This study focused on the contents of the air particulate matter pollution in two districts of Ulaanbaatar and determined the chemical composition of air borne samples and the source of those particles. Samples of fine and coarse fractions of PM were collected using a “Gent” stacked filter unit in two fractions of 0 - 2.2 μm and 2.2 - 10 μm sizes in two semi-residential areas from September 2012 to August 2013. This paper points out that fine and coarse concentration varied seasonally with meteorological changes. In sampling site 3, Zuun Ail (Figure 1) combustion generators generate the majority of pollution around 50.6% of household waste furnace to create high-temperature combustion of 21.6%. However, this net contributes to soil contamination near the lower value (5%) that arises around the vacuum environment in substantial amounts (14%), where is open around the buildings and residential areas, and the soil is considered to be due to the construction. But the data point to the highway in the distance, where is 9% of contamination of all vehicles’ smoke, and exhaust is similar to the data collected in Ulaanbaatar. According to analysis of samples of Nuclear Research Center (NRC) sampling site 2, it shows burning source of Particulate Matter 2.5 pollution in the air is around 25.5% of household waste furnace to create high-temperature product of combustion. But here the very high net contribution to the pollution of soil, is 31.6%. Today’s emerging dust is around 15.2%, showing that motor vehicle pollution causes 19.7%. Since the analysis was done on a sample-by-sample basis, it is possible to estimate the daily contributions of pollution sources and provide useful information based on a limited number of samples in order to address air quality management issues in Ulaanbaatar.
Daily life is interconnected to environmental change and air quality. Today, pollution is one of the world’s most important issues. In recent years, air quality concerns have become one of the most important problems to be solved for the capital city of Mongolia, Ulaanbaatar (UB). Located at approximately 1300 meters above sea level, the coldest national capital in the world, UB has an average annual temperature of −1.3˚C (29.7˚F), and population of 1.8 million [
Particulate matter (PM) air pollution in Ulaanbaatar is several times higher than the permissible level of the Mongolian National Air Quality Standards 4585:2007 (MNS) and the World Health Organization (WHO) standards. Ulaanbaatar was ranked in the list of the most polluted cities of the world by the World Bank.
With special focus on particulate matter, the secondary PM consists of significant portions of sulfates and nitrates, which are due to chemical transformation of SO2 and NOx. Of these pollutants, the PM is one of the most critical, responsible for the largest healthy and economic damages and also affects in visibility and weather condition.
Fine particles (PM2.5) are mainly from combustion sources like vehicles, diesel engines and industrial facilities. Coarse particles are directly emitted from activities that distract the soil including travel on roads, construction, mining, open burning and agricultural operations. Other sources include windblown dust, pollen, salts, brake dust and tire wear [
The purpose of this study is to investigate particulate matter air pollution in UB, and to compare it with research conducted in 2008, and determine the level of chemical elemental composition and black carbon (BC) concentration data. The PM samples were collected at two semi-residential sites in UB. The local source profiles used in this analysis were obtained from a previous data analysis study [
Previous work mainly focused on sampling in the Zuun Ail location. The same equipment was used in this study as was used in the previous research, but a second sampling site for comparison was chosen. That is why we have to do this research and compare it with meteorological conditions and monitor how depends on it.
By comparing the results of two-point measurements of the city with the results of September 2012 to August 2013, the annual average concentration of PM2.5 decreased by 58% from 296.5 µg/m3 to 123.5 µg/m3 and the an annual average concentrations of PM10 decreased by 50% from 557.5 µg/m3 to 276.1 µg/m3, and it appears that measures taken by the parliament and the national government, as well as the city government may have reduced air pollution.
The results of the research work have been compared with those obtained from PM analysis performed in an earlier study [
Our study of changes in the elemental concentration of PM2.5 and PM10 - 2.5 in two districts of UB began in September 2012 and ended in August 2013. The research was conducted at the 2 points for 2 times in a 24 hour period.
In this study PM samples were collected at two semi-residential sites in UB (
Previous work (from 2008 to 2009) [
Sampling was done using a “Gent” type stacked filter sampler [
A portable particle analyzer, known as an optical particle counter (OPC, Model 1.108, GRIMM Inc.), specifically designed for PM2.5 and PM10 ambient air sampling in the present study. Collecting fraction samples of particulate matter in the coarse particles (PM10) and fine particulates (PM2.5) size have been monitored using the GRIMM sampler.
The research to collect air particulate matter two extract fraction samples has the special work tapes, and fractions uses were collected GENT air pump system for sampling, and polycarbonate filter with 2 mm thick, 8 mm to filter PM10 - 2.5 large particles and 0.4 mm hole filtration to filter less than PM2.5 micron diameter air particulate matter.
The masses of the coarse and fine fraction samples were determined by balancing the filters before and after the exposure. The concentration of BC in the fine fraction of the samples is determined by reflectance measurement using an EEL-type Smoke Stain Reflectometer.
Air samples have been determined and elemental concentrations were measured by RFA using SPESTRO XEPOS spectrometer and up to 20 chemical elements have been identified from Na to U. The contamination source has been determined by the result of element analysis. Data on the concentrations of sixteen species, BC and mass were available for further analysis. To this end, research was done on the data based on multivariate statistical methods used SPSS 22 program.
The meteorological data used in this study was obtained from a local meteorological station.
At the Zuun Ail and NRC measurement point coarse and fine particle concentrations were collected to provide measurements during the period of September 2012 to August 2013. PM10 - 2.5 and PM2.5 fraction measurement samples determined the amount of PM air pollution in UB. The results are shown in
Particulate matter concentrations were found to be extremely high at times with average PM10 concentrations measured at 276.1 µg/m3 and PM2.5 concentrations measured at 123.5 µg/m3 in the Zuun Ail respectively (the Guidelines recommends 10 µg/m3 for fine, and 20 µg/m3 for coarse).
PM | Average concentrations of the PM (µg/m3) | МNS 4585:2007 | Air Quality Guidelines WHO, 2005 | |
---|---|---|---|---|
Zuun Ail 2012-2013 | NRC 2012-2013 | |||
PM2.5 | 123.5 | 117.5 | 25 | 10 |
PM10 | 276.1 | 263.7 | 50 | 20 |
Fine particle average annual concentration was measured at 123.5 µg/m3 and 117.5 µg/m3. MNS 4585:2007 specified in (25 µg/m3) 4.9 greater than, (50 µg/m3) again 4.7 greater than, WHO Air Quality Guidelines from size (10 µg/m3) 12.35 greater than, 11.75 greater than recommended standard respectively (
There is high air pollution from October through May and extremely high air pollution from January through March. Fine particle concentration peaked during the winter (December, January, March). The monthly average concentration of PM10 is relatively higher 576.9 µg/m3 than 549.9 µg/m3. The average concentration of the other months is from January to May. The average monthly maximum in 2012-2013 from June through October had uniformly low concentration levels. Air pollutant concentration at the surface is strongly influenced by the characteristics of the source emission and the meteorological conditions of the atmosphere [
According to
Three meteorological and 12 hour radio-sound data weather charts were used to characterize the atmospheric conditions in UB during the measurement period of September 2012 to August 2013.
At both Zuun Ail and NRC sites fractions of 20 chemical elements in the ambient air PM2.5 samples and PM10 - 2.5. Si, Al, Ca, Fe, Ti were found in the soil-derived components, such these are considered as high-grade (
Elements | Average concentrations in (ng/m3) | |||
---|---|---|---|---|
Zuun Ail | NRC | |||
РМ2.5 | РМ10 - 2.5 | РМ2.5 | РМ10 - 2.5 | |
Маss | 133,654 | 155,762 | 117,452 | 146,259 |
BC | 5586 | 2373 | 8685 | 3482 |
Na | 1940 | 3858 | 3017 | 5778 |
Mg | 600 | 2197 | 1040 | 3383 |
Al | 1211 | 7903 | 2119 | 13,382 |
Si | 1629 | 14,423 | 3442 | 25,153 |
P | 260 | 333 | 282 | 360 |
S | 3868 | 2036 | 5824 | 2412 |
Cl | 300 | 661 | 361 | 891 |
K | 244 | 1567 | 392 | 2795 |
Ca | 309 | 3180 | 713 | 5546 |
Ti | 143 | 315 | 159 | 481 |
Mn | 57 | 105 | 63 | 151 |
Fe | 269 | 2254 | 495 | 3962 |
Cu | 12 | 21 | 13 | 22 |
Zn | 47 | 49 | 68 | 69 |
Pb | 17 | 6 | 26 | 13 |
Near the NRC site there was fine particulate pollution (PM2.5) and the samples contained a high level of BC and sulfur (S) and the products of combustion. The combustion was from the small scale stoves and also the smoke from the thermal plant. It shows high concentration levels of elements (
Around the NRC there may have been a lot of pollution from the soil. This profile contains S and BC as well as other soil components [
РМ2.5 source of pollution | Contribution to pollution (%) | ||
---|---|---|---|
NRC | Zuun Ail | ||
1 | Combustion-1 | 25.5 | 50.6 |
2 | Combustion-2 | 8.1 | 21.6 |
3 | Soil | 31.6 | 4.9 |
4 | Road dust | 15.2 | 13.9 |
5 | Motor vehicles | 19.7 | 9.1 |
buildings, and around the location of NRC there is construction in progress. In proximity to this point there are dusty road passes. For the vehicles near the NRC there is an east route and central road of the city that passes on either side (
Particulate matter (PM2.5) annual average concentration is 123.5 µg/m3 and 117.5 µg/m3 and it has 5 times more than MNS 4585:2007 allowing, and 11 - 12.5 times more than the measurement specified from the Air Quality Counsel of WHO. The annual average concentration of PM10 is 276.1 µg/m3 and 263.7 µg/m3 and it is 5.2 - 5.8 times higher than Mongolian standards, 13.2 - 14.5 times higher than the amount specified from the Air Quality Counsel. In this research, for the population health assessment of the air quality, the indexes of 2 points indicate at a high risk for health.
In addition, air pollution may depend on the wind. From January through March Ulaanbaatar has the highest concentration than other months. Wind speed is constant in the cold seasons and it increases in March and it may be the reason for the increase in soil and dust emissions.
An EMF analysis result shows UB’s air pollution sources in the territory of the two different points have variety as shown by the data.
Measures to reduce air pollution in the city not from smoking, but from other sources are necessary. Dust should be regarded as a defined contribution source of particulate pollution.
We acknowledge the support provided by professor (Ph.D) S. Lodoisamba, NRC of National University of Mongolia (NUM) and the anonymous referees for their useful comments on earlier drafts of this paper.
AN was supported by high-tech grants (NO. ӨС 2015 ШУС 12) from the NUM for research.
Amgalan, N., Narantsetseg, T. and Shagjjamva, D. (2016) Valuations of Elemental Concentrations of Particle Matter in Ulaanbaatar, Mongolia. Open Journal of Air Pollution, 5, 160-169. http://dx.doi.org/10.4236/ojap.2016.54012