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Journal of Minerals & Materials Characterization & Engineering, Vol. 7, No.2, pp 147-161, 2008
jmmce.org Printed in the USA. All rights reserved
Studies of The Mechanism of Polyvinyl Alcohol Adsorption on The
Calcite/Water Interface in The Presence of Sodium Oleate
Department of chemistry, Faculty of sciences, University of the sciences and technology
of Oran (U.S.T.O.MB), BP-1505 Oran El-M’naouer (31000), Algeria
Laboratoire d'Etude des Matériaux Organiques LEMO, Faculté des Sciences-
Département de chimie Université de Batna, 05000, Algerie
*E-mail: firstname.lastname@example.org, Tel /Fax : (213)41.56.03.00
The adsorption behavior of polyvinyl alcohol (PVA) on the CaCO
under the influence of sodium oleate (SOl) interaction was investigated by the adsorbed
amount, FTIR spectra, X-Ray diffraction and zeta potential. Effects of solid to liquid
ratio and temperature was also examined. Observed increase of the PVA adsorption in
presence of the sodium oleate resulted from a polymer-surfactant complex formation. The
surfactant also influences on the structure of the adsorbed polymer layers. This effect was
proved by adsorption measurements that allow calculation of the thickness of the
adsorbed layer of the polymer on the surface of CaCO
in the presence and the absence
of sodium oleate. The interaction between oleate anions and PVA is a physical type (via
Key Words: Adsorption; Polyvinyl alcohol (PVA) ; Sodium oleate; Calcite ; Polymer-
Interaction between polymers and particles surfaces are widespread and of great
industrial and technological significance For instance, the flocculation of colloidal
particles by the introduction of a polymer into the liquid suspensions is an important
solid-/liquid separation process in various industrial and technological processes, mineral
processing, municipal water and waste water treatments, etc. [1-3]. Adsorption of
polymers at the solid-solution interface has profound effects on the flocculation and
148 N.S. LABIDI
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stabilization behavior of colloidal suspensions. For charged polymer-adsorbent systems,
mainly strong electrostatic interaction works and influences adsorption according to their
charges. For uncharged polymers, only H-bonding and solvation forces are important.
Although the adsorption behavior of PVA polymer on solid-liquid interface are well
documented in literature, the amount adsorbed is strongly dependent on the molecular
weight and the number of acetate groups of PVA, resulting in different adsorption layer
thickness. The adsorption force increases with increasing degree of hydrolysis of PVA.
The presence of the hydrophobic acetate groups also affects the conformation of polymer
chains adsorbed on the particle surface [4-7]. The adsorption mechanisms of PVA on
different types of particles are also varied. For example, the amount adsorbed on TiO
increases with the suspension pH as the thickness of the double-layer surrounding the
particle is determined mainly by the molecular weight and the number of the acetate
groups of PVA. By contrast, the affinity of PVA and SiO
particles is strong at low pH,
but weak at high pH. That is, the quantity of PVA adsorbed on the silica surface
decreases with increasing pH. Since the adsorption of nonionic polymers, such as PVA, is
through hydrogen bonding with the silanol group on the silica surface, the adsorption is
favorably under low pH [8-10].
Introduction of a surfactant to a polymer solution-solid system may markedly influence
the adsorption properties of the polymer. This problem is very interesting also from
practical point of view because of increasing application of both, polymers and
surfactant, in mineral processing . Many studies on polymer-surfactant interaction on
solid surfaces, was frequently found possible to obtain elevated uptake of one or other of
the components. Otsuka and Esumi , dealing with a coadsorption study, shows a
remarkable increase in uptake of PVP on alumina in the presence of LiDS. A second
illustration by Cosgrove et al. , concerns the effect of SDS on the adsorption of PEO
by silica. PEO adsorbs strongly on silica, and SDS hardly at all. In this case SDS is seen
to bring about a progressive thinning of the PEO layer, reaching a limit around the CMC
of the surfactant and beyond the CMC the layer thickness increases again, suggesting that
SDS micelles are bound by the residually attached PEO chains. Kilau and Voltz. 
find that the wetting of a hydrophobic surface (coal) by an anionic surfactant is promoted
by the addition of the uncharged polymer PEO. Fleming et al. , studies on the
graphite-PVP-SDS system shown that addition of surfactant leads to an initial increase
and then to a decrease in PVP adsorption. Unfortunately literature data concerning such
systems polymer-surfactant onto salt-type minerals (such as calcite, dolomite,
phosphorite etc..) are scarce.
In the present study, adsorption of polyvinyl alcohol (PVA), with and with out
sodium oleate (SOl) onto calcite surface has been investegated in order to elucidate the
effects of polymer molecular weight, and the polarity of calcite surface, on the polymer-
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 149
surfactant interaction. In addition the conformation of PVA adsorbed on calcite is also
estimated from adsorption denseties.
The calcite sample used in this study was supplied from a mining company (Djebl
Onk- mining complex of phosphate) in Algeria.The sample was air-dried and then sieved
to give a -80+100µm size fraction using ASTM Standard sieves. The chemical
composition of the calcite, determined by a Cameca SX-50 electronic microprobe, is is
given in Table 1. Mineralogical species of calcite were characterized by X-ray powder
diffraction employing Bruker Axs diffractometer using monochromated Cu-Kα (α=
1.5406 Å) Fig.1.The specific surface area of calcite measured at 77 K using the BET N
method, was found to be 0.40 m
/g (via an Micometrics model 2100).
Table 1. Chemical anlyses of Calcite
CaO MgO FeO
52.50 0.72 0.09
As a nonionic polymer, Polyvinyl alcohol, PVA (Aldrich) with the average molecular
weights (Mw) of 13,000 and 23,000 (degree of hydrolysis 97.5%) were used in the
study.The polymer was filtered through the cellulose membranes (Millipore) to eliminate
inorganic contamination and lower polymer fraction.PVA chains contain acetate groups
which did not undergo hydrolysis in the production process of polyvinyl alcohol from
polyvinyl acetate. PVA 13,000 and PVA 23,000 used in the study have the degree of
hydrolysis equal to 97.5%. Depending on the degree of hydrolysis, the PVA contains
2.5% of acetate groups (–C
–). The polymer used may be considered as a
copolymer of vinyl alcohol and vinyl acetateaccording to the following scheme:
150 N.S. LABIDI
DJEBAILI Vol.7, No.2
The anionic surfactant used in these studies was pure sodium oleate C
99%) provided by the Sigma Chemical Company.
Fig. 1. X-Ray diffraction patterns of calcite (In agreement with JCPDS, cardN°-05-0586).
Adsorption experiments were carried out by the direct contact method which
involves shaking of a 100 ml PVA solution of definite concentration containing 1 g of
calcite (S/L=0.01, the ionic strength fixed at 3x10
M using KNO
, pH=7). The
suspension was shaken for 1 h to be sure that the equilibrium is reached, After shaking,
the suspensions were centrifuged at 3000 rpm for 5 min and the residual concentration of
PVA in the supernatant was estimated by the PVA /boric acid /iodide complex method
. The amount of residual concentration of PVA was calculated with the help of a
calibration plot obtained by measuring the absorbance of the yellow/red colored formed
complex spectrophotometrically at 682 nm using UV–vis Janway6300
spectrophotometer. The adsorption density and The thickness of PVA layer adsorbed on
calcite were calculated using equations (1) and (2), respectively [17,18].
Where, Γ is the adsorption density (mg/m
are the initial and equilibrium
concentrations (mg/ml) of PVA, respectively, V is the volume of suspensions (l) and (m)
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 151
the amount of adsorbent in g. S
is the specific surface area of calcite particles (calcite
/g).δ is the adsorbed layer thickness (m) and ρ is PVA density, g/m
• Effect of Sodium oleate on PVA adsorption
In these experiments, the sodium oleate concentration was kept constant, whereas
that of PVA was varied. The dispersions were left rolling for 1h and then centrifuged at
10000 rpm for 15 min. The supernatant liquid was then analysed for both PVA and
sodium oleate using the methods described above.
2.3. Zeta Potential Measurements
In the zeta potential measurement tests, 1 g of -80+120
mineral samples was
added into a 250 ml beaker in which 100 ml 10
solutions were added. The
suspension was conditioned for 3 min during which the pH was adjusted, followed by 10
min of conditioning after adding the appropriate reagents. It was then allowed to settle for
5 min, and about 10 ml of the supernatant was transferred into a standard cuvette for zeta
potential measurement using a Micromertrics Zeta Potential Analyzer. Solution
temperature was maintained at 25 °C. Ten measurements were taken and the average was
reported as the measured zeta potential [19,20].
2.4. FT-IR Measurements
FT-IR measurements were recoded on a JASCO 460 FT-IR spectrometer in the
region of 400-4000cm-1 supplied with OMNIC software. The tablets were prepared by
grinding 2 mg of the solid sample with 50 mg of KBr. Before every analysis, the
background was collected and subtracted from the spectrum of the sample. Two hundred
scans at a resolution of 4cm
were recorded for each sample.
3. RESULTS AND DISCUSSION
3.1. Zeta potential measurements
These measurements indicate charge properties of calcite particles and in turn can
suggest what can adsorb, penetrate, and adhere. Fig.2 displays the zeta potential of calcite
in absence and presence of polymer PVA as a function of pH. It is clear that in distilled
water the calcite had, an isoelectric point at about 9. Above it, the surface charge is
positive.The presence of PVA does not alter the surface potential of calcite.However, a
compression in the electrical double layer was observed. After conditionnig with sodium
oleate, calcite became negatively charged with a minimum at pH=8-10, indicating that
the maxium sodium oleate occured in this pH range.
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The results indicate that the surface sites remain accessible to potential determining H
and the IEP remains unchanged during PVA adsorption.This implys that the
polymer does not alter the surface potential. It can be considered, that the decrease in zeta
potential relating to adsorption of polymer is not due to a decrease in charge and surface
potential, but rather to a shift of the shear plane.The changes of the zeta potential
produced by the adsorption of substances with high molecular weight are resulted from
blocking of the active sites on the minerals’ surface and from the shift of the shear plane
as other investigators asserted [21,22].
Calcite+ Sodium oleate(3x10
Fig.2. Zeta potential of calcite in absence and presence of PVAand SOl.
3.2. Adsorption isotherm
Fig. 3 presents adsorption isotherms obtained for pure solutions of PVA of molecular
weights 13,000-23,000 at constant pH of 7 and temperature of 25°C . One can see that an
increase of molecular weight of PVA gives distinct increase of the polymer adsorption.
This increase is produced by higher affinity of big macromolecules, having more
functional groups, than smaller ones to the surface of the solid, as well as appearance of
various structures during adsorption of such chains at the solid-solution interface. That is
because bonding of the macromolecule with the surface of the solid runs by the number
of all existing segments presented in the macromolecule. According to this number of
segments of the polymer chain, that interacts with the surface of the solid may be the
same for different molecular weights, while total adsorbed amount of the polymer will be
greater for the higher molecular weight one [23,24]. We can see that the adsorption
isotherms shown in Figures are S-shaped, which suggests a physical adsorption of PVA
onto the calcite surface.The adsorption is due to the formation of hydrogen bonding
between the calcite surface from one side and OH
polymer functional group from the
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 153
Fig. 3. Adsorption isotherm of PVA of various molecular weights on the surface of
Calcite (T=25°C,pH= 7,C
Fig. 4 illustrates the influence of the sodium oleate on the magnitude of PVA adsorption
in the systems studied. As can be seen, the adsorption of PVA on the surface of CaCO
increases in the presence of sodium oleate.This effect is probably connected with the
formation of polymer-surfactant complexes. At the solid interface, the concentration of
polymer and surfactant increases in comparison to bulk of the solution. In such place the
conditions for PVA-SOl interactions are more favorable and formed complexes follow
distinct increase of the polymer adsorption. Another important factor influencing the
polymer-surfactant interactions may be caused by changes of the macromolecule
conformation in this area. Macromolecules at the solid surface vicinity may increase their
linear dimensions (polymer coils may spread due to interaction of the salt-type minerals
surface) that increases possibility of their interactions with surfactants.
Fig. 5 shows the influence of the molecular weight on the adsorbed amount of the
The result is that the conformation of the chain with high number of loops and
tails should give thicker adsorption layer, so does the increase of the polymer molecular
weight. Results presented in Table 2 confirm such hypothesis. Obtained data reveal an
increase of thickness of the adsorbed layer of the polymer with increasing of its
molecular weight. These results are similar to those previously reported by Chibowski et
al (2000-2005) for PVA - Alumina and polyacrylic acid (PAA)-Aluimina [25,26].
154 N.S. LABIDI
DJEBAILI Vol.7, No.2
Fig. 4. Adsorption isotherm of PVA of various molecular weights on the surface of
with and without sodium oleate (C
M) as a function of the equilibrium
concentration of the polymer in 10
Table 2. Thickness of the adsorption layer of the polyvinyl alcohol (PVA) on the
surface of CaCO
from solutions with the mixture of PVA and sodium oleate (SOl).
13,000 0.25 19 0.33 25
23,000 0.36 28 0.39 30
Fig. 5. Polymer-conformation changes with increase of the polymer chain length
(molecular weight) on amount of adsorbed polymer : (A) small molecular weight, flat
conformation ; (B) big molecular weight, conformation with numerous loops and tails
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 155
3.3. FTIR Spectral Analysis
FTIR spectroscopic studies were carried out on calcite, PVA polymer and sodium
oleate samples both before and after adsorption. The assignments of the various bands
and peaks made in this study are in reasonable agreement with those reported in the
literature for similar functional groups.
The FTIR spectra Fig. (6A) show the characteristic absorption bands of calcite (CaCO
located in 1403, 875 and 711 cm
, corresponding to the the asymmetric stretching (ν
out-of-plane bending (ν
), and the in-plane-bending (ν
) modes of the carbonate CO
ion group are found to be active. The strong bands related to the presence of bound water
(ν) O-H stretching is around 3400 cm
The FTIR spectra of calcite treated with 10
M Na-oleate Fig.(6B) shows a band at 1648
. This suggests the formation of a metal complex involving the COO
(monocoordinated surface calcium oleate COO-Ca
). The absorption band at 1133 cm
is related to C–O bonds and the band at 1296 cm
is assigned to the bending vibration
-). Two bands at 2956 and 2853 cm
which are characteristic of (-CH)
asymmetric and the symmetric stretching respectively. The band at 3475 cm
characteristic of O-H stretching. From these results, it can be concluded that oleate anions
are chemisorbed on the calcite surface.This agrees with data on the dependence of the
frequency on the metal nature [29,30].
The FTIR spectra of calcite, PVA, PVA-adsorbed onto calcite and mixed (SOl-PVA)
adsorbed onto calcite are presented in Fig. 7(A), (B) and(C) respectively.
The spectra Fig. 7(A) of PVA used in this study is in good agreement with published IR
spectra of PVA. The spectra indicates a wide and intense band due to the presence of
hydroxyl groups (O-H) at 3441 cm
.The bands corresponding to the (-CH
and the symmetric stretching at 2956cm
and 2854 cm
.The band at 1450 cm
attributed to O–H and C-H bending. The band at 941 cm
results from an angular
deformation outside the plan of O-H bond. The absorption peaks at 1112 cm
related to C–O stretching. The absorption bands at 1625 cm
is due to the symmetric
stretching of carboxylate anion (-COO
The spectra Fig. 7(B) of PVA-adsorbed onto calcite shows a broad band around 3445 cm
is due to the O–H vibrations and hence attributable to the existence of surface hydroxyl
group (free hydroxyl group) and chemisorbed water (bonded hydroxyl group)
hydroxyl group peak is present in calcite powder without polymer, but the spectra with
polymer shows the appearance of this peak. Moreover, the peak intensity of the
156 N.S. LABIDI
DJEBAILI Vol.7, No.2
hydrogen-bonded hydroxyl groups is smaller in case of the powder with the polymer than
without.This can be attributed to the decrease of surface hydroxyl groups. The extra
bands at 1797 and 2250 cm
(artefact) corresponds to C-O stretching vibration of ketones,
aldehydes, lactones or carboxyl groups. Intensity of these bands decreases after
adsorption of PVA onto calcite and therefore the surface functional group is generally
neutral or slightly acidic [32,33]. This finding is in concurrence with earlier studies,
including Pattanayek et al, (2002) on silica-PVA, Besra et al, (2003) on kaolin-
polyacrylamide (PAM), and Santhiya et al, (1999) on Alumina-Poly acrylic acid (PAA)
and Polyvinyl alcohol (PVA).They showed that the presence of isolated O-H groups on
the surface is responsible for the adsorption of polymer molecules by hydrogen bonding
The spectra Fig. 7(C) of PVA-sodium oleate adsorbed onto calcite shows absorption
peaks at about 3450 and 3546 cm
due the presence of hydroxyl groups (O-H).Two
bands at 2956cm
and 2854 cm
are corresponding to (-CH) asymmetric and the
symmetric stretching.An absorption band at 1637cm
due to the asymmetrical COO
stretching vibrations is probably associated with COOH in slight dimerization of oleic
acid through partial hydrolysis of the salt. The absorption peaks at 1100 cm
to C–O stretching of -C-OH groups of PVA. These results indicating hydrogen bonding
interaction between the surfactant SOl and polymer PVA onto calcite.
Fig. 6. IR spectra of (A) calcite, (B) calcite-sodium oleate.
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 157
Fig. 7. IR spectra of (A) PVA, (B) PVA-adsorbed onto calcite, (C) (PVA-SOl) adsorbed
onto calcite water interface.
3.4. Mechanism of Adsorption
Before talking about the mechanism of adsorption the following points need to be taken
into consideration to explain the nature of adsorption of long chain surfactant from
aqueous solutions first and polymer surfactant in second:
1) In the simple calcite-water system, there are three important factors governing the
formation of the calcite surface charge: a) the concentration of potential-determining
b) the pH, on which the concentration of the potential-
determining anion CO
depends ; c) suspension concentration.In such system the
following species are in equilibrium:Ca
charge balance can be expressed by the equation :
] + 2[Ca
] = [HCO
] + 2[CO
] + OH
2) In the approximate pH range 7 < pH < 10,calcite is positively charged, because of the
prevalence of positive ionic species. The concentration of Ca
singly charged hydroxo
reaches maximum and covered the calcite surface
witch is rendered positively charged
3) Species to be considered in a system with an anionic surfactant RCOOH in aqueous
solution in the presence of an indifferent electrolyte MX are RCOOH (undissociated
(oleate anion), RCOO
(oleate dimer), (RCOO)
158 N.S. LABIDI
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, and H
O. It may be noted that in the basic region the contribution of
species such as RCOO
are maximum .
4) PVA chains contain acetate (–C
–) groups and hydroxyl -OH groups which did
not undergo hydrolysis.An electrostatic interaction forces via hydrogen bonding betwen
these functionals groups and (–CH, RCOO
) group from sodium oleate occurs.
In this condition, chemical interaction between surfactant and mineral occur. The
negative oleate are bonded to the positively ions charged surface and this leads to the
monocoordinated surface (calcium oleate RCOO-Ca
or bicoordinated surafce (calcium
dioleate RCOO-Ca-OOCR). After these complexe formation onto calcite surface
coadsorption of polymer (PVA) at the calcite-sodium oleate/water interface may be due
to electrostatic interaction forces via hydrogen bonding between PVA functional groups
and hydroxyl, -OH) and (carboxylates RCOO
and -C-H groups) in
sodium oléate. A Schematic representation of the coadsorption of a nonionic polymer on
(positively charged) calcite in the presence of an anionic surfactant is given in Fig. 8.
Cleverdon and Somasundaran, (1985) , in a similar approach, proposed a
conformational scheme for the cationic polymer masking the anionic dodecylsulfonate
layer on negatively charged silica.
active sites on calcite
OLEATE + CALCITE
Fig. 8. Schematic representation of sodium oleate-calcite adsorption (A), and
coadsorption of a surfactant (SOl) and a polymer (PVA) at the calcite/water interface (B).
Vol.7, No.2 Studies of the Mechanism of PVA Adsorption 159
Results of adsorption, zeta potential meauserments, FTIR and X-Ray diffraction stuides
allowed formulate following conclusions:
- Sodium oleate presence markedly influenced amount of PVA adsorbed on the
surface of CaCO
. The increase of the polymer adsorption is connected with formation of
polymer-surfactant complexes in water solution of PVA and sodium oleate. The same
complexes are formed also on the surface of CaCO
- Polymer surfactant interactions lead to the change of the structure of macromolecule
in the solution and at the interface alike.
- Presence of the surfactant results in a certain increase of the thickness of the
adsorbed polymer layers on the surface of CaCO
- Molecular weight of the polymer and its concentration, are found main parameters
influencing PVA adsorption onto calcite surface.
- The reaction between oleate anions and calcite is a chemical type. The interaction
between oleate anions and PVA is a physical type (via hydrogen bonding).
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