Roughness Control of Layer-by-Layer and Alternative Spray Films from Congo Red and PAH
via Laser Light Irradiation
555
about 50%.
The large difference in roughness between the LbL
and spray films can be explained by considering the for-
mation process of each kind of film. LbL films are
formed by the spontaneous adsorption of molecules from
solution onto the substrate [9] or PAH layer that is ac-
companied of drying process, whereas in the alternative
spray films, a large amount of molecules staying in
contact for more time during the drying process (5 min
for each layer). Decher showed that the thickness in-
crease as function of time [11].
In addition LbL films have a smaller roughness and a
more stable structure under irradiation because of the
spontaneous adsorption of molecules which produces a
higher molecular packing. In the case of alternative spray
films, the lower packing concert with the higher rough-
ness becomes possible controlling the roughness through
the laser irradiation. This can occur though relaxing of
the surface structure caused by the interplay between
photoisomerization and heating of the films.
4. Conclusion
Layer-by-layer and alternative spray films were success-
fully prepared from congo red dye alternated with PAH.
The comparison between the two systems revealed that
the roughness of the LbL films is smaller than those
exhibited by the spray ones. This was attributed to dif-
ference in structure of the two kinds of films due to for-
mation mechanisms. It was found that only the spray
films displayed regular roughness changes of their
surface under laser irradiation which was associated to
lower packing concert with the higher roughness. These
results suggested that this alternative spray technique
provide films thicker and with higher roughness that may
be a good alternative to LbL one when is required more
material adsorbed and a roughness control for device
applications.
5. Acknowledgements
This work was supported by CNPq and CAPES (Brazil).
R. J. da Silva and R. R. G. Maciel thank Capes (nbioNet)
and CNPq for the scholarship.
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