K. SREEVANI ET AL.
Copyright © 2013 SciRes. JMMCE
23
Table 3. Comparitive study of SHG efficiencies of different
centrosymmetric crystals.
Compound Space group
SHG SHG efficiency in
comparison with
KDP(in times)
R,S-serine [9] P21/a 0.02
(p-Nitrophenol,
hexamethyltetramine,
phosphoric acid and water)
super molecular crystal [10]
P21/c 3.1
Glycine picrate [11] P21/a 2.34
CdCl2 (TPPO)4
[present work] Pbca 0.94
material was confirmed by EDAX analysis. The func-
tional groups were identified using FTIR analysis. The
UV-Vis-NIR spectrum reveals the wider transmission
window of CdCl2 (TPPO)4. Thermal analysis indicates
that CdCl2 (TPPO)4 is thermally stable upto ~573 K. The
powder SHG efficiency of this CdCl2 (TPPO)4, a centro-
symmetric crystal is ~0.94 times that of the efficiency of
KDP and can be used in photonics device fabrication.
The mechanical stability of CdCl2 (TPPO)4 has been de-
termined using Vickers microhardness studies.
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