cu,
Ga and Zr occurred as trace elements.
Chikila has S and Ti as major elements while K, Sc, Ni
and Zn are the minor elements and Ca, V, Cr, Mn, Fe, Cu,
Ga and Z. r are the trace elements present.
Sulphur is the only major element while K, Ca, Ti, Ni
and Zn are present as minor element and Sc, V, Cr, Mn,
Fe, Cu and Ga are present as a trace element in the Lafia
obi coal. In Jankwa shankodi S and Ca are major ele-
ments present while K, Ti, Ni, and Zn are present as the
minor elements and Sc, V, Cr, Mn, Fe, Cu, Ga and Zr are
the trace element present. It is important to no te that sig-
nificantly higher values were measured for all metals
when compared to some previous studies [17-19]. This
could be adduced to the inefficiency of the digestion
procedures adopted by these authors prior to AAS analy-
sis. This was unlike the XRF technique used in th is study
which enabled a direct analysis of solid materials and
thus, avoiding a preliminary acid digestion of coal sam-
ples. It is also worthy of note that some coal samples (Iva,
Okpara, Chikila, Okaba and Onyeama) are very rich in
titanium metal and this could be an indication of pre-
sence of titanium-rich minerals such as TiO2 and FeTiO3
[19,20]. Okaba and Okpara also exhibited high concen-
tration of zinc and nickel. The high concentration of zinc
could be an indication of the presence of sphalerite min-
eral in thess areas [21] In terms of the degree of the ele-
mental analysis using, it is observed that Jankwa Shan-
kodi has the highest total metal concentration (102600.0
ppm) while Onyeama has the least (12,382 ppm). In
terms of degree of mineralization, the results show that
the three coal samples (Chikila, Lafia obi and Jankwa
shankodi) from the northern region of the country are
highly mineralized based on their total metal conten t.
The presence of Vanadium in traces (9.0 - 106.3 ppm)
for all the coal samples is an indication of low maturity
and marine/terrestrial sou r c ed coal [19].
The values of Ni/V ratio are presented in Table 3 and
they range between 8.8 - 32.9. Ni /V ratio has been u sed
by several authors as a means of providing information
on the source rock depositional environment [18,19].
The seven coal types investigated in this work appear
to fall into three distinct groups based on Ni/V ratio.
Onyeama, Okpara, Okaba and Iva coals with lowest and
practically the same Ni/V ratio can be put in the same
group. These coal samples can therefore be considered to
Table 3. The ratios of Ni/V and V/(V+Ni).
Samples Ni/ V V/V+Ni
Onyeama 10.7 0.09
Okpara 10.6 0.09
Okaba 8.8 0.1
Iva 9.9 0.1
Chikila 18.2 0.05
Lafia obi 32.9 0.04
Jankwa shankodi 17.4 0.05
Copyright © 2012 SciRes. JMMCE
F. A. ADEKOLA ET AL.
968
have the same depositional environment.
The second group consists of Chikila and Jankwa
shankodi with Ni/V ratio of almost twice the Ni/V ratio
of the first group would also be considered to the same
depositional enviro nment. And lastly, Lafia obi coal with
Ni/V ratio of 32.9 which is thrice the value of the first
group can be said to have a distinct depositional envi-
ronment.
It is important to mention that the Ni/V ratio calculated
for Onyeama, Okpara and Okaba were much greater than
the value earlier reported [19].
Futhermore V/V + Ni ratios are generally low for all
the coal samples and this suggest that they were all
formed under toxic conditions [19].
3.2. Sulphur and Metal Analysis of Ashes from
Coal Samples
The results of elemental analysis of the ashes of the coal
samples are presented in Table 4.
The coal ash elemental analysis gives the following
concentrations.
Vanadium concentration ranges from 8 to 137 ppm
with an average of 42.71 ppm. Chromium concentration
ranges from 12 to 86 ppm with an average value of 29
ppm. The concentration of manganese ranges between 16
and 154 ppm with an average value of 78.14 ppm and the
highest concentration was found in Iva coal while the
lowest concentration was recorded in Lafia obi coal.
Concentration of Nickel ranges from 86 to 1451 ppm
with the average value of 475.57 ppm; highest concen-
tration of Nickel was recorded in Okpara coal and the
least in Oyeama coal. The concentration of Zinc ranges
between 197 to 1078 ppm with the average of 541 ppm.
Iron concentration ranges from 4.92% to 8.26% with an
average value of 6.93%. It was revealed from this work
that coal beds are very rich source of some metals such
as Ni, Ti, Cu, Fe and Cu. This indicates that the ash resi-
due after burning would be a very good source of these
metals and they can also be used to manufacture some
other chemicals [19].
The sulphur content of the ashes is generally lower
than values measured in the raw coal samples. The va-
lues in the ashes rang e from 2441 - 8247 ppm. The varia-
tion follows same trend as observed for the raw coal
samples. The highest value was recorded for Okpara coal
while the lowest was recorded for Lafia obi coal. The
high level of Sulphur in the ash is an indication of the
predominance of inorg anic Sulphur (Sulphate and Pyritic
Sulphur) in all the coal samples.
The analytical results obtained for the three chemical
forms of sulphur in the coal samples are summarized in
Table 5.
Table 4. Total metal analysis of coal ash.
Elements Onyeama Okpara Okaba Iva Chikila Lafia obi Jankwa shankodi
S (ppm) 2577 ± 222 8247 ± 1372 6476 ± 1157 2841 ± 236 6219 ± 387 2441 ± 256 3325 ± 255
K (ppm) 200 ± 11 660 ± 73 791 ± 76 102 ± 8 3 29 ± 1 9 178 ± 13 285 ± 14
Ca(ppm) 532 ± 40 9749 ± 100 8195 ± 100 3 847 ± 1 00 15,200 ± 0.013 3 8 ± 37 5643 ± 100
Sc(ppm) 33 ± 5 1221 ± 175 1059 ± 158 168 ± 19 413 ± 40 63 ± 11 83 ± 10
Ti (ppm) 784 ± 17 14,200 ± 0.03 1 2,400 ± 0.02 1557 ± 26 1341 ± 32 356 ± 13 691 ± 18
V (ppm) 8 ± 1 137 ± 8 106 ± 7 15 ± 1 15 ± 1 9 ± 1 9 ± 1
Cr (ppm) 10 ± 1 86 ± 8 50 ± 6 13 ± 1 18 ± 2 14 ± 1 12 ± 1
Mn (ppm) 45 ± 2 128 ± 8 85 ± 6 154 ± 3 67 ± 3 16 ± 2 52 ± 2
Fe(%) 8.21 ± 0.03 4.92 ± 0.05 5.50 ± 0. 05 7.76 ± 0. 03 6.22 ± 0.03 8.26 ± 0.04 7.61 ± 0.03
Ni(ppm) 86 ± 8 1451 ± 69 932 ± 53 150 ± 14 275 ± 18 294 ± 18 141 ± 11
Cu(ppm) 51 ± 5 289 ± 19 278 ± 18 74 ± 6 85 ± 6 65 ± 6 72 ± 6
Zn(ppm) 206 ± 16 854 ± 53 1078 ± 57 197 ± 16 528 ± 26 461 ± 25 463 ± 25
Ga(ppm) 75 ± 5 345 ± 25 290 ± 22 83 ± 8 69 ± 7 69 ± 6 50 ± 5
Zr(ppm) 177 ± 8 219 ± 21 144 ± 17 99 ± 9 42 ± 5 24 ± 4 33 ± 4
Table 5. Concentration (%) of various chemical forms of sulphur in Nige rian c oal sample s.
Samples Total sulphur Sulphate-S Pyritic-S Organic-S
Onyeama 0.302 0.082 0.176 0.054
Okpara 0.861 0.469 0.356 0.036
Okaba 0.700 0.337 0.311 0.052
Iva 0.300 0.008 0.276 0.016
Chikila 0.781 0.012 0.610 0.159
Lafia obi 0.350 0.002 0.242 0.106
Jankwa S. 0.451 0.047 0.286 0.118
Copyright © 2012 SciRes. JMMCE
F. A. ADEKOLA ET AL. 969
The results of suphur speciation revealed that pyritic-
sulphur is by far the most important form in Onyeama
(58.2%), Iva (92%), Chikila (78.1%), Lafia obi (69.1%)
and Jankwa shankodi (63.4%) coals. Sulphate-sulphur
constitutes 54.5% and 48.1% of total sulphur in Okpara
and Okaba coals respectively. Organic-sulphur is gener-
ally very low in the coal samples except in Chik ila, Lafia
Obi and Jankwa Shankodi where it constitutes 20.4%,
30.3% and 26.2% of the total suphur respectively.
REFERENCES
[1] B. G. Miller, “Coal Energy Systems,” Elsevier Academic
Press, Burlington, 2005, p. 1.
[2] http://www.ket.org/Trips/Coal/AGSMM/agsmmtypes.htm
l
[3] K. S. Ryoo, J. Choi and Y. P. Hong, “Analysis of Sulfur
in Coal and Coal Desulfurization by Counterflow Oxida-
tive Trea tment, ” Bulletin of the Korean Chemical Society,
Vol. 21, No. 8, 2000, pp. 828-830.
[4] W. H. Calkins, “The Chemical Forms of Sulfur in Coal:
A Review,” Fuel, Vol. 73, No. 4, 1994, pp. 475-484.
doi:10.1016/0016-2361(94)90028-0
[5] W. Wise, “Coal, Water, Fuel Technology,” Workshop US
Departmnet of Energy, Pittsburgh, ETCtr-Report-NO.
BNL 51427. Pittsburgh, 1981.
[6] M. Constanti, J. Giralt and A. Bordons, “Desulphuriza-
tion of Dibenzothiophene by Bacteria,” World Journal of
Microbiology & Biotechnology, Vol. 10, No. 5, 1994, pp.
510-516. doi:10.1007/BF00367655
[7] J. Klein, M. Van Afferden, F. Pfeifer and S. Schacht,
“Microbial Desulfurization of Coal and Oil,” Fuel Proc-
essing Technology, Vol. 40, No. 2-3, 1994, pp. 297-310.
doi:10.1016/0378-3820(94)90152-X
[8] Y. Kadioglu, S. Bayrukceken and M. Gulaboglu, “The
Removal of Organic Sulfur from Two Turkish Lignites
by Chlorinolysis,” Turkish Journal of Chemistry, Vol. 22,
No. 2, 1998, pp. 129-136.
[9] P. Prayuenyong, “Coal Biodesulfurization Processes,”
Songklanakarin Journal of Science and Technology, Vol.
24, No. 3, 2002, pp. 493-507.
[10] S. Ratanakandilok, S. Ngamprasertsith and P. Prasas-
sarakich, “Coal Desulfurization with Methanol/Water and
Methanol/KOH,” Fuel, Vol. 80, No. 13, 2001, pp. 1937-
1942. doi:10.1016/S0016-2361(01)00047-3
[11] A. T. M. Mehliss, “Sulphur in South African Coal,” De-
partment of Mineral and Energy Affairs Report, The Bu-
reau, Johannesburg, 1987.
[12] G. F. Morrison, “Chemical Desulfurization of Coal,” IEA
Coal Research, London, 1981, pp. 43-45.
[13] http://www.tradeinvestnigeria.com/investment_opportunit
ies/724113.html
[14] G. R. Blake and K. H. Hartage, “Bulk Density,” In A.
Klute, Ed., Methods of Soil Analysis, part I, physical and
mineralogical methods. Agronomy monograph, 2nd Edi-
tion, 1986, pp. 363-375.
[15] American Society for Testing and Materials (ASTM),
“Annual Book of Standards, D2492-02,” Standard Test
Methods for Forms of Sulphur in Coal, American Society
for Testing an d Materials, Pennsylvania, 2007.
[16] D. O. Onwu, “Coal Fundamental and Conversion Tech-
nology,” Immaculate Publication, Enugu, 1999, p. 360.
[17] A. Jauro, A. Chigozie and M. B. Nasirudeen, “Determi-
nation of Selected Metals in Coal Samples from La-
fia-Obi and Chikila,” Science World Journal, Vol. 3, No.
2, 2008, pp. 79-81.
[18] A. A. Olajire, A. B. Ameen, M. Abdul-Hameed and F. A.
Adekola, “Occurrence and Distribution of Metals and
Porphyrins in Nigerian coal Minerals,” Journal of Fuel
Chemistry and Technology, Vol. 35, No. 6, 2007, pp.
641-647. doi:10.1016/S1872-5813(08)60001-8
[19] T. A. Adedosu, H. O. Adedosu and F. M. Adebiyi, “Geo-
chemical and Mineralogical Significance of Trace Metals
in Benue through Coal, Nigeria,” Journal of Applied Sci-
ences, Vol. 7, No. 20, 2007, pp. 3101-3105.
doi:10.3923/jas.2007.3101.3105
[20] K. O. Ipinmoroti and A. F. Aiyesanmi, “Trace Metals in
the Bituminous Sands of Ondo State Nigeria,” Nigerian
Journal of Science, Vol. 35, No. 1, 2001, pp. 63-68.
[21] O. A. Ehinola and A. F. Abimbola, “Prelimi Nary Asses-
sement of Major and Trace Elements Content in the Mid-
dle Cretaceous Black Shales of the Abakaliki Fold Belt,
Southeastern Nigeria,” Nafta, Vol. 53, No. 9, 2002, pp.
323-326.
Copyright © 2012 SciRes. JMMCE