Journal of Geoscience and Environment Protection
2013. Vol.1, No.2, 22-25
Published Online October 201 3 in SciRes (http://www.scirp.org/journal/gep) http://dx.doi.org/10.4236/gep.2013.12005
Copyright © 2013 SciRes.
Experimental Study on Fly Ash for Conditioning of Specific
Resistance of Sludge Water
Bingtao Liu, Pengju Ding
School of Environmental and Municipal Engineering, North China University of Water Resources and Electric
Power, Zhengzhou, C hina
Received August 2013
Discharge of sludge from water works into waters will result in the increased deterioration of water envi-
ronment. Therefore, an experimental study was conducted on the addition of conditioning agent to im-
prove sludge dewatering performance. The result shows that coagulation is inadaptable to the treatment of
sludge from water works and use of powdered coal ash from power plant as conditioning agent can great-
ly reduce the specific resistance of sludge and the dewatering performance can be improved. The optimal
dosage of fine powdered coal is 20 g/100 mL and coarse powdered coal is 30 g/100 mL. Powdered coal is
mixed with sludge to form filter cake, which is blended with coal in certain proportion to make into fuel.
So that incineration of sludge from water works can be realized.
Keywords: Fly Ash; Sludge Water; Sludge; Specif i c Resi s t ance
The sludge water of waterworks includes sludge water of set-
tling tank and backwash wastewater of filter. After the simple
sedimentation and separation, the supernatant can be reused,
sediment forms so-called sludge of sludge water. At present,
most of the existing waterworks directly discharge sludge of
sludge water into natural water in China which will cause pol-
lution to water (Liu Hui & Xu Jianhua, 2001; Lu jiajuan, 2005).
In the 1970s, the United States, Japan and other developed
countries began to pay attention to the treatment and disposal of
sludge of waterworks (John T. Novak, 1999; J Kopp & N Dichtl,
2001). The treatment method is similar to sludge treatment me-
thod of municipal sewage plant (Xu Qiang , 2003). However, the
sludge from waterworks and sewage plant has different charac-
teristics, even if the sludge is all from waterworks. There are
significant differences in properties because of the different raw
water quality and the different production technology. We have
an experimental research on methods of treatment and disposal
of sludge from inclined tube sedimentation tank of water treat-
ment plant in Zhengzhou.
Main Reagents and Mud Sample
PAC, light yellow powder, alumina content 31%, basicity
76%, confect concentration of 10 g∙L−1 when use i t.
Sludge samples, Activated sludge from Zhengzhou city se-
wage sludge treatment plant emissions, take underlayer preci-
pitation after standing.
Two kinds of fly ash that contains fly ash of coarse particle
and fine particle in the experiment are from Zhengzhou thermal
power plant. Its quality is shown in Table 1.
Test is divided into two steps. First of all is test of coagula-
Quality index of powdered fly ash (%).
(Remai ni ng amount of 45 µm screen)
Fly ash of coarse particle 55.2 4.41
Fly ash of fine particle 12.9 3.13
tion, sedimentation and pre-concentration of waterworks sludge
is in progress and we can obtain settlement curve. Then specific
resistance of mud sample is measured (an important index of
sludge dewatering performance) and make optimization of the
sludge conditioner of specific resistance in order to achieve the
sludge dehydration and drying.
The purpose of adding 1 g PAC and 5 mg PAM coagulant to
per liter of sludge water is to destabilize colloids that inorganic
coagulant is the first dosing and PAM is dosing after 5 S. Oper-
ating parameters: in the mixing process, n = 300 r/min, T = 30
S; in the flocculation process, n1 = 150 r/min, T1 = 3 min, n2 =
30 r/min, T2 = 10 min. Static precipitation continues for 2 h
after coagulation, a decline height of muddy liquid level along
with time is recorded and subsidence curves is depicted.
Specific resistance has a special measuring device shown in
Figure 1. Including Büchner funnel, filter media, smoke filters,
cylinders, vacuum table and vacuum pump.
Test run at room temperature. Measure out 100 ml of sludge
in the beaker, stir in a certain pH by adding flocculents, stir in
medium-speed about 5 minutes and pour into the Büchner fun-
nel, the vacuum filtration dehydrat ion until no drop. Then record
at different times (t) and the corresponding filtrate volume (v),
with t/v as the vertical coordinate, v the horizontal mapping, t/v
and v is linear, the slope b, constant pressure filtration
B. T. LIU, P. J. DING
Copyright © 2013 SciRes.
Experimental set of specific resistance measurement.
P: filtration pressure (for the cake pressure difference be-
tween top and bottom surfaces), N∙m−2
A: filter media area, m2
b: filtration time/filtrate volume and filtrate volume formed
by the slope, s∙m−6
µ: filtrate dynamic viscosity, (N.s)∙m−2
C: filter biscuits dry quality by the filtrate, kg∙m−3, according
to the weight of dry solid and the filtrate volume by filtrate to
We can calculate the specific resistance of sludge and meas-
ure its filtrate turbidity, filtration time and filtrate volume, and
needed time to get same filtrate. Sludge dewatering perfor-
mance reflect by the specific resistance, the greater the value
the worse the dehydration properties. By contrary, dehydration
performance is better.
At present, in order to improve dewatering performance of
the sludge of waterworks, sludge usually be added the right
amount of polyacrylamide (PAM) to reduce specific resistance
of sludge before its mechanical dehydration. But PAM exists
many problems in practice. Firstly the price is expensive. It
cannot reach to the effect of reducing specific resistance when
dosage is insufficient and dosage is more and it will make the
operation cost become too high. Secondly PAM is a kind of
viscous slurry. It is easy to stick on the cloth filter and choke
filtration pore which affects the dehydration efficiency. So the
material such as fly ash of power plant is chosen as a condi-
tioner. Optimization experiment is carried out in order to im-
prove the separation efficiency and reduce the production cost.
Results and Discu ssion
Curve of Natural Sedimentation and Coagulation
Settlement curve can be seen by Figure 2, Whether the nat-
ural sedimentation of original sludge water or static precipita-
tion under optimum amount of coagulant, the drop height of
muddy liquid are not very satisfactory, which decrease by only
3.2%, 4.0% and 8.1%, respectively, thus we need not set up the
coagulation process when we design the process of sludge wa-
ter treatment for waterworks, only set up an intermediate regu-
Settlement curve of sludge water.
lating pond, and preliminary sinking separation pool is not ne-
Specific Resist ance C onditioning Curve of Sludge
Measurement results of specific resistance of original sludge
are shown in Table 2. Literature Novak J indicates that, gener-
ally speaking, when the specific resistance < 1011 m/kg, sludge
is easy to dewater, and specific resistance > 1013 m/kg, sludge
dewatering becomes difficult. It is obvious that original sludge
dewatering is difficult, suction filtration time is long, and it
needs to be conditioning.
Figure 3 shows that specific resistance of sludge decrease
quickly with the increase of dosage of fly ash from the pre-
treatment magnitude of 1013 to 1010. When the dosage of fly ash
increased to 30 g per 100 ml of mud sample, the curve tend to
gentle. In the case of low dosage, that the effect of improving
sludge dewatering performance for fine fly ash is more obvious
than coarse fly ash, with the increase of dosage of fly ash, the
ability of improving specific resistance for the coarse and fine
fly ash tend to be the same. In the measurement experiment of
specific resistance, the linear slope (b) formed by filtering time/
filtrate volume and filtrate volume can indirectly reflect the
speed of filtration rate, the smaller of the value of b, the greater
of the speed of filtration rate. The results show that, the value of
b drops rapidly with the increase of the dosage of fly ash (the
filtration rate increases rapidly), when the dosage of coarse fly
ash is 30 g or the dosage of fine fly ash is 20 g, the speed of
filtration rate is the largest, after that, the filtration rate is de-
creased with the increase of the dosage of fly ash.
The Amplification Test under the Optimal Do sage
According to the front of the test results, it shows that the
optimum dosage of coarse fly ash and fine fly ash is 30 g/100
ml and 20 g/100 ml of sludge, respectively. The optimal dosage
of sludge dewatering performance and the nature of the filtrate
are shown in Table 2.
From Table 3, we can know that the specific resistance of
sludge decreases rapidly and the speed of filtration rate in-
creases significantly after the conditioning of fly ash, the suc-
tion filtration can be completed in about 3 minutes, and the
B. T. LIU, P. J. DING
Copyright © 2013 SciRes.
Specific resistance measurement of original sludge.
Items Suction filtration time/S Filtrate volume/ml Moisture content of filter cake/% specific resistance/1013∙m∙kg−1
Numeric value 930 94.5 92.25 1.92
Dewatering performance and filtrate quality at optimum dosage.
Conditioning dose Dosage (g) Specific resistance
(1011 m/kg) Filtering
time (s) Filtrate
volume (ml ) Moisture content
of filter cake (%) Filtrate turbidity
of filtrate (NCU) CODMn
of filtrate (mg/L)
Coarse fly ash 30 .50 160 70 41.12 4 32 16.00
Fine fly ash 20 .70 200 75 47.80 4 23 15.04
Amplification of 1 1500 .45 140 73 40.04 4 30 20.77
Amplification of 2 1000 .80 220 80 47.96 4 28 17.45
Effect of Sludge specific resistance.
filter cake is dry, it is easy to strip from the filter paper, the
value of filtrate turbidity, chromaticity and CODMn is not high,
it can be used as municipal miscellaneous water.
Ignition loss is due to the unburned carbon particles burning
again in the laboratory. The ignition loss in the filter cake
formed by the fine fly ash after dehydration is 6.47%, and igni-
tion loss of fine fly ash is only 3.13%, so it can be inferred that
the increase combustible comes from combustible components
of the sludge. It can be taken use of, for example, it can be
made of blend coal cake through mixing with proportion coal,
which is available for civilian or power boiler burning, so as to
achieve the final incineration disposal of sludge.
Analysis Results of Scanning Elec tron Microscop e
The section of filter cake of original mud and conditioning is
sprayed gold, then scanning electron microscope is carried out.
The results are shown in figure. The sludge particle size of
sludge water is very small, about the quality of 76% of particle
size is less than 4 microns, so the channel of filter cake formed
is small (Fei Xiali & Cui Fu yi, 2004). In addition, there is a layer
of hydration shell in granular bed of filter cake whose flowabil-
ity is poor. It can be seen from Figure 4. The filter cake gap of
original sludge is very small and it will make filtration resis-
tance increases and the fly ash is a variety of mechanical mix-
SEM appearance made from original sludge.
ing of powder particles. Generally the particle size is more than
30 microns due to the unique structural characteristics of fly ash.
The mud sample of conditioning can be used as a skeleton
which make the sludge flocs form the structure of persistence
and strong. The channel of filter cake is larger, which can form
the solidified layer of loosened structure and increase the void
fraction as is shown in Figures 5 and 6. At the same time, the
carbon that is not burning enough and porous vitreous content
of fly ash is less, the content of glass beads is more, it is not
easy to store water for caves and gap of sphere but coarse fly
ash is instead, so in the case of low additive amount of fly ash,
fine fly ash is better to the improvement of the sludge dewater-
ing effect .
When the sludge of sludge water of waterworks carries on
the treatment of dewatering and drying, it is better to choose fly
ash as conditioners (filter aid). In the process design of treat-
ment of sludge water of waterworks, we need not set up the
coagulation process, and only set up an intermediate regulating
pond. It is easy to dewater for the sludge of waterworks that
have been conditioning by fly ash, mud cake that comes from
the process of filter-press and suction filtration is mixed with
coal to make coal cake, which can realize the final incineration
B. T. LIU, P. J. DING
Copyright © 2013 SciRes.
SEM appearance by coarse fly ash.
SEM appearance by fine fly ash.
We thank the financial support by North China University of
Water Resources and Hydroelectric Power.
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