Applied Mathematics
Vol.06 No.08(2015), Article ID:58410,17 pages
10.4236/am.2015.68129
Heat and Mass Transfer of Upper Convected Maxwell Fluid Flow with Variable Thermo-Physical Properties over a Horizontal Melting Surface
Kolawole S. Adegbie1, Adeola J. Omowaye1, Akeem B. Disu2, Isaac L. Animasaun1
1Department of Mathematical Sciences, Federal University of Technology, Akure, Nigeria
2School of Science and Technology, National Open University of Nigeria, Lagos, Nigeria
Email: anizakph2007@gmail.com
Copyright © 2015 by authors and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/



Received 31 May 2015; accepted 26 July 2015; published 29 July 2015
ABSTRACT
The objective of this article is to present the dynamics of an Upper Convected Maxwell (UCM) fluid flow with heat and mass transfer over a melting surface. The influence of melting heat transfer, thermal and solutal stratification are properly accounted for by modifying the classical boundary conditions of temperature and concentration respectively. It is assumed that the ratio of inertia forces to viscous forces is high enough for boundary layer approximation to be valid. The corresponding influence of exponential space dependent internal heat source on viscosity and thermal conductivity of UCM is properly considered. The dynamic viscosity and thermal conductivity of UCM are temperature dependent. Classical temperature dependent viscosity and thermal conductivity models were modified to suit the case of both melting heat transfer and thermal stratification. The governing non-linear partial differential equations describing the problem are reduced to a system of nonlinear ordinary differential equations using similarity transformations and completed the solution numerically using the Runge-Kutta method along with shooting technique. For accurate and correct analysis of the effect of variable viscosity on fluid flow in which (Tw or Tm)
Keywords:
Melting Heat Transfer, Viscoelastic Fluid, Variable Viscosity, Solutal Stratification

1. Introduction
Mass transfer can be described as the movement of mass (material) through a fluid-fluid interface or a fluid-solid interface. The term “mass transfer” is commonly used in engineering and in industry for physical processes that involve diffusive and convective transport of chemical species within physical systems. The three kinds of fluxes in relation to mass transfer have been explained in Asano [1] ; Mass flux can be expressed as the addition of diffusional flux and convective mass flux. The analysis, description, theoretical and experimental studies of boundary layer flow together with heat and mass transfer across incompressible fluid as it flows over ahorizontal surface has gained attention of many researchers. In addition, series of investigations have been carried out towards the understanding of the dynamics of viscoelastic material since the contribution of James Clerk Maxwell in 1867 to the body of knowledge. The dynamics of material having the properties of elasticity and viscosity when undergoing deformation is a fundamental topic in fluid dynamics. This kind of material referred to as “Maxwell fluid” has attracted the attention of many researchers due to its wide industrial and technical applications. James Clerk Maxwell proposed Maxwell fluid in 1867 and the knowledge was popularized by James G. Oldroyd few years after (for details see Christopher [2] ). The Upper Convected Maxwell model can be described as the generalization of the Maxwell material for the case of large deformation using the upper- convected time derivative (also known as Oldyrold derivative) which is the rate of change of some tensor properties of a small parcel of fluid that is written in the coordinate system stretching with the fluid. It is worth noticing that mathematical model of Upper Convected Maxwell has been described (or defined) as a function of stress tensor, relaxation time, upper convected time derivative of stress tensor, fluid velocity, material viscosity at steady simple shear and tensor of the deformation rate.
It is a common known fact in rheology that given enough time, even a solid-like material will flow (see Barnes et al. [3] ). In view of this, it is required to characterize the fluidity of materials under specific flow conditions (i.e. adimensionless number that incorporates both the elasticity and viscosity of material is required). Steffe [4] reported that Deborah number which is defined as a ratio of stress relaxation time (i.e. time it takes for a material to adjust) to applied stresses (deformations) was proposed by Eugene C. Bingham and Markus Reiner. Recently, Poole [5] reported the history behind the given name “Deborah” according to Reiner [6] as a ratio of time of relaxation to time of observation. In view of this, Sadeghy et al. [7] investigated Sakiad is flow of a UCM fluid. The role played by a fluid’s elasticity on the characteristics of its Sakiadis flow was analyzed. In the same context, it was reported that at high Deborah number, UCM flow corresponds to solid-like behavior and low Deborah numbers to fluid-like behavior. Recently, Shateyi et al. [8] investigated entropy generation on a magnetohydrodynamic flow and heat transfer of a Maxwell fluid over a stretching sheet in a Darcian porous medium. In the article, a new numerical scheme (Chebyshev Spectral Collocation Method) is adopted to solve nonlinear systems of boundary value problems. Considering some rheological complex fluids such as polymer solutions, blood, ice creams and synovia fluid, Abbas et al. [9] argued that the second-grade fluid model adopted in the work of Fosdick and Rajagopal [10] does not give reasonable results for flows of highly elastic fluids (polymer melts) that occur at high Deborah number. Forsuch situations the Upper Convected Maxwell (UCM) model is quite appropriate. Using the UCM model, MHD boundary layer flow of a UCM fluid in a rectangular porous channel was successfully investigated. The study on dynamics of Upper Convected Maxwell fluid is extended in Hayat et al. [11] and reported that boundary layer thickness decreases by increasing the magnitude of MHD parameter, suction/injection velocity parameter and relaxation time parameter. In recent years, many researchers has investigated and reported the effect of some parameters on Upper Convected Maxwell fluid flow [12] - [22] .
Internal energy generation can be explained as a scientific method of generating heat energy within a body by chemical, electrical or nuclear process. Natural convection induced by internal heat generation is a common phenomenon in nature. Crepeau and Clarksean [23] have reported a similarity solution of a fluid problem along a vertical plate with constant temperature in the presence of an exponential decaying heat generation term under the assumption that the fluid has an internal volumetric heat generation. In many situations, there may be appreciable temperature difference between the surface and the ambient fluid. This necessitates the consideration of temperature dependent heat source(s) that may exert a strong influence on the heat transfer characteristics (see Salem and El-Aziz [24] ). Salem and El-Aziz [25] further stated that exact modeling of internal heat generation or absorption is quite difficult and argued that some simple mathematical models can express its average behavior for most physical situations. Recently, Animasaun et al. [26] reported that when the plastic dynamic viscosity and thermal conductivity of non-Newtonian Casson fluid are considered as temperature dependent, exponentially decaying internal heat generation parameter is an important dimensionless number that can be used to increase velocity and temperature of the fluid as it flows. Effect of this internally generated heat energy on the
surface may lead to melting of solid surface. From the knowledge of kinetic theory of matter, some solids may melt if expose to a high temperature. In an earlier study, the effect of melting on heat transfer was studied by Yin-Chao and Tien [27] for the Leveque problem. The tangential velocity profile is assumed to be linear. It was further reported by Tien and Yen [28] that the approximation in [27] is valid if one deals with a high Prandtl number fluid so that the significant temperature change takes place only within a thin layer of fluid immediately adjacent to the solid boundary and consequently the velocity profile inside this thin layer can be approximated by a linear segment. The similarity between the melting problems and mass transfer or transpiration cooling problems is further explained in [28] . In addition, effect of melting on heat transfer between melting body and surrounding fluid qualitatively from the point of view of boundary layer theory was investigated. This contribution to the existing knowledge attracted Epstein [29] to present a note on a systematic method of calculating steady state melting rates in all circumstances involving the melting of solid bodies immersed in streams of warmer fluid of the same material. In the same context, relationship between boundary condition of evaporation and that of melting is discussed. In recent years, many researchers have investigated and reported the effect of melting parameters; for details see [30] - [32] .
In all of the above mentioned studies, fluid viscosity and thermal conductivity have been assumed to be constant function of temperature within the boundary layer. However, it is known that physical properties of the fluid may change significantly when expose to internal generated temperature. For lubricating fluids, heat generated by the internal friction and the corresponding rise in temperature affect the viscosity of the fluid and so the fluid viscosity can no longer be assumed constant. In a case of melting as reported by many researchers [30] - [33] , it is worth mentioning that temperature of fluid layers at free stream may also have significant effect on the intermolecular forces of upper convected Maxwell fluid. The increase of temperature may also leads to a local increase in the transport phenomena by reducing the viscosity across the momentum boundary layer and so the heat transfer rate at the wall may also be affected greatly. According to Batchelor [34] , Animasaun [35] and Meyers et al. [36] , it is a well-known fact that properties which are most sensitive to temperature rise are viscosity and thermal conductivity. Recently, Mukhopadhyay [37] considered this same fact in order to explain stagnation point flow behavior on non-melting surface while Animasaun [38] adopted the model and reported the dynamics of unsteady magnetohydrodynamic convective fluid flow with radiation and thermophoresis of particles past a vertical porous plate moving through a binary mixture in an optically thin environment. Motivated by all the works mentioned above, it is of interest to contribute to the body of knowledge by studying the dynamics of upper-convected Maxwell fluid flow considering a case in which the influence of temperature on viscosity and thermal conductivity is properly accounted for. In this study, we aim at investigating the motion of UCM fluid flow over a melting surface; considering a case in which the flow is subjected to thermal and solutal stratification. This is achieved by modifying and incorporating all the necessary term (s) into the boundary layer equation in line with boundary layer theory, heat and mass transfer theory. Lastly, to extend the research of Hayat et al. [39] , Mustafa et al. [17] , Pop et al. [30] , and Prasad et al. [21] .
2. Mathematical Formulation
We consider steady and incompressible Upper Convected Maxwell (UCM) fluid flow with variable thermo- physical properties over a melting surface situated in hot environment. The flow under consideration is assumed to occupy the domain
as shown in Figure 1. Boundary layer equations which best describe Upper Convected Maxwell fluid flow can be derived starting from Cauchy equations of motion. Following (Dunn and Rajagopal [40] and Sadeghy et al. [7] ), steady two-dimensional fluid flow can be written as
(1)
(2)
(3)
Figure 1. Physiwcal configuration.
where
is the density of the steady Upper Convected Maxwell fluid. Poole [5] explained that in steady simples hear flow (SSSF), the dominant elastic force will be due to the first normal-stress difference (
,
) and the viscous force is simply the shear stress (
).
In Equation (2) and Equation (3), elastic terms are
and
. The viscous terms are
and
.
Using order of magnitude as introduced by Ludwig Prandtl and stated in Schichting [41] , it is valid to say that
(4)
and easy to show that in Equations (2) and (3), order of magnitude of the two elastic terms and order of magnitude of the two viscous terms are the same if
(5)
This condition can be explained following Sadeghy et al. [7] . Elastic effects should be considered in aboundary layer only for those viscoelastic fluids for which
is of an order larger than 



In the presence of pressure gradient, the equations of motions together with continuity equation can be written as


In Equation (8) and Equation (9), there exist five unknowns (i.e. five dependent variables) which are u, v, 




The time derivative 
has been devised to satisfy the requirements of continuum mechanics (i.e., material objectivity and frame in difference; see Larson [42] ) and 

In Equation (11), 
This can be differentiated and used to eliminate the pressure gradient Lienhard-IV and Lienhard-V [43]
Since the flow is along flat horizontal melting plate, 



In this study on Maxwell fluid flow, it is assumed that the normal stress is of the same order of magnitude as that of the shear stress in addition to the usual boundary layer approximation for deriving the component of the
momentum boundary layer Equation (12). This is properly accounted for by introducing 
momentum Equation (12); for details, see Motsa et al. [18] . In this present study, it is important to state that exponential heat source is adopted to account for internal distribution of temperature in energy equation. This con- cept can be traced to the idea of Crepeau and Clarksean [23] , Salem and El-Aziz [24] [25] , Animasaun et al. [26] and Animasaun [44] . The energy and concentration equations can be written as


Equations (8), (12), (13) and (14) are subject to the following boundary conditions


κ is the thermal conductivity, 




The classical models in Equation (17) are valid when

It is worth mentioning that the first and fourth terms of Equation (18) are valid since
In this study, the idea of Vimala and Loganthan [47] and Animasaun [44] is followed to define thermal stratification





From these models, it is valid to write the relation of the form






Upon using Equation (18) - Equation (22), we obtain


In order to write the governing equations and the boundary conditions in dimensionless form, the following non-dimensional quantities are introduced,

It is important to note that the first two terms of Equation (25) automatically satisfy continuity Equation (8). Then, Equation (23) and Equation (24) becomes



The corresponding boundary conditions take the form


Here dimensionless viscoelastic parameter (Deborah number)





and melting parameter
tion coefficient 



where the wall skin friction



Using Equation (25)

the local Reynolds number is defined as
3. Method of Solution
Numerical solutions of the ordinary differential Equation (26) - Equation (28) with the Neumann boundary conditions Equation (29) and Equation (30) are obtained using classical Runge-Kutta method with shooting techniques. The BVP can not be solved on an infinite interval, and it would be impractical to solve it for even a very large finite interval. In this study, we impose the infinite boundary condition at a finite point











The calculated values for













Verification of the Results
In order to verify the accuracy of the present analysis, the results of Classical Runge-Kutta together with shooting (RK4SM) have been compared with that of bvp4c for the limiting cases when





4. Discussion of Results
The numerical computations have been carried out for various values of temperature dependent viscous parameter, thermal stratification parameter, solutal stratification parameter, Deborah number, magnetic field parameter, temperature dependent thermal conductivity parameter, Schmidt number, Prandtl number, space dependent heat source parameter, intensity of heat distribution on space parameter and melting parameter using numerical scheme discussed in the previous section. To avoid any corresponding effect(s) on the fluid flow (i.e. decrease in the volume and changing of state) of UCM due to high temperature when investigating the effect of dimensionless temperature dependent viscous and thermal conductivity parameters, variable “a1 = a2” in Equations (26) and (27) have been considered as unity. In order to illustrate the results graphically, the numerical values are plotted in Figures 2-14. Table 1 provides the numerical value of skin friction coefficients, reduced Nusselt numbers 









Figure 2 and Figure 3 illustrate the influence of solutal stratification parameter on the concentration and
Table 1. Comparison of





Figure 2. Concentration profiles 

Figure 3. Concentration gradient profiles 

Figure 4. Temperature profiles 

Figure 5. Temperature gradient profiles 

Figure 6. Velocity profiles 

Figure 7. Transverse velocity profiles 

Figure 8. Sheer stress profiles 

Figure 9. Concentration profiles 

Figure 10. Concentration gradient profiles 

Figure 11. Transverse velocity profiles 

Figure 12. Velocity profiles 

Figure 13. Temperature profiles 

Figure 14. Sherwood number 


concentration gradient profiles. The effect of 















The variations of temperature profiles 







In this study, setting m = 0 can seriously affect the melting processes at the wall. In addition to this fact, existence of melting at the wall together with an increase in thermal stratification parameter depicts anegligible increase in longitudinal velocity and significant increase in transverse velocity (see Figure 6 and Figure 7). As temperature decreases due to an increase in thermal stratification parameter, velocity profile is expected to decrease as reported in [44] . It is worth noticing that such effect exists due to the presence of suction and the kind of fluid under consideration (Casson fluid). In this research, mathematical model which denotemelting heat transfer has replaced the suction at the wall. It is worth noticing that the result we obtained here is in good agreement with that of Figure 6 reported in [32] .
We believe that this influence requires further investigation by replacing melting heat transfer model with suction model (i.e. to study the effect of suction on UCM fluid with variable thermo-physical properties subject to thermal and solutal stratification). It is also important to report that the influence of free stream temperature together with internal exponential heat source account for the increase in velocity and transverse velocity of UCM as it flows. In fact, these influences totally subdues the effect of increasing stratification which ought to decrease velocity profiles as reported in [44] . Figure 8 shows that the shear stress profile increases near the melting surface with an increase in thermal stratification parameter. Opposite effect is observed near free stream (η = 4). Figure 9 and Figure 10 illustrate the effect of thermal stratification parameter on the concentration of UCM fluid flow over melting surface towards thermal stratified environment. It is seen that the concentration increases negligibly with






Hence, this increase in temperature weakens the intermolecular forces which hold the molecule of UCM so tight. In view of this, the dynamic viscosity is gradually reduced and corresponds to increase in velocity as shown in Figure 11 and Figure 12. It is further observed in Figure 12 that increases in the magnitude of temperature dependent viscous parameter has negligible effect on velocity profiles near the free stream. Physically, the temperature of UCM near the hot environment (upper layers at the free stream) is almost the same. In such a situation, the flow velocity approaches to the maximum value. In this study, it is important to note that increase in the temperature dependent thermal conductivity parameter (ε) at a constant value of δ corresponds to an increase in temperature difference











5. Conclusion
Similarity solutions of steady UCM fluid flow over a melting surface; considering a case in which the flow is subjected to thermal and solutal stratification have been studied theoretically. The corresponding influence of thermal stratification, solutal stratification, variation in viscosity and thermal conductivity due to temperature is properly considered. The governing (dimensional) partial differential equations are converted into (dimensionless) nonlinear ordinary differential equations by using similarity transformation before being solved numerically using fourth order Runge-Kutta integration scheme along with shooting techniques. Results for the skin friction coefficient, local Nusselt number, local Sherwood number, transverse velocity profiles, velocity profiles, temperature profiles as well as concentration profiles are presented for different values of the pertinent parameters. Effects of Prandtl number, the melting parameter, temperature dependent viscous parameter, temperature dependent thermal conductivity parameter, solutal and thermal stratification on the flow and heat transfer characteristics are thoroughly examined. For accurate and correct analysis of fluid flow in which (


Table 2. Influence of startification parameter 










conductivity is to be investigated; the term 





Conflict of Interests
Authors declare that there is no conflict of interests regarding the publication of this paper.
Acknowledgements
The authors wish to express their thanks to the anonymous Reviewer for his/her valuable and interesting comments.
Cite this paper
Kolawole S.Adegbie,Adeola J.Omowaye,Akeem B.Disu,Isaac L.Animasaun, (2015) Heat and Mass Transfer of Upper Convected Maxwell Fluid Flow with Variable Thermo-Physical Properties over a Horizontal Melting Surface. Applied Mathematics,06,1362-1379. doi: 10.4236/am.2015.68129
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