Advances in Materials Physics and Chemistry
Vol.3 No.1(2013), Article ID:29137,10 pages DOI:10.4236/ampc.2013.31008

Cuand Ni-Doping Effect on Structure and Magnetic Properties of Fe-Doped ZnO Nanoparticles

Jefferson A. Wibowo, Nadia F. Djaja, Rosari Saleh*

Departemen Fisika, FMIPA-Universitas Indonesia, Depok, Indonesia

Email: *rosari.saleh@ui.ac.id, *rosari.saleh@gmail.com

Received January 7, 2013; revised February 8, 2013; accepted February 18, 2013

Keywords: Codoped ZnO Nanoparticles; Room-Temperature-Ferromagnetic; Co-Precipitation

ABSTRACT

Cuand Ni-codoped FeZnO particles with the wurzite structure were successfully synthesized at low temperature by a co-precipitation method. The samples were characterized using a vibrating sample magnetometer, X-ray diffraction, energy dispersive X-ray spectroscopy, UV-Vis spectrophotometry and electron spin resonance. The results demonstrated that room temperature ferromagnetic order was observed in both samples and the magnetization was higher than that of Fe-doped ZnO. The correlation between the structural and magnetic properties is discussed.

1. Introduction

Dilute magnetic semiconductors (DMSs) in which some of the cations host lattice are replaced by a transition metal ions have attracted considerable attention due to their potential as spin-polarized carrier sources and their potential applications in spintronic devices [1-5]. The main challenge for practical application of DMSs is the attainment of Curie temperature above room temperature [6]. Following the theoretical prediction of room temperature ferromagnetic by Dietl et al. [7], several studies involving magnetic ions doped II-VI semiconductors were performed by different researcher in transition metal doped ZnO. It is known that ZnO has high solubility for transition metals and superior semiconductor properties [8]. Moreover, ZnO is a wideband gap semiconductor with a relative large exciton binding energy. Among transition metal, ZnO doped with Fe ions without any modification of the structure has been the most considerable interest. Ferromagnetism with Curie temperature higher than room temperature has been observed in Fe-doped [9-12], Co-doped [13-15], Mn-doped [16-18], Ni-doped [19-21], Cu-doped [22] and V-doped [23] ZnO nanoparticles. Meanwhile, several codoped ZnO have also been reported with the expectation that codoping can lead to remarkable changes in the properties of the materials [24-26]. Presence of two different kind of transition ions simultaneously in a host material produces magnetic property that can be different from the magnetic property due to single transition metal ions. For instance, Han et al. [27] reported that the Curie temperature of bulk Zn0.94Fe0.05Cu0.01O was above room temperature and the maximum saturation of magnetization was larger than that of the sample without Cu [27,28]. Shim et al. [29] also prepared FeCu co-doped ZnO sample and reported that the room temperature ferromagnetic in the sample is due to the secondary phase ZnFe2O4 [27,29].

Despite the considerable amount of data a great deal of controversy remains, especially regarding the fundamental issue of whether the system actually exhibits room temperature ferromagnetic at all; and in the case where it does, whether the effect is intrinsic to the material. Further studies suggested that the inconsistencies in the literature regarding the ferromagnetic ordering of transition metal doped ZnO indicate that these materials are very sensitive to the fabrication and processing conditions. Therefore, this paper we attempt to study the effect of Cuand Ni co-doping on the weakest ferromagnetic Fedoped ZnO (1 at% of Fe). The co-precipitation method was chosen for the synthesis of these materials because it is cost effective, requires low temperature processing and offers a higher degree of solubility. The effects of Cu and Ni doping on the structural, optical and magnetic properties of nanocrystalline Fe-doped ZnO particles was investigated using X-ray diffraction (XRD), energy dispersive X-ray (EDX), UV-Vis spectroscopy (UV-Vis), electron spin resonance (ESR) and vibrating sample magnetometer (VSM). It was found that the incorporation of Cu and Ni in Fe-doped ZnO nanoparticles not only enhances ferromagnetic properties to the host materials but also changes lattice constant and the optical properties.

2. Experimental

For the synthesis of Cuand Ni-doping of Fe-doped ZnO nanoparticles in this study the following starting materials were used without further purification: zinc (II) sulfate (ZnSO4·7H2O, 99%, Merck), iron (II) sulfate (FeSO4·7H2O, 99%, Merck), cooper (II) sulfate (CuSO4·5H2O, 99%, Merck) and nickel (II) nitrate (Ni(NO3)2·6H2O, 99% Merck). FeSO4·7H2O and CuSO4·5H2O, FeSO4·7H2O and Ni(NO3)2·6H2O, were added simultaneously to the ZnSO4·7H2O, solution under continuous stirring to get homogeneous solutions. These mixtures (solution A) were placed in an ultrasonic cleaner operating at 57 kHz for 2 h. Simultaneously, 44 mmol NaOH solution was prepared in 440 ml of deionized water (solution B). Then solution B was added drop wise to solution A with constant stirring for 2 h until a pH of 13 was reached. The mixed solution was allowed to stand at room temperature for 18 h. Subsequently, the solution was centrifuged and washed several times with ethanol and distilled water to remove residual and unwanted impurities. The final product was dried in a vacuum oven at 200˚C for 1 h to yield Fe/Cu and Fe/Ni-codoped ZnO powders.

Elemental analyses of the samples were carried out using scanning electron microscope (SEM) with EDX attachment. To evaluate the phase purity of the samples, XRD measurements were performed using a Philips PW 1710 and monochromatic Cu-Kα (λ = 1.54060 Å) radiation operated at 40 kV and 20 mA in the range of 10˚ to 80˚. The instrumental broadening including the instrumental symmetry was calibrated using a Si powder standard sample. The X-ray diffraction patterns were analyzed by means of the MAUD program using the Rietveld whole profile fitting method to determine the crystal structure and lattice parameters.

To study the electronic interaction near the optical band gap resulting from the addition of dopant atoms, diffuse reflectance UV-Vis measurements were performed using a Shimadzu UV-Vis spectrophotometer with an integrating sphere and a spectral reflectance standard in the wavelength range of 200 - 800 nm. The diffuse reflectance, R, of the sample is related to the Kubelka-Munkfunction, F(R), according to the following equation: F(R)= (1 − R)2/2R [30]. The energy band gap of the samples was calculated from the diffuse reflectance spectra by plotting the F(R)2 as a function of energy and extrapolating to F(R)2 = 0.

Magnetic measurements were performed on Oxford Type 1.2 T vibrating sample magnetometer (VSM). These measurements were taken from 0 to ±1 Tesla field. To obtain information on electronic structure ESR was carried out using X-band JEOL JES-RE1X at room temperature. The shape and area of the ESR spectra were analyzed using standard numerical methods.

3. Results

To confirm the presence of Fe, Cu and Ni ions in the synthesized nanocrystalline ZnO particles, EDX measurements were performed. Four different random areas in the sample were chosen and about the same Fe, Cu and Ni concentration was obtained for all of them. This result suggested that the distribution of doping is homogeneously. The EDX data from concentrations of Fe, Cu and Ni are listed in Table 1. It is seen that the amounts of Fe, Cu and Ni incorporated in the samples are slightly lower than their nominal composition introduced in the synthesis.

The XRD patterns for Zn0.96Fe0.01Cu0.03O and Zn0.96 Fe0.01Ni0.03O samples are presented in Figure 1. Also shown the XRD patterns of Zn0.95Fe0.05O [31], Zn0.94 Cu0.06O [32], Zn0.95Ni0.05O [33] and undoped ZnO [34]. It has been observed that all of peaks of XRD pattern belong to the hexagonal lattice of ZnO with three most preferred orientations namely (100), (002) and (101). Most importantly, all of the XRD peaks were attributed to ZnO and no other undesired peaks were observed due to secondary phases or impurity phases within the detection limit of the X-ray diffractometer. From the 2Θ values, the inter-planar spacing d of the peaks is calculated.

The values are listed in Table 2. A good agreement between the observed and the calculated d values is found to exist indicated a suitability of unit cell parameters and the crystal structure.

The lattice constants, calculated from Rietveld refinement using MAUD programs, unit cell volume, the values ratio (c/a) are summarized in Table 2. The results are compared with those of Fe-doped ZnO. The average crystallite size and strain were also obtained from Rietveld refinement of the X-ray diffraction patterns of the samples obtained by constructing Williamson-Hall plots [35] with different peaks for the same families. In the present study, (100), (002), (101), (102), (110), (103)Table 1. EDX data of Fe-, Cu-, Ni-doped ZnO and Cuand Ni-codoped FeZnO nanoparticle.

Figure 1. XRD patterns of ZnO, Zn0.95Fe0.05O, Zn0.94 Cu0.06O, Zn0.95Ni0.05O, Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01 Ni0.03O nanoparticles.

and (112) peaks were used to construct the WilliamsonHall plot. From the linear fit to the data, the average crystallite size, , was extracted from the y-intercept and the strain, ε, from the slope of the fit of:

In this calculation the strain was assumed to be uniform in all directions of the samples. The average crystallite size, and the strain, ε, are shown in Table 2. These results indicate that the in the Zn0.96Fe0.01 Cu0.03O and Zn0.96Fe0.01Ni0.03O samples have a similar average crystallite size with Zn0.97Fe0.03O. These data showed that the substitutional doping does not influence the crystal structure significantly.

To study the electronic interactions near the optical band gap region of Zn0.96Fe0.01Cu0.03O an Zn0.96Fe0.01 Ni0.03O samples diffuse-reflectance measurements were performed on the samples in the UV-Vis region at room temperature. All spectra were obtained in the range of 200 - 800 nm. Figure 2 shows the diffuse-reflectance spectra, R, as a function of wavelength. The band gap energy of the doped ZnO samples was calculated from the diffuse-reflectance spectra by plotting the square of the Kubelka-Munk function F(R)2 vs. the energy in electron volts. The linear part of the curve was extrapolated to F(R)2 = 0 to calculate the direct band gap energy. The Table 2 also shows the band of Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O samples. It is seen that the absorption edge is slightly different with the addition of Cu and Ni in Fe-doped ZnO sample compare to Fe-doped ZnO sample itself.

To gain insight into the oxidation state of the dopant cations involved in the spin coupling and site occupancy of the dopant ion in the host material, ESR spectra were

Figure 2. The diffuse-reflectance spectra of Zn0.96Fe0.01 Cu0.03O and Zn0.96Fe0.01Ni0.03O compared with Zn0.95Fe0.05O nanoparticles.

measured at room temperature. Typical ESR spectra of both the Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O particles are provided in Figure 3. For interpretation of Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O results a comparison with Fe-, Niand Cu-doped ZnO ESR spectra was also instructive. In Zn0.95Fe0.05O the ESR signal can be considered as a superposition of two overlapping signals, a broad and intense signal attributed to Fe2+ and another weak and narrow signal assigned to Fe3+ [31,33]. In the case of Zn0.95Ni0.05O, the ESR spectra had similar features, which exhibited two overlapping resonance peaks. One peak corresponded to the broad resonance while the other peak located at higher magnetic field was much narrower. The linewidth and the g-values of the broad signal in our Zn0.95Ni0.05O was consistent with the line shape and position of the previously reported Ni-doped ZnO samples [33,36] and have been attributed to a ferromagnetic resonance due to Ni2+ ions. A comparison of the g-values of the narrow ESR signal with the ESR signals of Ni in Li1−XNi1+XO2 [37,38], SnO2 [39] and TiO2 [40], which have g-values in the range of 2.13 - 2.18, suggests that the narrow resonance in our Zn0.95 Ni0.05O samples is attributable to paramagnetic Ni3+ ion centers.

The electronic configuration of Cu2+ ion is 3d9 and the electronic ground state is 3S1/2. The only natural isotope is 63Cu, which has nuclear spin 3/2. The ESR spectrum of Zn0.94Cu0.06O sample shown in Figure 3 revealed the presence of broad signal, which is superimposed on poor-resolved quadruplet signals and a pronounce narrow resonance. The broad signal at g value of 2.05 is associated with Cu2+ interacting with nearby Cu2+ via dipole interaction [41] whereas a narrow signal at g value of 1.98 could be attributed to an unpaired electron trap-

Table 2. The The lattice constants, unit cell volume, ratio of lattice parameters, interplanar spacing, average crystallite size, strain and band gap energy of Zn0.95Fe0.05O, Zn0.94Cu0.06O, Zn0.95Ni0.05O, Zn0.96Fe0.01Cu0.03O, and Zn0.96Fe0.01Ni0.03O nanoparticle.

Figure 3. The electron spin resonance spectra of Zn0.96Fe0.01 Cu0.03O and Zn0.96Fe0.01Ni0.03O compared with Zn0.95Fe0.05O, Zn0.94Cu0.06O, and Zn0.95Ni0.05O nanoparticles.

ped on an oxygen vacancy site [42-52].

Comparing the ESR spectra of Zn0.95Fe0.05O and Zn0.94 Cu0.06O with that of Zn0.96Fe0.01Cu0.03O, the line width and the g-value of Zn0.96Fe0.01Cu0.03O can be attributed to Fe2+, since the g-value observed here does not agree with the reported value for Cu2+. In addition, hyperfine structure due to 63Cu and 63Cu nuclei necessary for identification of Cu-related center was not observed. So the peak observed here would not be attributed to the Cu ions themselves.

It is apparent from Figure 3 that the two resonances of Zn0.96Fe0.01Ni0.03O are too close to be separated with confidence. We have carefully studied the line signal and found that the line-width and the line intensity can be deconvoluted in Fe2+ and Ni2+ signals. Although, it was reported that the g-value of Ni metallic species is centered at 2.2 [53], the presence of Ni metallic might be ruled out since the line width of this species is much broader than that of our ESR spectra of Zn0.96Fe0.01 Ni0.03O. The g-values, total number of spins associated with each signals and the line width are quite variable as shown in Table 3.

The room temperature ferromagnetic behavior of both the Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O particles in the magnetic field range from 0 to ±1 T using VSM measurements have been shown in Figure 4. The magnetization is plotted as a function of magnetic field for different dopant ions incorporated in Fe-doped ZnO particles. The diamagnetic contribution from the sample holder has already been subtracted to estimate the actual ferromagnetic contribution of each sample. Also shown in Figure 4 the magnetization of Zn0.95Fe0.05O, Zn0.94 Cu0.06O and Zn0.95Ni0.05O. The comparative M(H) loops showed that, the Zn0.96Fe0.01Ni0.03O exhibits higher magnetization than that of Zn0.97Fe0.03O as well as Zn0.95 Ni0.05O. The same result was also observed in Zn0.96Fe0.01 Cu0.03O. In the case of Zn0.96Fe0.01Cu0.03O sample a coercive field (HC) and the remnant magnetization (MR) are found to be 554 Oe and 0.012 emu/g, while for Zn0.96Fe0.01Ni0.03O smaller values are observed, namely 120 Oe and 0.004 emu/g. However, the saturation magnetization for Ni incorporation in Fe-doped ZnO is clearly higher than that of Cu co-doping.

The mechanism responsible for the observed ferromagnetism at room temperature in transition metaldoped ZnO is also not clear and has been debated over the years. Several explanations are discussed below. Nevertheless a few researchers have claimed to observe ferromagnetic behavior arising only from a secondary phase and not from the material itself. The results of the XRD and EDX measurements in our samples demonstrate that the dopant ion was incorporated into the wurtzite lattice at Zn sites forming a solid solution instead of precipitates. However, a secondary phase might

Table 3. The g value, linewidth (ΔHpp), and peak area of Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O compared with Zn0.95Fe0.05 O, Zn0.94Cu0.06O, and Zn0.95Ni0.05O nanoparticle.

(a)(b)(c)(d)(e)

Figure 4. The room temperature ferromagnetic of Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O compared with Zn0.95Fe0.05O, Zn0.94Cu0.06O, and Zn0.95Ni0.05O nanoparticles.

exist in the sample even though it was not detected in our XRD spectra. Thus, it is useful to consider all possible ferromagnetic impurity phases that might be present in both samples. It is known that Cu-related oxides such as CuO, Cu2O or Cu clustering could not contribute to the room temperature ferromagnetism, because none of them exhibit ferromagnetism above room temperature [54-56]. Therefore the ferromagnetism behavior observed in our Cu-doped samples studied here does not seem to be related with the presence of any secondary phases or Cu clusters, while Cu clusters and its oxides are generally considered to be non-ferromagnetic and could not contribute to the room temperature ferromagnetic. In the case of Fe-doped samples nearly all possible Fe-based oxides, such as FeO and Fe2O3 are antiferromagnetic with TN values of 198 and 963 K, respectively [57,58]. The exception to this is Fe3O4, which is ferromagnetic with a Tc of approximately 858 K [59]. Another secondary phase that can be found in Fe-doped ZnO samples is ZnFe2O4. However, this phase is antiferromagnetic and can be excluded as the origin of room temperature ferromagnetic in our samples. In the case of Ni co-doping, the formation of secondary phase such as NiO is a unlikely source of ferromagnetism as NiO is antiferromagnetic in nature with TN values of 523 K [60] and 5 K [61] for bulkand nanocrystalline NiO, respectively. Accordingly, the ferromagnetism behavior observed in our Zn0.96Fe0.01Cu0.03 O and Zn0.96Fe0.01Ni0.03O particles studied here does not seem to be related with the presence of any secondary phases.

There is also an emerging consensus that ferromagnetic behavior in transition metal-doped ZnO is correlated with defects such as oxygen or zinc vacancies [62-64]. Karmakar et al. [11] investigated the origin of ferromagnetism in Fe-doped ZnO using local probe measurements such as ESR and Mössbauer spectroscopy. The results revealed that the Fe ions are present in both Fe2+ and Fe3+ valence states. The presence of uncoupled Fe3+ ions is possibly due to hole doping in the system, which was caused by cation (i.e., Zn) vacancies. By comparing the ESR measurements from our sample with

 
the results obtained from Karmakar et al. [11] it is confirmed that the ferromagnetism observed in our Zn0.97 Fe0.03O sample was due to the presence of Fe atoms in the form of Fe2+ ions and Fe3+ ions.

According to Karmakar et al. [11] a cation vacancy near Fe can promote Fe2+ into Fe3+ and also mediate the Fe2+-Fe2+ exchange interaction. Moreover, since the transition metal ion is slightly higher side towards cationic percolation threshold, Fe2+-Fe3+ exchange interaction may also possible. Viswanatha et al. [65] investigated the origin of ferromagnetism in FeCu-codoped ZnO experimentally as well as theoretically. Their results revealed that the Fe ions are present in both Fe2+ and Fe3+ valence states, with the concentration of trivalent state increased with increasing Cu doping and redox-like pairs Fe2+ + Cu2+ Û Fe3+ + Cu1+ can be occurred to stabilize the ferromagnetism in codoped system. They believed that the ferromagnetism of this system is ascribed to a double-exchange interaction between the Fe atoms mediated by the Cu atom. It is obvious from ESR spectra of Zn0.96Fe0.01Cu0.03O show the presence of Fe2+ ion and the absence of Cu2+ ion. However, our EDX result shows the presence of Cu atom in our Zn0.96Fe0.01Cu0.03O. These results suggested that the oxidation state of Cu is +1, since Cu in the +1 state has no unpaired spin. Usually, a Cu ion will contribute to the net ferromagnetic moment only if it is in the +2 state. Interestingly, the Zn0.96Fe0.01 Cu0.03O sample shows an evidence of ferromagnetic order. Therefore we believed that a small amount of Fe3+ and Cu2+ ions would be found in our sample to neutralize the charge imbalance, although both ions (Fe3+ and Cu2+) were not detected in our ESR spectra. Comparing the XRD, EDX, VSM and ESR results for Zn0.96Fe0.01Cu0.03O with Zn0.95Fe0.05O, Zn0.94Cu0.06O and the results obtained in the literature, we conclude that Fe2+, Cu1+, Fe3+ and Cu2+ are presence in our Zn0.96Fe0.01Cu0.03O sample and have played the important role in obtaining the room temperature ferromagnetism.

In the case of Zn0.96Fe0.01Ni0.03O, the bent nature of the curve exhibits a shallow ferromagnetism in our sample. The ferromagnetism could arise due to possible reason: 1) secondary phase or clustering of metallic or 2) the presence of charge carriers, or 3) the formation of defect structures such as oxygenand zinc vacancies. It is already discussed above that the formation of secondary phase is unlikely. Moreover, from the ESR spectra of Zn0.96Fe0.01Ni0.03O the presence of Ni metallic might be ruled out. In addition the ESR measurement exhibits superposition of Fe2+ and Ni2+ signals. It is also known that the presence of Ni in ZnO nanoparticle could enhance the magnetic d-d exchange interaction between the magnetic moment of Ni2+ contribute for the ferromagnetic state [66]. Thus the observed ferromagnetism in the Zn0.96 Fe0.01Ni0.03O could be considered as a result of the exchange interaction between conductive electron with local spin polarized electron on the Ni2+ or Fe2+ ions. In some reported transition metal doped ZnO systems, bound magnetic polaron (BMP) models are widely proposed mechanisms to explain the presence of room temperature ferromagnetism. The BMP model was used to explain room temperature ferromagnetism in semiconducting as well as insulating materials [67]. Other studies reported that defects and oxygen vacancies are common in Ni-doped ZnO nanostructures and are responsible for the formation of BMP [68]. However, the oxygen vacancy signal was not observed in Zn0.96Fe0.01Ni0.03O ESR spectra. Therefore, the conductive electron with local spin polarized electron exchange interaction is the more probable mechanism in the present investigation.

4. Conclusion

In conclusion, the room temperature ferromagnetism of Zn0.96Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O nanoparticles were observed. Several assumptions have been addressed to explain room temperature ferromagnetism: the role of secondary phases, metallic clusters and defect-induced ferromagnetism. A detailed analysis of XRD, EDX, UVVis and ESR measurements revealed that the formation of secondary phases and metallic clusters in Zn0.96 Fe0.01Cu0.03O and Zn0.96Fe0.01Ni0.03O nanoparticles were not responsible for the room temperature ferromagnetism. In Zn0.96Fe0.01Cu0.03O nanoparticles ESR and EDX analysis revealed that Fe2+ ions and Cu1+ were present. However, to neutralize the charge imbalance we believed that a small amount of Fe3+ and Cu2+ ions would be found in our sample and have played the important role in obtaining the room temperature ferromagnetism. In Zn0.96 Fe0.01Ni0.03O the conductive electron with local spin polarized electron exchange interaction is the more probable mechanism for the origin of room temperature ferromagnetism.

REFERENCES

  1. J. H. Shim, T. Hwang, S. Lee, J. H. Park and S.-J. Han, “Origin of Ferromagnetism in Feand Cu-Codoped ZnO,” Applied Physics Letters, Vol. 86, No. 8, 2005, Article ID: 082503. doi:10.1063/1.1868872
  2. S. A. Wolf, D. D. Awschalom, R. A. Buhrman, J. M. Daughton, S. Von Molnar, M. L. Roukes, A. Y. Chichelkanova and D. M. Treger, “Spintronics: A Spin-Based Electronics Vision for the Future,” Science, Vol. 294, No. 5546, 2001, pp. 1488-1495. doi:10.1126/science.1065389
  3. S. Ghosh and K. Mandal, “Study of Zn1xCoxO (0.02 < x < 0.08) Dilute Magnetic Semiconductor Prepared by Mechanosynthesis Route,” Journal of Magnetism and Magnetic Materials, Vol. 322, No. 14, 2010, pp. 1979-1984. doi:10.1016/j.jmmm.2010.01.017
  4. H. Ohno, “Making Nonmagnetic Semiconductors Ferromagnetic,” Science, Vol. 281, No. 5379, 1998, pp. 951- 956. doi:10.1126/science.281.5379.951
  5. G. A. Prinz, “Magnetoelectronics,” Science, Vol. 282, No. 5394, 1998, pp. 1660-1663. doi:10.1126/science.282.5394.1660
  6. L. B. Duan, W. G. Chu, J. Yu, Y. C. Wang, L. N. Zhang, G. Y. Liu, J. K. Liang and G. H. Rao, “Structural and Magnetic Properties of Zn1xCoxO (0 < x < 0.30) Nanoparticles,” Journal of Magnetism and Magnetic Materials, Vol. 320, No. 8, 2008, pp. 1573-1581. doi:10.1016/j.jmmm.2008.01.009
  7. T. Dietl, H. Ohno, F. Matsukura, J. Cibert and D. Ferrand, “Zener Model Description of Ferromagnetism in ZincBlende Magnetic Semiconductors,” Science, Vol. 287, No. 5455, 2000, pp. 1019-1022. doi:10.1126/science.287.5455.1019
  8. X. Y. Xu and C. B. Cao, “Structure and Ferromagnetic Properties of Co-Doped ZnO Powders,” Journal of Magnetism and Magnetic Materials, Vol. 321, No. 14, 2009, pp. 2216-2219. doi:10.1016/j.jmmm.2009.01.017
  9. J. M. Wesselinowa and A. T. Apostolov, “A Possibility to Obtain Room Temperature Ferromagnetism by Transition Metal Doping of ZnO Nanoparticles,” Journal of Applied Physics, Vol. 107, No. 5, 2010, Article ID: 053917. doi:10.1063/1.3329457
  10. P. K. Sharma, R. K. Dutta, A. C. Pandey, S. Layek and H. C. Verma, “Effect of Iron Doping Concentration on Magnetic Properties of ZnO Nanoparticles,” Journal of Magnetism and Magnetic Materials, Vol. 321, No. 17, 2009, pp. 2587-2591. doi:10.1016/j.jmmm.2009.03.043
  11. D. Karmakar, S. K. Mandal, R. M. Kadam, P. L. Paulose, A. K. Rajarajan, T. K. Nath, A. K. Das, I. Dasgupta and G. P. Das, “Ferromagnetism in Fe-Doped ZnO Nanocrystals: Experiment and Theory,” Physical Review B, Vol. 75, No. 14, 2007, Article ID: 144404. doi:10.1103/PhysRevB.75.144404
  12. M. L. Dinesha, H. S. Jayanna, S. Ashoka and G. T. Chandrappa. J. Op-toel. Adv. Mater., Vol. 11, 2009, p. 964.
  13. S. K. Mandal, A. K. Das, T. K. Nath, D. Karmakar and B. Satpati, “Microstructural and Magnetic Properties of ZnO: TM (TM=Co, Mn) Diluted Magnetic Semiconducting Nanoparticles,” Journal of Applied Physics, Vol. 100, No. 10, 2006, Article ID: 104315. doi:10.1063/1.2360387
  14. B. Martínez, F. Sandiumenge, L. Balcells, J. Arbiol, F. Sibieude and C. Monty, “Structure and Magnetic Properties of Co-Doped ZnO Nanoparticles,” Physical Review B, Vol. 72, No. 16, 2005, Article ID: 165202. doi:10.1103/PhysRevB.72.165202
  15. L. B. Duan, G. H. Rao, J. Yu and Y. C. Wang, “Ferromagnetism of Lightly Co-Doped ZnO Nanoparticles,” Solid State Communications, Vol. 145, No. 11, 2008, pp. 525- 528. doi:10.1016/j.ssc.2008.01.014
  16. G. J. Huang, J. B. Wang, X. L. Zhong, G. C. Zhou and H. L. Yan, “Synthesis, Structure, and Room-Temperature Ferromagnetism of Ni-Doped ZnO Nanoparticles,” Journal of Materials Science, Vol. 42, No. 15, 2007, pp. 6464- 6468. doi:10.1007/s10853-006-1256-4
  17. Z. X. Cheng, X. L. Wang, S. X. Dou, K. Otawa, H. Kimura and P. Munroe, “Synthesis, Structure, and Room-Temperature Ferromagnetism of Ni-Doped ZnO Nanoparticles,” Journal of Physics D, Vol. 40, No. 21, 2007, p. 6518. doi:10.1088/0022-3727/40/21/008
  18. P. K. Sharma, K. Prashant, R. K. Dutta and K. Ranu, “Effect of Nickel Doping Concentration on Structural and Magnetic Properties of Ultrafine Diluted Magnetic Semiconductor ZnO Nanoparticles,” Journal of Magnetism and Magnetic Materials, Vol. 321, No. 20, 2009, pp. 3457-3461. doi:10.1016/j.jmmm.2009.06.055
  19. J. Luo, J. K. Liang, Q. L. Liu, F. S. Liu, Y. Zhang, B. J. Sun and G. H. Rao, “Structure and Magnetic Properties of Mn-Doped ZnO Nanoparticles,” Journal of Applied Physics, Vol. 97, No. 8, 2005, Article ID: 086106. doi:10.1063/1.1873058
  20. J. B. Wang, G. J. Huang, X. L. Zhong, L. Z. Sun, Y. C. Zhou and E. H. Liu, “Raman Scattering and High Temperature Ferromagnetism of Mn-Doped ZnO Nanoparticles,” Appled Physics Letters, Vol. 88, No. 25, 2006, Article ID: 252502.
  21. O. D. Jayakumar, I. K. Gopalakrishnan, C. Sudakar, R. M. Kadam and S. K. Kulshreshtha, “Magnetization and Structural Studies of Mn Doped ZnO Nanoparticles: Prepared by Reverse Micelle Method,” Journal of Crystal Growth, Vol. 300, No. 2, 2007, pp. 358-363. doi:10.1016/j.jcrysgro.2006.12.030
  22. H. L. Liu, J. H. Yang, Y. J. Zhang, Y. X. Wang, M. B. Wei, D. D. Wang, L. Y. Zhao, J. H. Lang and M. Gao, “Ferromagnetism in Cu-Doped ZnO Nanoparticles at Room Temperature,” Journal of Materials Science: Materials in Electronics, Vol. 20, No. 7, 2009, pp. 628-631. doi:10.1007/s10854-008-9776-0
  23. N. Tahir, S. T. Hussain, M. Usman, S. K. Hasanain and A. Mumtaz, “Effect of Vanadium Doping on Structural, Magnetic and Optical Properties of ZnO Nanoparticles,” Applied Surface Science, Vol. 255, No. 20, 2009, pp. 8506-8510. doi:10.1016/j.apsusc.2009.06.003
  24. L. B. Duan, G. H. Rao, Y. C. Wang, J. Yu and T. Wang, “Magnetization and Raman Scattering Studies of (Co, Mn) Codoped ZnO Nanoparticles,” Journal of Applied Physics, Vol. 104, No. 1, 2008, Article ID: 013909. doi:10.1063/1.2952516
  25. O. D. Jayakumar, I. K. Gopalakrishnan and S. K. Kulshreshtha, “The Structural and Magnetization Studies of Co-Doped ZnO Co-Doped with Cu: Synthesized by CoPrecipitation Method,” Journal of Materials Chemistry, Vol. 15, 2005, pp. 3514-3518. doi:10.1039/b507201h
  26. H. W. Zhang, Z. R. Wei, Z. Q. Li and G. Y. Dong, “Room-Temperature Ferromagnetism in Fe-Doped, Feand Cu-Codoped ZnO Diluted Magnetic Semiconductor,” Materials Letters, Vol. 61, No. 17, 2007, pp. 3605-3607. doi:10.1016/j.matlet.2006.11.139
  27. H. Liu, J. Yang, Z. Hua, Y. Liu, L. Yang, Y. Zhang and J. Cao, “Cu-Doping Effect on Structure and Magnetic Properties of Fe-Doped ZnO Powders,” Materials Chemistry and Physics, Vol. 125, No. 3, 2011, pp. 656-659. doi:10.1016/j.matchemphys.2010.10.002
  28. S. J. Han, J. W. Song, C. H. Yang, S. H. Park, J. H. Parket and Y. H. Jeong, “A Key to Room-Temperature Ferromagnetism in Fe Doped ZnO:Cu,” Applied Physics Letters, Vol. 81, No. 22, 2002, p. 4212. doi:10.1063/1.1525885
  29. J. Shim, T. Hwang, J. Park, S. J. Han and Y. Jeong, “Origin of Ferromagnetism in Feand Cu-Codoped ZnO,” Applied Physics Letters, Vol. 86, No. 8, 2005, Article ID: 082503. doi:10.1063/1.1868872
  30. B. Hapke, “Theory of Reflectance and Emittance Spectroscopy,” Cambridge University Press, Cambridge, 1993. doi:10.1017/CBO9780511524998
  31. R. Saleh, S. P. Prakoso and A. Fishli, “The Influence of Fe Doping on the Structural, Magnetic and Optical Properties of Nanocrystalline ZnO Particles,” Journal of Magnetism and Magnetic Materials, Vol. 324, No. 5, 2012, pp. 665-670. doi:10.1016/j.jmmm.2011.07.059
  32. M. Mukhtar, L. Munisa and R. Saleh, “Co-Precipitation Synthesis and Characterization of Nanocrystalline Zinc Oxide Particles Doped with Cu2+ Ions,” Materials Sciences and Applications, Vol. 3, No. 8, 2012, pp. 543-551. doi:10.4236/msa.2012.38077
  33. R. Saleh, N. F. Djaja and S. P. Prakoso, “The Correlation between Magnetic and Structural Properties of Nanocrystalline Transition Metal-Doped ZnO Particles Prepared by the Co-Precipitation Method,” Journal of Alloys and Compounds, Vol. 546, 2013, pp. 48-56. doi:10.1016/j.jallcom.2012.08.056
  34. S. P. Prakoso and R. Saleh, “Synthesis and Spectroscopic Characterization of Undoped Nanocrytalline ZnO Particles Prepared by Co-Precipitation,” Materials Sciences and Applications, Vol. 3, No. 8, 2012, pp. 530-537. doi:10.4236/msa.2012.38075
  35. G. K. Williamson and W. H. Hall, “X-Ray Line Broadening from Filled Aluminium and Wolfram,” Acta Metallurgica, Vol. 1, No. 1, 1953, pp. 22-31. doi:10.1016/0001-6160(53)90006-6
  36. K. Srinivas, S. M. Rao and P. V. Reddy, “Preparation and Properties of Zn0.9Ni0.1O Diluted Magnetic Semiconductor Nanoparticles,” Journal of Nanoparticle Research, Vol. 13, No. 2, 2011, pp. 817-837. doi:10.1007/s11051-010-0084-2
  37. C. B. Azzoni, A. Paleari, V. Massarotti and D. Capsoni, “Electron Paramagnetic Resonance Response and Magnetic Interactions in Ordered Solid Solutions of Lithium Nickel Oxides,” Journal of Physics: Condensed Matter, Vol. 8, No. 39, 1996, p. 7339. doi:10.1088/0953-8984/8/39/010
  38. E. Zhecheva, R. Stoyanova, R. Alcántara, P. Lavela and J.-L. Tirado, “Cation Order/Disorder in Lithium Transition-Metal Oxides as Insertion Electrodes for LithiumIon Batteries,” Pure and Applied Chemistry, Vol. 74, No. 10, 2002, pp. 1885-1894. doi:10.1351/pac200274101885
  39. L. He, X.-X. Wu, H.-G. Liu and W.-C. Zheng, “Theoretical Calculation of EPR g Factors for Ni3+ Ion at the Interstitial Site of SnO2 Crystal,” Spectrochimica Acta Part A, Vol. 68, No. 3, 2007, pp. 891-893. doi:10.1016/j.saa.2006.12.075
  40. S.-Y. Wu, X.-Y. Gao, J.-Z. Lin, Q. Fu and G.-D. Lu, “Studies on the Local Structures of the Substitutional and Interstitial Ni3+ Centers in Rutile,” Chemical Physics, Vol. 328, No. 1-3, 2006, pp. 26-32. doi:10.1016/j.chemphys.2006.06.004
  41. R. Elilarassi and G. Chandrasekaran, “Structural, Optical, and Magnetic Characterization of Cu-Doped ZnO Nanoparticles Synthesized Using Solid State Reaction Method,” Journalo of Materials Science: Materials in Electronics, Vol. 21, No. 11, 2010, pp. 1168-1173. doi:10.1007/s10854-009-0041-y
  42. X. L. Li, X. H. Xu, Z. Y. Quan, J. F. Guo, H. S. Wu and G. A. Gehring, “Role of Donor Defects in Enhacing Ferromagnetism of Cu-Doped ZnO Films,” Journal of Applied Physics, Vol. 105, No. 10, 2009, Article ID: 103914. doi:10.1063/1.3130104
  43. A. J. Reddy, M. K. Kokila, H. Nagabhushana, R. P. S. Chakradhard, C. Shivakumara, J. L. Rao and B. M. Nagabhushana, “Structural, Optical and EPR Studies on ZnO:Cu Nanopowders Prepared via Low Temperature Solution Combustion Synthesis,” Journal of Alloys and Compounds, Vol. 509, No. 17, 2011, pp. 5349-5355. doi:10.1016/j.jallcom.2011.02.043
  44. N. Y. Garces, L. Wang, L. Bai, N. C. Giles, L. E. Halliburton and G. Cantwell, “Role of Copper in the Green Luminescence from ZnO Crystals,” Applied Physics Letters, Vol. 81, No. 4, 2002, p. 622. doi:10.1063/1.1494125
  45. D. M. Hoffmann, A. Hofstaetter, F. Leiter, H. Zhou, F. Henecker and B. K. Meyer, “Hydrogen: A Relevant Shallow Donor in Zinc Oxide,” Physical Review Letters, Vol. 88, No. 4, 2002, Article ID: 045504. doi:10.1103/PhysRevLett.88.045504
  46. K. M. Sancier, “ESR Investigation of Photodamage to Zinc Oxide Powders,” Surface Science, Vol. 21, No. 1, 1970, pp. 1-11. doi:10.1016/0039-6028(70)90059-2
  47. M. Schulz, “ESR Experiments on Ga Donors in ZnO Crystals,” Physica Status Solidi, Vol. 27, No. 1, 1975, pp. K5-K8. doi:10.1002/pssa.2210270140
  48. P. H. Kasai, “Electron Spin Resonance Studies of Donors and Acceptors in ZnO,” Physical Review, Vol. 130, No. 3, 1963, pp. 989-995. doi:10.1103/PhysRev.130.989
  49. A. Hausmann and B. Schallenberger, “Interstitial Oxygen in Zinc Oxide Single Crystals,” Zeitschrift fur Physik, Vol. 31, No. 3, 1978, pp. 269-273.
  50. V. Ischenko, S. Polarz, D. Grote, V. Stavarache, K. Fink and M. Driess, “Zinc Oxide Nanoparticles with Defects,” Advanced Functional Materials, Vol. 15, No. 12, 2003, pp. 1945-1954. doi:10.1002/adfm.200500087
  51. N. G. Kakazev, T. V. Sreckovic and M. M. Ristic, “Electronic Paramagnetic Resonance Investigation of The Evolution of Defects in Zinc Oxide during Tribophysical Activation,” Journal of Materials Science, Vol. 32, No. 7, 2007, pp. 4619-4622. doi:10.1023/A:1018689721667
  52. L. S. Vlasenko, “Magnetic Resonance Studies of Intrinsic Defects in ZnO:Oxygen Vacancy,” Applied Magnetic Resonance, Vol. 39, No. 1-2, 2010, pp. 103-111. doi:10.1007/s00723-010-0140-1
  53. M. M. Selim and I. H. Abd El-Maksoud, “Spectroscopic and Catalytic Characterization of Ni Nano-Size Catalyst for Edible Oil Hydrogenation,” Microporous and Mesoporous Materials, Vol. 85, No. 3, 2005, pp. 273-278. doi:10.1016/j.micromeso.2005.06.027
  54. P. Thakur, V. Bisogni, J. C. Cezar, N. B. Brookes, G. Ghiringhelli, S. Gautam, K. H. Chae, M. Subramanian, R. Jayavel and K. Asokan, “Electronic Structure of CuDoped ZnO Thin Films by X-Ray Absorption, Magnetic Circular Dichroism, and Resonant Inelastic X-Ray Scattering,” Journal of Applied Physics, Vol. 107, No. 10, 2011, Article ID: 103915.
  55. M. Wei, N. Braddon, D. Zhi, P. A. Midgley, S. K. Chen, M. G. Blamire and J. L. MacManus-Driscoll, “Room Temperature Ferromagnetism in Bulk Mn-Doped Cu2O,” Applied Physics Letters, Vol. 86, No. 7, 2005, Article ID: 072514. doi:10.1063/1.1869547
  56. M. S. Seehra, P. Dutta, V. Singh, Y. Zhang and I. Wender, “Evidence for Room Temperature Ferromagnetism in CuxZn1−xO from Magnetic Studies in CuxZn1−xO/CuO composite,” Journal of Applied Physics, Vol. 101, No. 9, 2007, Article ID: 09H107.
  57. D. Wang, Z. Q. Chen, D. D. Wang, J. Cong, C. Y. Cao, Z. Tang and L. R. Huang, “Effect of Thermal Annealing on the Structure and Magnetism of Fe-Doped ZnO Nanocrystals Synthesized by Solid State Reaction,” Journal of Magnetism and Magnetic Materials, Vol. 322, No. 22, 2010, pp. 3642-3647. doi:10.1016/j.jmmm.2010.07.014
  58. D. A. A. Santos and M. A. Macedo, “Study of the Magnetic and Structural Properties of Mn-, Fe-, and CoDoped ZnO Powder,” Physica B, in Press.
  59. F. Lin, D. M. Jiang and X. M. Ma, “The Influence of Annealing on the Magnetism of Fe-Doped ZnO Prepared by Mechanical Alloying,” Physics B, Vol. 405, No. 6, 2010, pp. 1466-1469. doi:10.1016/j.physb.2009.12.010
  60. [61] S. Yılmaz, E. McGlynn, E. Bacaksız, J. Cullen and R. K. Chellappan, “Structural, Optical and Magnetic Properties of Ni-Doped ZnO Micro-Rods Grown by the Spray Pyrolysis Method,” Chemical Physics Letters, Vol. 525, 2012, pp. 72-76. doi:10.1016/j.cplett.2012.01.003
  61. [62] M. Jagodic, Z. Jaglicic, A. Jelen, J. B. Lee, Y. M. Kim, H. J. Kim and J. Dolinsek, “Surface Spin Magnetism of Antiferromagnetic NiO in Nanoparticle and Bulk Morpholgy,” Journal of Physics: Condensed Matter, Vol. 21, No. 21, 2009, Article ID: 215302. doi:10.1088/0953-8984/21/21/215302
  62. [63] C. J. Cong, J. H. Hong and K. L. Zhang, “Effect of Atmosphere on the Magnetic Properties of the Co-Doped ZnO Magnetic Semiconductors,” Materials Chemistry and Physics, Vol. 113, No. 1, 2009, pp. 435-440. doi:10.1016/j.matchemphys.2008.06.062
  63. [64] Z. Xiong, X.-C. Liu, S.-Y. Zhuo, J.-H. Yang, E.-W. Shi and W.-S. Yan, “Oxygen Enhanced Ferromagnetism in Cr-Doped ZnO Films,” Applied Physics Letters, Vol. 99, No. 5, 2011, Article ID: 052513. doi:10.1063/1.3624589
  64. [65] S. Ramachandran, J. Narayan and J. T. Prater, “Effect of Oxygen Annealing on Mn Doped ZnO Diluted Magnetic Semiconductors,” Applied Physics Letters, Vol. 88, No. 24, 2006, Article ID: 242503. doi:10.1063/1.2213930
  65. [66] R. Viswanatha, D. Naveh, J. R. Chelikowsky, L. Kronik and D. D. Sarma, “Magnetic Properties of Fe/Cu Codoped ZnO Nanocrystals,” Journal of Physical Chemistry Letters, Vol. 3, No. 15, 2012, pp. 2009-2014. doi:10.1021/jz300741z
  66. [67] X. F. Liu and R. H. Yu, “Mediation of Room Temperature Ferromagnetism in Co-Doped SnO2 Nanocrystalline Films by Structural Defects,” Journal of Applied Physics, Vol. 102, No. 8, 2007, Article ID: 083917. doi:10.1063/1.2801375
  67. [68] G. Venkataiah, M. R. S. Huang, H. L. Su, C. P. Liu and J. C. A. Huang, “Microstructure and Magnetic Properties of Ni:ZnO Nanorod/Zn:NiO Nanowall Composite Structures,” Journal of Physics Chemistry C, Vol. 114, No. 39, 2010, pp. 16191-16196. doi:10.1021/jp1036553
  68. [69] M. El-Hilo, A. A. Dakhel and A. Y. Ali-Mohamed, “Room Temperature Ferromagnetism in Nanocrystalline Ni-Doped ZnO Synthesized Byco-Precipitation,” Journal of Magnetism and Magnetic Materials, Vol. 321, No. 24, 2009, pp. 2279-2283. doi:10.1016/j.jmmm.2009.01.040

NOTES

*Corresponding author.